Amorphous copolyamide article of manufacture with moisture-insensitive
oxygen barrier properties
    1.
    发明授权
    Amorphous copolyamide article of manufacture with moisture-insensitive oxygen barrier properties 失效
    无定形共聚酰胺制品具有不透湿氧阻隔性能

    公开(公告)号:US4826955A

    公开(公告)日:1989-05-02

    申请号:US146673

    申请日:1988-01-21

    CPC分类号: C08G69/36

    摘要: An article of composition which has a barrier layer of an amorphous nylon copolymer. The copolymer is polymerized from (A) a lactam or aminoalkanoic acid, such as caprolactam, (B) an aralkylene or cycloalkylene diamine, such as m-xylylenediamine, and (C) one or more aromatic diacids, such as isophthalic acid and terephthalic acid. The copolymer barrier layer exhibits excellent oxygen barrier resistance when exposed to moisture.

    摘要翻译: 一种具有无定形尼龙共聚物阻挡层的组合物。 共聚物由(A)内酰胺或氨基链烷酸如己内酰胺,(B)亚芳基或亚环烷基二胺如间苯二甲胺和(C)一种或多种芳族二酸例如间苯二甲酸和对苯二甲酸 。 当暴露于水分时,共聚物阻隔层表现出优异的耐氧屏障性。

    Chain extension of polyethylene terephthalate with polyacyllactams
    2.
    发明授权
    Chain extension of polyethylene terephthalate with polyacyllactams 失效
    聚对苯二甲酸乙二醇酯与聚酰基内酰胺的延伸

    公开(公告)号:US4857603A

    公开(公告)日:1989-08-15

    申请号:US161927

    申请日:1988-02-29

    CPC分类号: C08G63/6854 C08G69/44

    摘要: High molecular weight polyethylene terephthalate resins in which there is used a chain extending agent having the formula: ##STR1## wherein A is any hydrocarbon group having the necessary number of available valences to bound itself to all of the acyl groups of the compound, Y is at least 1 and x is an integer of from 6 to 12.Preferably, the chain extending agent is a bisacyllactam, such as terephthaloyl bislaurolactam.The chain extending agent can be used in combination with a carboxyl reactive compound.

    摘要翻译: 高分子量聚对苯二甲酸乙二醇酯树脂,其中使用具有下式的扩链剂:其中A是具有必要数量的可用价数的任何烃基,以将其本身与化合物的所有酰基结合,Y是 至少1和x是6至12的整数。优选地,扩链剂是双链酰基内酰胺,例如对苯二甲酰双十二内酰胺。 链增长剂可以与羧基反应性化合物组合使用。

    Thermoplastic compositions containing acyllactam graft linkages
    4.
    发明授权
    Thermoplastic compositions containing acyllactam graft linkages 失效
    含有酰基内酰胺接枝键的热塑性组合物

    公开(公告)号:US4847322A

    公开(公告)日:1989-07-11

    申请号:US111469

    申请日:1987-10-22

    摘要: The present invention is directed to a reaction product of a polymer and a graft linking agent, resulting in a modified polymer especially suited for blending with one or more second thermoplastic polymers.The modified polymers of the invention comprise a reaction product of the polymer and an acyllactam having the general formula: ##STR1## wherein L is a linking moiety that is capable of a thermal or radical-initiated addition reaction with said polymer; and preferably ##STR2## or N.sub.3 SO.sub.2 --R.sub.6 -- wherein R.sub.1, R.sub.2 and R.sub.3 are the same or different and comprise at least one of the following moieties: Hydrogen, alkyl, aryl, halo, cyano, carboxylic acid, ester, amide, imide, or acyllactam, and wherein R.sub.4 is -- (valence bond) or ##STR3## with R.sub.5 being hydrogen, alkyl, or aryl, and R.sub.6 being alkylene or arylene; and wherein the acyllactam portion of the grafting agent has an alkyl chain length, n, of about 2 to 11 carbon atoms, preferably about 3 to 11 carbon atoms, most preferably about 5 to 11 carbon atoms.The reaction product of the first polymer and grafting agent itself is useful as a structural resin, and does not have to be blended with a second polymer. However, it also demonstrates adhesive properties useful in laminations to other polymers, coextrusions with other polymers, metal bonding, and the like, and could be used in applications such as these. The reaction product is a stable product that may be stored for further use. Alternatively, it may be desirable for some applications to blend all the components, a first polymer, grafting agent, and a second thermoplastic polymer, either together or sequentially.

    摘要翻译: 本发明涉及聚合物和接枝连接剂的反应产物,得到特别适于与一种或多种第二热塑性聚合物共混的改性聚合物。 本发明的改性聚合物包含具有以下通式的聚合物和酰基内酰胺的反应产物:其中L是能够与所述聚合物进行热或自由基引发的加成反应的连接部分; 并且优选地,其中R 1,R 2和R 3相同或不同,并且包含至少一个以下部分:氢,烷基,芳基,卤素,氰基,羧酸,酯,酰胺,酰亚胺, 或酰基内酰胺,并且其中R 4为 - (价键)或R 5为氢,烷基或芳基,R 6为亚烷基或亚芳基; 并且其中所述接枝剂的酰基内酰胺部分具有约2至11个碳原子,优选约3至11个碳原子,最优选约5至11个碳原子的烷基链长度n。 第一聚合物和接枝剂本身的反应产物可用作结构树脂,并且不必与第二聚合物共混。 然而,它还表现出对其它聚合物的叠片有用的粘合性能,与其它聚合物的共挤出物,金属粘合等,并且可以用于这些应用中。 反应产物是稳定的产品,可以储存以供进一步使用。 或者,一些应用可能期望一起或顺序地将所有组分,第一聚合物,接枝剂和第二热塑性聚合物共混。