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公开(公告)号：US20140173835A1
公开(公告)日：2014-06-26
申请号：US14236364
申请日：2012-06-19
IPC分类号： C09B62/533 , C09B62/513
CPC分类号： C09B62/533 , C09B62/4415 , C09B62/513 , C09B67/0055 , D06P1/38 , D06P3/248 , D06P3/66
摘要： Dye mixtures comprising at least one reactive dye of the formula (1) together with at least one reactive dye of the formula (2), wherein one of the radicals A and B denotes NH2, and the other one of the radicals A and B denotes OH, D is a benzene or naphthalene radical, R1 is hydrogen, hydroxy, sulfo, C1-C4alkyl or C1-C4alkoxy unsubstituted or substituted in the alkyl moiety by hydroxy or by sulfato, R2 is hydrogen, C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino or ureido, R3 is C1-C4alkyl, (R4)0-2 denotes 0 to 2 identical or different substituents selected from the group C1-C4alkyl, C1-C4alkoxy or sulfo, X1 is halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, Y1, Y2, Y3, Y4 and Y5 are each independently of the other vinyl or a radical —CH2CH2—U and U is a group removable under alkaline conditions, h, k, l, m and n are each independently of the other the number 0, 1 or 2, and p and q are each independently of the other the number 0 or 1, are suitable for dyeing and printing cellulosic or nitrogen-containing fibre materials.
摘要翻译： 包含至少一种式（1）的活性染料与至少一种式（2）的活性染料的染料混合物，其中基团A和B中的一个表示NH 2，基团A和B中的另一个表示 OH，D是苯或萘基，R 1是氢，羟基，磺基，C 1 -C 4烷基或被烷基部分被羟基或硫酸酯取代的C 1 -C 4烷氧基，R 2是氢，C 1 -C 4烷基，C 1 -C 4烷氧基， C 2 -C 4烷酰基氨基或脲基，R 3是C 1 -C 4烷基，（R 4）0-2表示0至2个相同或不同的选自C 1 -C 4烷基，C 1 -C 4烷氧基或磺基，X 1为卤素，3-羧基吡啶-1-基， 吡啶-1-基或3-氨基甲酰基吡啶-1-基，Y 1，Y 2，Y 3，Y 4和Y 5各自独立地为其它乙烯基或基团-CH 2 CH 2 -U，U是在碱性条件下可除去的基团，h，k，l，m 和n各自独立于数字0,1或2中的另一个，并且p和q各自独立于数字0或1中的另一个，适用于染色和印刷c 纤维素或含氮纤维材料。
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公开(公告)号：US20100154145A1
公开(公告)日：2010-06-24
申请号：US12063277
申请日：2006-08-02
CPC分类号： C09B62/043 , C09B62/4416 , Y10S8/918
摘要： Reactive dyes of formula wherein B is an aliphatic bridging member, R1 is C1-C4alkyl, halogen or an —SO2—Z radical, R2 and R3 are each independently of the other C1-C4alkoxy, R4, R5 and R6 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, k and q are each independently of the other the number 0 or 1, p is the number 0, 1 or 2, X1 and X2 are each independently of the other halogen, and T is halogen, a non-fibre-reactive substituent or a fibre-reactive radical of formula wherein (R7)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, Q is a —CH(Hal)-CH2-Hal or —C(Hal)=CH2 group and Hal is halogen, or T is a radical of formula wherein R1, R2, R3, R4, k, p and q each have the definitions given above, are suitable especially for dyeing cotton and yield dyeings having good all-round fastness properties.
摘要翻译： R 1为C 1 -C 4烷基，卤素或-SO 2 - Z基团，R 2和R 3各自独立地为C 1 -C 4烷氧基，R 4，R 5和R 6各自独立地为 其他氢或未取代或取代的C 1 -C 4烷基，k和q各自独立地为数字0或1，p为数0,1或2，X 1和X 2各自独立地为其它卤素，T为卤素 ，非光纤反应性取代基或下式的纤维反应性基团其中（R7）0-2表示0至2个相同或不同的取代基，如卤素，C 1 -C 4烷基，C 1 -C 4烷氧基和磺基，Z是乙烯基 或-CH 2 -CH 2 -U基团，U是在碱性条件下可除去的基团，Q是-CH（Hal）-CH 2 - Hal或-C（Hal）= CH 2基团，Hal是卤素，或T是 其中R1，R2，R3，R4，k，p和q各自具有上述定义的基团，其特别适用于染色棉花和具有良好全部成分的产量染色剂， 圆形坚牢性。
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3.发明申请MIXTURES OF REACTIVE DYES AND THEIR USE IN A METHOD FOR TRICHROMATIC DYEING OR PRINTING 有权反应性染料的混合物及其在三色染色或印刷方法中的应用公开(公告)号：US20100077555A1
公开(公告)日：2010-04-01
申请号：US12513464
申请日：2007-10-30
IPC分类号： C09B62/095 , C09B62/012
CPC分类号： C09B62/4407 , C09B62/4413 , C09B62/4415 , C09B67/005 , C09B67/0059
摘要： Dye mixtures, comprising at least one dye of formula and at least one dye from the group of formulae wherein Q1 is C1-C4alkyl, halogen or a radical —SO2—Z, Q2 and Q3 are each independently of the other C1-C4alkoxy, Q4 is C1-C4alkoxy, C1-C4alkyl, halogen or sulfo, Q5 is C1-C4alkoxy, C1-C4alkyl, C1-C4alkanoylamino, ureido, halogen or sulfo, R1, R2 and R3 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, k and q are each independently of the other the number 0 or 1, n and p are each independently of the other the number 0, 1 or 2, m is the number 0, 1, 2 or 3, t is the number 1, 2 or 3, X1, X2 and X3 are each independently of the others halogen, 3-carboxypyridin-1-yl, 3-carbamoylpyridin-1-yl or a non-fibre-reactive substituent, and T1, T2 and T3 are each independently of the others a non-fibre-reactive substituent or a fibre-reactive radical of formula wherein (R4)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, Q is a group —CH(Hal)-CH2-Hal or —C(Hal)=CH2, and Hal is halogen, are suitable especially for the dichromatic or trichromatic dyeing or printing of cellulosic fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.
摘要翻译： 染料混合物，其包含至少一种下式的染料和至少一种下式基团的染料，其中Q 1是C 1 -C 4烷基，卤素或基团-SO 2 -Z，Q 2和Q 3各自独立地为C 1 -C 4烷氧基，Q 4 C1-C4烷氧基，C1-C4烷基，卤素或磺基，Q5是C1-C4烷氧基，C1-C4烷基，C1-C4烷酰基氨基，脲基，卤素或磺基，R1，R2和R3各自独立地是氢或未取代的或取代的C1 -C 1-4烷基，k和q各自独立于数字0或1中的另一个，n和p各自独立于数字0,1或2中的另一个，m是数字0,1,2或3，t是 1,2或3个，X1，X2和X3各自独立地为卤素，3-羧基吡啶-1-基，3-氨基甲酰基吡啶-1-基或非纤维反应性取代基，T1，T2和T3 各自独立地为非纤维反应性取代基或具有下式的纤维反应性基团其中（R4）0-2表示0至2个相同或不同的取代基，基团卤素 ，C 1 -C 4烷基，C 1 -C 4烷氧基和磺基，Z是乙烯基或基团-CH 2 -CH 2 -U，U是在碱性条件下可除去的基团，Q是基团-CH（Hal）-CH 2 - Hal或-C（ Hal）= CH2，Hal是卤素，特别适用于纤维素纤维材料的二色或三色染色或印花，并且具有良好的再现性和良好的全面牢固性的产量染色或印花。
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公开(公告)号：US20080250575A1
公开(公告)日：2008-10-16
申请号：US10592976
申请日：2005-03-09
IPC分类号： C09B62/513 , B05D1/02
CPC分类号： C09B62/09 , C09B62/475 , C09B62/513
摘要： Reactive dyes of formula wherein Q1 and Q2 are each independently of the other hydrogen or unsubstituted or substituted C1-C4alkyl, D1 is the radical of a diazo component, which is itself a mono- or dis-azo dye or contains such a dye, D2 has the same definition as D1 or is a radical of formula wherein (Q3)0-3 denotes from 0 to 3 identical or different substituents selected from the group halogen, C1-C4alkyl, C1-C4alkoxy, carboxy and sulfo and Z1 is a radical of formula —SO2—Y , (3a) —NH—CO—(CH2)m—SO2—Y , (3b) —CONH—(CH2)n—SO2—Y , (3c) —NH—CO—CH(Hal)-CH2-Hal or (3d) —NH—CO—C(Hal)=CH2 , (3e) Y is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, m and n are each independently of the other the number 2, 3 or 4, and Hal is halogen, are suitable for dyeing cellulosic or amide-group-containing fibre materials.
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公开(公告)号：US07887602B2
公开(公告)日：2011-02-15
申请号：US12063277
申请日：2006-08-02
IPC分类号： C09B45/28
CPC分类号： C09B62/043 , C09B62/4416 , Y10S8/918
摘要： Reactive dyes of formula wherein the variables are defined herein. B is an aliphatic bridging member, R1 is C1-C4alkyl, halogen or an —SO2—Z radical, R2 and R3 are each independently of the other C1-C4alkoxy, R4, R5 and R6 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, k and q are each independently of the other the number 0 or 1, p is the number 0, 1 or 2, X1 and X2 are each independently of the other halogen, and T is halogen, a non-fiber-reactive substituent or a fiber-reactive radical of formula wherein (R7)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, Q is a —CH(Hal)-CH2-Hal or —C(Hal)=CH2 group and Hal is halogen, or T is a radical of formula wherein R1, R2, R3, R4, k, p and q each have the definitions given above, are suitable especially for dyeing cotton and yield dyeings having good all-round fastness properties.
摘要翻译： 式的活性染料，其中变量在本文中定义。 B是脂族桥连构件，R 1是C 1 -C 4烷基，卤素或-SO 2 - Z基团，R 2和R 3各自独立地是C 1 -C 4烷氧基，R 4，R 5和R 6各自独立地是氢或未被取代的 取代的C 1 -C 4烷基，k和q各自独立地为数字0或1，p为数0,1或2，X 1和X 2各自独立地为其它卤素，T为卤素，非纤维 - 反应性取代基或下式的纤维反应性基团其中（R7）0-2表示0至2个相同或不同的取代基，如卤素，C 1 -C 4烷基，C 1 -C 4烷氧基和磺基，Z为乙烯基或-CH 2 - CH2-U基团，U是在碱性条件下可除去的基团，Q是-CH（Hal）-CH 2 - Hal或-C（Hal）= CH 2基团，Hal是卤素，或者T是下式的基团其中 R1，R2，R3，R4，k，p和q各自具有上述定义，特别适用于染色棉和具有良好全面坚牢性的产量染色。
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公开(公告)号：US07572301B2
公开(公告)日：2009-08-11
申请号：US10592976
申请日：2005-03-09
CPC分类号： C09B62/09 , C09B62/475 , C09B62/513
摘要： Reactive dyes of formula wherein Q1 and Q2 are each independently of the other hydrogen or unsubstituted or substituted C1-C4alkyl, D1 is the radical of a diazo component, which is itself a mono- or dis-azo dye or contains such a dye, D2 has the same definition as D1 or is a radical of formula wherein (Q3)0-3 denotes from 0 to 3 identical or different substituents selected from the group halogen, C1-C4alkyl, C1-C4alkoxy, carboxy and sulfo and Z1 is a radical of formula —SO2—Y (3a), —NH—CO—(CH2)m—SO2—Y (3b), —CONH—(CH2)n—SO2—Y (3c), —NH—CO—CH(Hal)-CH2-Hal (3d) or —NH—CO—C(Hal)=CH2 (3e), Y is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, m and n are each independently of the other the number 2, 3 or 4, and Hal is halogen, are suitable for dyeing cellulosic or amide-group-containing fibre materials.
摘要翻译： 式的活性染料其中Q1和Q2各自独立于另一个氢或未取代或取代的C1-C4烷基，D1是重氮组分的基团，其本身是单或二偶氮染料或含有这种染料D2 具有与D1相同的定义或其为式（Ⅵ）的基团，其中（Q3）0-3表示0至3个选自卤素，C 1 -C 4烷基，C 1 -C 4烷氧基，羧基和磺基的相同或不同的取代基，Z 1为基团 公式<？in-line-formula description =“In-line Formulas”end =“lead”？> - SO2-Y（3a），<？in-line-formula description =“In-line Formulas”end =“ - 尾数“？> <？in-line-formula description =”In-line formula“end =”lead“？ - NH-CO-（CH2）m-SO2-Y（3b） 描述=“在线公式”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> - CONH-（CH2）n-SO2-Y ），<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> - NH-CO -CH（Hal）-CH 2-Hal（3d） 或<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> - NH-CO- C（Hal）= CH2（3e），<？在线公式描述=“内联式”末端=“尾”→Y是乙烯基或-CH 2 -CH 2 -U基，U是 在碱性条件下是可除去的，m和n各自独立地为数2，3或4，Hal为卤素，适用于染色含纤维素或含酰胺基的纤维材料。
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公开(公告)号：US20090178213A1
公开(公告)日：2009-07-16
申请号：US11994732
申请日：2006-06-28
CPC分类号： D06P3/66 , C09B67/0042 , C09B67/0045 , C09B67/0057 , C09B67/0059 , C09D11/037 , C09D11/17 , C09D11/18 , C09D11/32 , D06P1/38
摘要： Dye mixtures that compriseat least one dye of formula together with at least one dye from the group of formulae wherein the radicals have the definitions given in the claims, are suitable, with good build-up behaviour, for dyeing or printing cellulose-containing fibre materials, and yield dyeings having a deep shade and good fastness properties.
摘要翻译： 包含至少一种式的染料的染料混合物以及至少一种下式基团的染料，其中基团具有权利要求中给出的定义，其具有良好的累积性能，用于染色或印刷含纤维素纤维 材料和产量染色具有深色度和良好的牢度性能。
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8.发明授权Mixtures of reactive dyes and their use in a method for trichromatic dyeing or printing 有权活性染料的混合物及其在三色染色或印刷方法中的应用公开(公告)号：US08083811B2
公开(公告)日：2011-12-27
申请号：US12513464
申请日：2007-10-30
IPC分类号： C09B45/42 , C09B62/09 , C09B62/095
CPC分类号： C09B62/4407 , C09B62/4413 , C09B62/4415 , C09B67/005 , C09B67/0059
摘要： Dye mixtures, comprising at least one dye of formula and at least one dye from the group of formulae wherein the substituents are defined in the specification.
摘要翻译： 包含至少一种式的染料和至少一种下式基团的染料的染料混合物，其中取代基在说明书中定义。
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公开(公告)号：US07211609B2
公开(公告)日：2007-05-01
申请号：US10512794
申请日：2003-06-12
IPC分类号： C08K5/34 , C08K5/3467
CPC分类号： C09B67/0035
摘要： The invention provides a composition comprising particles of an optionally halogenated phthalocynine (a); from 0.5 to 10% weight, preferably from 2 to 8% by weight, based on the optionally halogenated phthalocyanine (a), or a vinylic or acrylic polymer (b); and from 1 to 15% by weight, preferably from 3 to 10% by weight, based on the optionally halogenated phthalocyanine (a), of an optionally halogenated phthalocyanine (c) which is outside the particles of the optionally halogenated phthalocyanine (a) and is substituted by a group comprising at least 1 hetero atom selected from the group consisting of N, O, S and P and at least 3 carbon atoms. The instant compositions comprising three essential components are surprisingly warpfree in substrate such as partially crystalline plastics, especially those processed by injection moulding. Geometrically identical parts of different colours are obtained.
摘要翻译： 本发明提供包含任选卤代酞菁（a）的颗粒的组合物; 基于任选卤代酞菁（a），或乙烯基或丙烯酸类聚合物（b），为0.5〜10重量％，优选为2〜8重量％。 和基于任选卤代酞菁（a）的1至15重量％，优选3至10重量％的任选卤代酞菁（c），其任选卤代酞菁（a）的颗粒外;和 被包含至少1个选自N，O，S和P的杂原子和至少3个碳原子的基团取代。 包含三种必需组分的本发明组合物在基材中例如部分结晶塑料，特别是通过注射成型加工的那些是令人惊奇地无翘曲的。 获得不同颜色的几何相同部分。
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