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    Process for the simultaneous production of 2-(2-aminoalkoxy)alkanol and morpholine
    2.
    发明授权
    Process for the simultaneous production of 2-(2-aminoalkoxy)alkanol and morpholine 失效
    同时生产2-（2-氨基烷氧基）链烷醇和吗啉的方法

    公开(公告)号：US4508896A

    公开(公告)日：1985-04-02

    申请号：US60266

    申请日：1979-07-25

    Applicant: James H. Templeton

    Inventor： James H. Templeton

    IPC: C07C213/02 ,  C07C217/08 ,  C07D295/023 ,  C07D295/02

    CPC classification number: C07C213/02 ,  C07D295/023

    Abstract: A process for simultaneously producing a 2-(2-aminoalkoxy)alkanol compound and a morpholine compound is disclosed wherein an oxydialkanol is contacted with ammonia in the presence of a catalytically effective amount of a hydrogenation/dehydrogenation catalyst at a temperature of from about 190.degree. C. to about 230.degree. C. and at a pressure ranging from about 700 psig to about 2200 psig, said oxydialkanol having the formula: ##STR1## wherein each R is, independently, a hydrogen or a lower alkyl radical; and recovering said 2-(2-aminoalkoxy)alkanol compound and said morpholine compound from the resulting reaction mixture.

    Abstract translation: 公开了同时制备2-（2-氨基烷氧基）烷醇化合物和吗啉化合物的方法，其中在约190℃的温度下，在催化有效量的氢化/脱氢催化剂存在下，使氧基二醇与氨接触 所述氧基二醇具有下式：其中每个R独立地是氢或低级烷基; R 3是氢或低级烷基; 并从所得反应混合物中回收所述2-（2-氨基烷氧基）烷醇化合物和所述吗啉化合物。

    Secondary isopropyl amine derivatives of polyoxyalkylene diamines and triamines
    3.
    发明授权
    Secondary isopropyl amine derivatives of polyoxyalkylene diamines and triamines 失效
    聚亚氧烷基二胺和三胺的仲异丙基胺衍生物

    公开(公告)号：US4946924A

    公开(公告)日：1990-08-07

    申请号：US264643

    申请日：1988-10-31

    Applicant: George P. Speranza ,  Jiang-Jen Lin ,  James H. Templeton

    Inventor： George P. Speranza ,  Jiang-Jen Lin ,  James H. Templeton

    IPC: C08G65/322 ,  C08G65/331 ,  C08L63/00

    CPC classification number: C08G65/331 ,  C08G65/322 ,  C08L63/00

    Abstract: Secondary isopropylamine terminated polyoxyethylene and/or polyoxypropylene diamines or triamines are formed in a one-step reaction when a polyoxyethylene and/or polyoxypropylene primary diamine or triamine is hydrogenated with hydrogen in the presence of a hydrogenation catalyst, hydrogen and acetone. The secondary isopropylamine terminated polyoxyethylene and/or polyoxypropylene primary diamines or triamines are useful as curing agents for epoxy resins.

    Abstract translation: 当在氢化催化剂，氢气和丙酮存在下，用氢氢化聚氧乙烯和/或聚氧丙烯一级二胺或三胺时，以一步反应形成仲异丙胺封端的聚氧乙烯和/或聚氧丙烯二胺或三胺。 二异丙胺封端的聚氧乙烯和/或聚氧丙烯原二胺或三胺可用作环氧树脂的固化剂。

    Process for the production of cyclohexane by liquid phase hydrogenation of benzene
    5.
    发明授权
    Process for the production of cyclohexane by liquid phase hydrogenation of benzene 失效
    通过苯的液相氢化生产环己烷的方法

    公开(公告)号：US5189233A

    公开(公告)日：1993-02-23

    申请号：US749346

    申请日：1991-08-23

    Applicant: John M. Larkin ,  James H. Templeton ,  Donald H. Champion

    Inventor： John M. Larkin ,  James H. Templeton ,  Donald H. Champion

    IPC: C07C5/10

    CPC classification number: C07C5/10 ,  C07C2101/14 ,  C07C2521/04 ,  C07C2523/72 ,  C07C2523/755 ,  C07C2523/86

    Abstract: Disclosed is an improvement in a process for production of cyclohexane by liquid phase hydrogenation of benzene wherein no diluent is necessary, which comprises contacting benzene and hydrogen in the presence of a mixed catalyst bed comprising a first catalyst which is a less active hydrogenation catalyst selected from elements of Group VIII of the Periodic Table and a second, more active catalyst, comprising a Group VIII metal supported on an oxide, such as, for example, alumina, silica or titania at a temperature of about 40.degree. C. to about 300.degree. C. and pressure sufficient to keep the benzene liquid at the chosen reaction temperature.

    Abstract translation: 公开了通过苯的液相氢化制备环己烷的方法的改进，其中不需要稀释剂，其包括在混合催化剂床的存在下使苯和氢接触，所述混合催化剂床包含第一催化剂，所述第一催化剂是选自 元素周期表第VIII族和第二种更有活性的催化剂，其包含负载在氧化物上的第VIII族金属，例如氧化铝，二氧化硅或二氧化钛，温度为约40℃至约300℃ C.和足以将苯液体保持在所选择的反应温度的压力。

    Preparation of N-alkylpiperazines
    6.
    发明授权
    Preparation of N-alkylpiperazines 失效
    N-烷基哌嗪的制备

    公开(公告)号：US5414087A

    公开(公告)日：1995-05-09

    申请号：US87093

    申请日：1993-07-07

    Applicant: George P. Speranza ,  James H. Templeton

    Inventor： George P. Speranza ,  James H. Templeton

    IPC: C07D295/023 ,  C07D295/03

    CPC classification number: C07D295/023

    Abstract: Disclosed is a one-step method for preparing N-alkylpiperazines which eliminates the initial preparation and isolation of piperazine which comprises reacting a carbonyl compound and an amine in the presence of hydrogen over a metallic hydrogenation-dehydrogenation catalyst from Group VIII of the Periodic Table such as, for example, nickel, copper, cobalt, chromium, palladium, platinum or ruthenium, alone or in combination with other Group VIII metals or transition metals selected from the group consisting of manganese, iron, zinc, copper and chromium.

    Abstract translation: 公开了一种用于制备N-烷基哌嗪的一步法，其消除了哌嗪的初始制备和分离，其包括在氢气存在下使羰基化合物和胺在元素周期表第VIII族的金属氢化脱氢催化剂中反应， 作为例如镍，铜，钴，铬，钯，铂或钌，单独或与其它选自锰，铁，锌，铜和铬的第Ⅷ族金属或过渡金属组合。

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