公开(公告)号：US07390439B2

公开(公告)日：2008-06-24

申请号：US11465627

申请日：2006-08-18

Applicant: Adam Pron ,  Bruno Dufour ,  Patrice Rannou ,  Jean-Pierre Travers

Inventor： Adam Pron ,  Bruno Dufour ,  Patrice Rannou ,  Jean-Pierre Travers

IPC: H01B1/12

CPC classification number: C08L79/02 ,  C08G73/0266 ,  C08K5/42 ,  C08K5/521 ,  C08K5/5317 ,  Y10T428/31533 ,  Y10T428/31786

Abstract: The invention relates to the use of sulphonic, phosphonic and phosphoric acids functionalized with plasticizing groups as dopants for conductive polyaniline films and for conductive polyaniline-based composite materials. These acids correspond to the following formula (I): in which: R1 represents —SO2(OH) or —PO(OH)2 or —OPO(OH)2; the R2 groups, which are identical or different, represent a hydrocarbonaceous group, such as a 2-ethylhexyl, butoxyethyl or isopropylbenzyl group; R3 and R4 independently represent a direct bond or a hydrocarbonaceous group, such as a methylene group.

Abstract translation: 本发明涉及用塑化基团官能化的磺酸，膦酸和磷酸作为导电聚苯胺膜和导电聚苯胺类复合材料的掺杂剂的用途。 这些酸对应于下式（I）：其中：R 1表示-SO 2（OH）或-PO（OH）2 或-OPO（OH）2; R 2 2基团相同或不同，表示烃基，如2-乙基己基，丁氧基乙基或异丙基苄基; R 3和R 4独立地表示直接键或烃基，例如亚甲基。

公开(公告)号：US20060278854A1

公开(公告)日：2006-12-14

申请号：US11465627

申请日：2006-08-18

Applicant: Adam Pron ,  Bruno Dufour ,  Patrice Rannou ,  Jean-Pierre Travers

Inventor： Adam Pron ,  Bruno Dufour ,  Patrice Rannou ,  Jean-Pierre Travers

IPC: H01B1/12

CPC classification number: C08L79/02 ,  C08G73/0266 ,  C08K5/42 ,  C08K5/521 ,  C08K5/5317 ,  Y10T428/31533 ,  Y10T428/31786

Abstract: The invention relates to the use of sulphonic, phosphonic and phosphoric acids functionalized with plasticizing groups as dopants for conductive polyaniline films and for conductive polyaniline-based composite materials. These acids correspond to the following formula (I): in which: R1 represents —SO2(OH) or —PO(OH)2 or —OPO(OH)2; the R2 groups, which are identical or different, represent a hydrocarbonaceous group, such as a 2-ethylhexyl, butoxyethyl or isopropylbenzyl group; R3 and R4 independently represent a direct bond or a hydrocarbonaceous group, such as a methylene group.

Abstract translation: 本发明涉及用塑化基团官能化的磺酸，膦酸和磷酸作为导电聚苯胺膜和导电聚苯胺类复合材料的掺杂剂的用途。 这些酸对应于下式（I）：其中：R 1表示-SO 2（OH）或-PO（OH）2 或-OPO（OH）2; R 2 2基团相同或不同，表示烃基，如2-乙基己基，丁氧基乙基或异丙基苄基; R 3和R 4独立地表示直接键或烃基，例如亚甲基。

公开(公告)号：US07101495B2

公开(公告)日：2006-09-05

申请号：US10264621

申请日：2002-10-04

Applicant: Adam Pron ,  Bruno Dufour ,  Patrice Rannou ,  Jean-Pierre Travers

Inventor： Adam Pron ,  Bruno Dufour ,  Patrice Rannou ,  Jean-Pierre Travers

IPC: H01B1/12

CPC classification number: C08L79/02 ,  C08G73/0266 ,  C08K5/42 ,  C08K5/521 ,  C08K5/5317 ,  Y10T428/31533 ,  Y10T428/31786

Abstract: The invention relates to the use of sulphonic, phosphonic and phosphoric acids functionalized with plasticizing groups as dopants for conductive polyaniline films and for conductive polyaniline-based composite materials. These acids correspond to the following formula (I): in which: R1 represents —SO2(OH) or —PO(OH)2 or —OPO(OH)2; the R2 groups, which are identical or different, represent a hydrocarbonaceous group, such as a 2-ethylhexyl, butoxyethyl or isopropylbenzyl group; R3 and R4 independently represent a direct bond or a hydrocarbonaceous group, such as a methylene group.

Abstract translation: 本发明涉及用塑化基团官能化的磺酸，膦酸和磷酸作为导电聚苯胺膜和导电聚苯胺类复合材料的掺杂剂的用途。 这些酸对应于下式（I）：其中：R 1表示-SO 2（OH）或-PO（OH）2 或-OPO（OH）2; R 2 2基团相同或不同，表示烃基，如2-乙基己基，丁氧基乙基或异丙基苄基; R 3和R 4独立地表示直接键或烃基，例如亚甲基。

公开(公告)号：US06753041B2

公开(公告)日：2004-06-22

申请号：US10312890

申请日：2002-12-31

Applicant: Adam Pron ,  Jean-Pierre Travers ,  Jacek Niziol

Inventor： Adam Pron ,  Jean-Pierre Travers ,  Jacek Niziol

IPC: B05D512

CPC classification number: H01B1/128

Abstract: The invention relates to a method of preparing a conductive composite material, consisting of performing at least one cycle of deposition comprising the following steps: (a) putting an insulating porous substrate (1) in contact with a solution of a conductive polymer such as polyaniline in a volatile organic solvent such as trifluoroacetic acid, and (b) eliminating the organic solvent by evaporation, for forming a deposit of conductive polymer (5) in the pores (3) of the porous substrate.

Abstract translation: 本发明涉及一种制备导电复合材料的方法，包括进行至少一个沉积循环，包括以下步骤：（a）将绝缘多孔基材（1）与导电聚合物如聚苯胺的溶液接触 在挥发性有机溶剂如三氟乙酸中，和（b）通过蒸发除去有机溶剂，用于在多孔基材的孔（3）中形成导电聚合物（5）的沉积物。

公开(公告)号：US07014794B1

公开(公告)日：2006-03-21

申请号：US10030584

申请日：2000-07-12

Applicant: Thomas Olinga ,  Adam Pron ,  Jean-Pierre Travers

Inventor： Thomas Olinga ,  Adam Pron ,  Jean-Pierre Travers

IPC: H01B1/12 ,  H01B1/20 ,  B32B5/00

CPC classification number: C07C309/77 ,  Y10T428/29 ,  Y10T428/2924 ,  Y10T428/2998

Abstract: The present invention concerns the use of sulphonic and phosphonic acids, functionalised with plastisizers, as dopants for polyaniline conductor films and polyaniline-based conductive composite materials.These acids meet the following formula: in which: R1 represents —SO3H or PO3H2 R2 is a linear or branched alkyl group and m equals 1 or 2, or R2 is a group having the formula: in which R1 is such as defined above and n is a whole number ranging from 1 to 16, and m equals 1.

Abstract translation: 本发明涉及使用功能化增塑剂的磺酸和膦酸作为聚苯胺导体膜和聚苯胺类导电复合材料的掺杂剂。 这些酸符合下列公式：其中：R 1表示-SO 3 H或PO 3 H 2 H 2， R 2是直链或支链烷基，m等于1或2，或R 2是具有下式的基团：其中R 1〜 >如上所定义，n是1到16的整数，m等于1。