Color-stabilized electrochromic devices
    1.
    发明授权
    Color-stabilized electrochromic devices 有权
    颜色稳定的电致变色装置

    公开(公告)号:US06876478B2

    公开(公告)日:2005-04-05

    申请号:US10781050

    申请日:2004-02-18

    IPC分类号: C09K9/02 G02F1/15

    摘要: An electrochromic medium for use in a normally operating electrochromic device comprising an anodic material and a cathodic material wherein both of the anodic and cathodic materials are electroactive and at least one of the anodic and cathodic materials is electrochromic, an additive, and means associated with the additive for maintaining a colorless or nearly colorless electrochromic medium while the electrochromic medium is in a high transmission state relative to an electrochromic medium without the additive.

    摘要翻译: 一种用于正常操作的电致变色装置的电致变色介质,其包括阳极材料和阴极材料,其中阳极和阴极材料都是电活性的,阳极和阴极材料中的至少一种是电致变色的,添加剂和与 用于维持无色或几乎无色的电致变色介质的添加剂,而电致变色介质相对于没有添加剂的电致变色介质处于高透射状态。

    Substituted metallocenes and electrochromic media and devices comprising the same
    2.
    发明授权
    Substituted metallocenes and electrochromic media and devices comprising the same 有权
    取代的金属茂和电致变色介质以及包含其的装置

    公开(公告)号:US06594066B2

    公开(公告)日:2003-07-15

    申请号:US10121760

    申请日:2002-04-22

    IPC分类号: G02F101

    CPC分类号: G02F1/1521 C07F17/02 C09K9/02

    摘要: An electrochromic device comprising at least one substantially transparent substrate having an electrically conductive material associated therewith, and an electrochromic medium which comprises a solvent, a cathodic material, and an anodic electrochromic material represented by the formula: wherein R1-R10 are the same or different and at least three of R1-R10 are the same or different and comprise a straight or branched alkyl, aryl, alkaryl, or aralkyl group containing approximately 1 to approximately 40 carbon atom(s), and/or a silyl or siloxyl group containing approximately 1 to approximately 40 silicon atom(s), wherein the carbon or silicon atom(s) may be a linking group to, or part of, one or more functional groups comprising nitrites; nitro constituents; sulfoxides; sulfonates; phosphonium constituents; phosphonates; phosphonites; ammonium constituents; viologens, including bipyridinyl constituents; carbonyls, including carbonates, carbamates; ketones; esters; and amides; ethers, including polyethers; amines, including tertiary amines; alkenes; alkynes; and mixtures thereof; wherein any remainder of R1-R10 comprise H; and wherein M comprises a transition metal.

    摘要翻译: 一种电致变色装置,包括至少一个具有与之相关的导电材料的基本上透明的基底,以及电致变色介质,其包含溶剂,阴极材料和由下式表示的阳极电致变色材料:其中R1-R10相同或不同 并且R1-R10中的至少三个相同或不同,并且包含含有约1至约40个碳原子的直链或支链烷基,芳基,烷芳基或芳烷基,和/或含有约1至约40个碳原子的甲硅烷基或硅氧烷基 1至约40个硅原子,其中碳或硅原子可以是与一个或多个包含亚硝酸根的官能团的一部分或部分的连接基团; 硝基成分; 亚砜 磺酸盐; 鏻成分; 膦酸盐 亚膦酸盐 铵成分; 紫罗兰,包括联吡啶成分; 羰基,包括碳酸酯,氨基甲酸酯; 酮类 酯类 和酰胺; 醚,包括聚醚; 胺,包括叔胺; 烯烃 炔烃 及其混合物; 其中R 1 -R 10的任何其余部分包括H; 并且其中M包含过渡金属。

    Color-stabilized electrochromic devices
    3.
    发明授权
    Color-stabilized electrochromic devices 有权
    颜色稳定的电致变色装置

    公开(公告)号:US06486998B2

    公开(公告)日:2002-11-26

    申请号:US10035721

    申请日:2001-10-25

    IPC分类号: G02F115

    摘要: An electrochromic medium for use in a normally operating electrochromic device comprising an anodic material and a cathodic material wherein both of the anodic and cathodic materials are electroactive and at least one of the anodic and cathodic materials is electrochromic, an additive, and means associated with the additive for maintaining a colorless or nearly colorless electrochromic medium while the electrochromic medium is in a high transmission state relative to an electrochromic medium without the additive.

    摘要翻译: 一种用于正常操作的电致变色装置的电致变色介质,其包括阳极材料和阴极材料,其中阳极和阴极材料都是电活性的,阳极和阴极材料中的至少一种是电致变色的,添加剂和与 用于维持无色或几乎无色的电致变色介质的添加剂,而电致变色介质相对于没有添加剂的电致变色介质处于高透射状态。

    Anodic electroactive materials having a solublizing moiety
    4.
    发明授权
    Anodic electroactive materials having a solublizing moiety 有权
    具有溶解部分的阳极电活性材料

    公开(公告)号:US06496294B2

    公开(公告)日:2002-12-17

    申请号:US09907047

    申请日:2001-07-17

    IPC分类号: G02F115

    摘要: Anodic electrochromic materials for use in an electrochromic device comprising a first moiety, wherein the first moiety comprises a metallocene or a substituted metallocene, and a second moiety, wherein the second moiety comprises at least one constituent which serves to increase the solubility of the first moiety in an associated solvent relative to solubility of the first moiety without the second moiety.

    摘要翻译: 用于包含第一部分的电致变色装置中的阳极电致变色材料,其中所述第一部分包含茂金属或取代的茂金属和第二部分,其中第二部分包含至少一种用于增加第一部分的溶解度的成分 在相关溶剂中相对于没有第二部分的第一部分的溶解度。

    Electroactive materials and beneficial agents having a solubilizing moiety
    5.
    发明授权
    Electroactive materials and beneficial agents having a solubilizing moiety 有权
    具有增溶部分的电活性物质和有益剂

    公开(公告)号:US06445486B1

    公开(公告)日:2002-09-03

    申请号:US09724118

    申请日:2000-11-28

    IPC分类号: G02F115

    摘要: An electrochromic medium for use in an electrochromic device comprising: at least one solvent; a cathodic electroactive material; an anodic electroactive material; an optional beneficial agent; wherein at least one of the cathodic and anodic electroactive materials is electrochromic; and wherein at least one of the cathodic electroactive material, anodic electroactive material, and/or optional beneficial agent is associated with a solubilizing moiety which serves to increase solubility of the associated material or agent relative to the same without the solubilizing moiety.

    摘要翻译: 一种用于电致变色装置的电致变色介质,包括:至少一种溶剂; 阴极电活性材料; 阳极电活性材料; 一种可选的有益药剂; 其中阴极和阳极电活性材料中的至少一种是电致变色的; 并且其中所述阴极电活性材料,阳极电活性材料和/或任选的有益试剂中的至少一种与增溶部分相关联,所述增溶部分用于增加相关材料或试剂相对于没有增溶部分的溶解度。

    Substituted metallocenes for use as anodic electrochromic materials, and electrochromic media and devices comprising the same
    6.
    发明授权
    Substituted metallocenes for use as anodic electrochromic materials, and electrochromic media and devices comprising the same 有权
    用作阳极电致变色材料的取代的金属茂,以及电致变色介质和包含其的器件

    公开(公告)号:US06392783B1

    公开(公告)日:2002-05-21

    申请号:US09677689

    申请日:2000-10-02

    IPC分类号: G02F115

    CPC分类号: G02F1/1521 C07F17/02 C09K9/02

    摘要: An electrochromic device comprising at least one substantially transparent substrate having an electrically conductive material associated therewith, and an electrochromic medium which comprises a solvent, a cathodic material, and an anodic electrochromic material represented by the formula: wherein R1-R10 are the same or different and at least three of R1-R10 are the same or different and comprise a straight or branched alkyl, aryl, alkaryl, or aralkyl group containing approximately 1 to approximately 40 carbon atom(s), and/or a silyl or siloxyl group containing approximately 1 to approximately 40 silicon atom(s), wherein the carbon or silicon atom(s) may be a linking group to, or part of, one or more functional groups comprising nitrites; nitro constituents; sulfoxides; sulfonates; phosphonium constituents; phosphonates; phosphonites; ammonium constituents; viologens, including bipyridinyl constituents; carbonyls, including carbonates, carbamates; ketones; esters; and amides; ethers, including polyethers; amines, including tertiary amines; alkenes; alkynes; and mixtures thereof; wherein any remainder of R1-R10 comprise H; and wherein M comprises a transition metal.

    摘要翻译: 一种电致变色装置,包括至少一个具有与之相关的导电材料的基本上透明的基底,以及电致变色介质,其包含溶剂,阴极材料和由下式表示的阳极电致变色材料:其中R1-R10相同或不同 并且R1-R10中的至少三个相同或不同,并且包含含有约1至约40个碳原子的直链或支链烷基,芳基,烷芳基或芳烷基,和/或含有约1至约40个碳原子的甲硅烷基或硅氧烷基 1至约40个硅原子,其中碳或硅原子可以是与一个或多个包含亚硝酸根的官能团的一部分或部分的连接基团; 硝基成分; 亚砜 磺酸盐; 鏻成分; 膦酸盐 亚膦酸盐 铵成分; 紫罗兰,包括联吡啶成分; 羰基,包括碳酸酯,氨基甲酸酯; 酮类 酯类 和酰胺; 醚,包括聚醚; 胺,包括叔胺; 烯烃 炔烃 及其混合物; 其中R 1 -R 10的任何其余部分包括H; 并且其中M包含过渡金属。

    Color-stabilized electrochromic devices
    7.
    发明授权
    Color-stabilized electrochromic devices 有权
    颜色稳定的电致变色装置

    公开(公告)号:US07265888B2

    公开(公告)日:2007-09-04

    申请号:US11098029

    申请日:2005-04-01

    IPC分类号: G02F1/15

    摘要: An electrochromic device comprising: (a) a first substantially transparent substrate having an electrically conductive material associated therewith; (b) a second substrate having an electrically conductive material associated therewith; (c) an electrochromic medium contained within a chamber positioned between the first and second substrates which comprises: (1) a solvent; (2) a cathodic electroactive material; (3) an anodic electroactive material, wherein at least one of the anodic and cathodic electroactive materials is electrochromic; and (4) a color-stabilizing additive, wherein the color-stabilizing additive is electroactive within a normal operating voltage of the electrochromic device; and (d) means associated with the color-stabilizing additive for maintaining an at least nearly colorless electrochromic device while the electrochromic device is in an open circuit and/or zero potential state relative to the same device without the color-stabilizing additive.

    摘要翻译: 一种电致变色装置,包括:(a)具有与其相关联的导电材料的第一基本上透明的基底; (b)具有与其相关联的导电材料的第二基板; (c)包含在位于第一和第二基板之间的室内的电致变色介质,其包括:(1)溶剂; (2)阴极电活性材料; (3)阳极电活性材料,其中阳极和阴极电活性材料中的至少一种是电致变色的; 和(4)颜色稳定添加剂,其中所述颜色稳定添加剂在所述电致变色装置的正常工作电压内是电活性的; 和(d)与颜色稳定添加剂相关联的装置,用于在电色变装置相对于没有颜色稳定添加剂的相同装置处于开路和/或零电势状态时,保持至少几乎无色的电致变色装置。

    Color-stabilized electrochromic devices

    公开(公告)号:US06876477B2

    公开(公告)日:2005-04-05

    申请号:US10753110

    申请日:2004-01-07

    IPC分类号: G02F1/15 G02F1/153 H01B1/00

    摘要: An electrochromic device comprising: (a) a first substantially transparent substrate having an electrically conductive material associated therewith; (b) a second substrate having an electrically conductive material associated therewith; (c) an electrochromic medium contained within a chamber positioned between the first and second substrates which comprises: (1) a solvent; (2) a cathodic electroactive material; (3) an anodic electroactive material, wherein at least one of the anodic and cathodic electroactive materials is electrochromic; and (4) a color-stabilizing additive, wherein the color-stabilizing additive is electroactive within a normal operating voltage of the electrochromic device; and (d) means associated with the color-stabilizing additive for maintaining an at least nearly colorless electrochromic device while the electrochromic device is in an open circuit and/or zero potential state relative to the same device without the color-stabilizing additive.

    Color-stabilized electrochromic devices

    公开(公告)号:US06697185B2

    公开(公告)日:2004-02-24

    申请号:US10208525

    申请日:2002-07-30

    IPC分类号: G02F115

    摘要: An electrochromic device comprising: (a) a first substantially transparent substrate having an electrically conductive material associated therewith; (b) a second substrate having an electrically conductive material associated therewith; (c) an electrochromic medium contained within a chamber positioned between the first and second substrates which comprises: (1) a solvent; (2) a cathodic electroactive material; (3) an anodic electroactive material, wherein at least one of the anodic and cathodic electroactive materials is electrochromic; and (4) a color-stabilizing additive, wherein the color-stabilizing additive is electroactive within a normal operating voltage of the electrochromic device; and (d) means associated with the color-stabilizing additive for maintaining an at least nearly colorless electrochromic device while the electrochromic device is in an open circuit and/or zero potential state relative to the same device without the color-stabilizing additive.