公开(公告)号：US5954944A

公开(公告)日：1999-09-21

申请号：US884813

申请日：1997-06-30

申请人： Yanping Zhang ,  Yulin Shi ,  Zhenlin Xiong ,  Jianwen Shi ,  Hong Nie ,  Yahua Shi ,  Yigin Zhu ,  Zhihai Hu

发明人： Yanping Zhang ,  Yulin Shi ,  Zhenlin Xiong ,  Jianwen Shi ,  Hong Nie ,  Yahua Shi ,  Yigin Zhu ,  Zhihai Hu

IPC分类号： B01J23/888 ,  B01J27/132 ,  B01J29/076 ,  B01J29/16 ,  B01J29/26 ,  C10G45/08 ,  C10G47/16 ,  C10G47/18 ,  C10G65/12 ,  C10G69/02

CPC分类号： C10G65/12 ,  B01J23/888 ,  B01J27/132 ,  C10G45/08 ,  C10G47/18

摘要： A process for producing middle distillates by hydrocracking a heavy distillate oil under middle pressure uses a hydrofining catalyst and a hydrocracking catalyst in series and once-through operation. The once-through volume conversion to 350.degree. C.--products is up to 80 vol. %. The yield and selectivity of middle distillates are greater than 40 wt % and less than 50 wt %, respectively. The process is particularly suited to treat heavy distillate oil having the nitrogen content of up to 1500 ppmw, the sulfur content of up to 3.5 wt % and dry point in the boiling range of higher than 500.degree. C. to produce the feed for reforming process, jet fuel, the low sulfur content diesel, the feed for catalytic cracker and the feed for producing ethylene.

摘要翻译： 通过在中等压力下加氢裂解重质馏出油生产中间馏分的方法使用加氢精制催化剂和加氢裂化催化剂串联和一次通过操作。 直接转化成350℃的产品可达80体积％。 ％。 中间馏分的产率和选择性分别大于40重量％且小于50重量％。 该方法特别适用于处理氮含量高达1500ppmw，硫含量高达3.5wt％和沸点范围高于500℃的干馏点的重馏分油，以产生重整过程的进料 ，喷气燃料，低硫含量柴油，催化裂化装置的进料和生产乙烯的进料。

公开(公告)号：US5972832A

公开(公告)日：1999-10-26

申请号：US884815

申请日：1997-06-30

申请人： Jianwen Shi ,  Hong Nie ,  Yahua Shi ,  Yulin Shi ,  Yanping Zhang ,  Dadong Li

发明人： Jianwen Shi ,  Hong Nie ,  Yahua Shi ,  Yulin Shi ,  Yanping Zhang ,  Dadong Li

IPC分类号： B01J29/076 ,  B01J23/888 ,  B01J27/132 ,  B01J29/16 ,  B01J29/26 ,  B01J29/48 ,  B01J29/78 ,  C10G45/12 ,  C10G47/18 ,  B01J23/40 ,  B01J21/08 ,  B01J27/06 ,  B01J29/06

CPC分类号： C10G47/18 ,  B01J23/888 ,  B01J27/132

摘要： The present invention relates to a hydrocracking catalyst containing nickel, tungsten, fluorine, zeolite as well as alumina, said catalyst is composed of, based on the total weight of the catalyst, 0.5-5.0 wt % fluorine, 2.5-6.0 wt % nickel oxide, 10-38 wt % tungsten oxide, and a catalyst carrier. Said carrier is composed of 20-90 wt % alumina and 10-90 wt % zeolite wherein the zeolite is mesopore or macropore zeolite of an acidity strength value 1.0-2.0 mmol/g determined by NH.sub.3 -TPD, the alumina is the alumina of an acidity strength value 0.5-0.8 mmol/g determined by NH.sub.3 -TPD. Said catalyst possesses good desulfurization activity, denitrogenation activity, and higher selectivity with respect to middle distillates than that of the prior art.

摘要翻译： 本发明涉及含有镍，钨，氟，沸石以及氧化铝的加氢裂化催化剂，所述催化剂由催化剂的总重量计为0.5-5.0重量％的氟，2.5-6.0重量％的氧化镍 ，10-38重量％的氧化钨和催化剂载体。 所述载体由20-90重量％的氧化铝和10-90重量％的沸石组成，其中沸石是由NH 3 -TPD测定的酸度强度值为1.0-2.0毫摩尔/克的中孔或大孔沸石，氧化铝为 NH3-TPD测定酸度强度值为0.5-0.8 mmol / g。 所述催化剂具有比现有技术更好的脱硫活性，脱氮活性和相对于中间馏分的更高选择性。