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    Mercury removal sorbents
    3.
    发明授权
    Mercury removal sorbents 有权
    除汞吸附剂

    公开(公告)号：US09295984B2

    公开(公告)日：2016-03-29

    申请号：US13834266

    申请日：2013-03-15

    申请人： Gokhan Alptekin

    发明人： Gokhan Alptekin

    IPC分类号： B01J20/02 ,  B01J37/04 ,  B01J37/22 ,  B01J37/24 ,  B01J27/08 ,  B01J27/10 ,  B01J27/128 ,  B01J27/132 ,  B01J35/00 ,  B01J35/10 ,  B01J20/04 ,  B01J20/08 ,  B01J20/12 ,  B01J20/28 ,  B01J20/10

    CPC分类号： B01J37/04 ,  B01J20/0222 ,  B01J20/0237 ,  B01J20/041 ,  B01J20/046 ,  B01J20/08 ,  B01J20/103 ,  B01J20/12 ,  B01J20/28004 ,  B01J20/28057 ,  B01J27/08 ,  B01J27/10 ,  B01J27/128 ,  B01J27/132 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/22 ,  B01J37/24

    摘要： Sorbents and methods of using them for removing mercury from flue gases over a wide range of temperatures are disclosed. Sorbent materials of this invention comprise oxy- or hydroxyl-halogen (chlorides and bromides) of manganese, copper and calcium as the active phase for Hg0 oxidation, and are dispersed on a high surface porous supports. In addition to the powder activated carbons (PACs), this support material can be comprised of commercial ceramic supports such as silica (SiO2), alumina (Al2O3), zeolites and clays. The support material may also comprise of oxides of various metals such as iron, manganese, and calcium. The non-carbon sorbents of the invention can be easily injected into the flue gas and recovered in the Particulate Control Device (PCD) along with the fly ash without altering the properties of the by-product fly ash enabling its use as a cement additive. Sorbent materials of this invention effectively remove both elemental and oxidized forms of mercury from flue gases and can be used at elevated temperatures. The sorbent combines an oxidation catalyst and a sorbent in the same particle to both oxidize the mercury and then immobilize it.

    摘要翻译： 公开了一种吸附剂和使用它们在宽范围的温度下从烟道气中去除汞的方法。 本发明的吸附剂材料包含锰，铜和钙的氧化或羟基 - 卤素（氯化物和溴化物）作为HgO氧化的活性相，并且分散在高表面多孔载体上。 除了粉末活性炭（PAC）之外，该载体材料可以由市售的陶瓷载体如二氧化硅（SiO 2），氧化铝（Al 2 O 3），沸石和粘土组成。 载体材料还可以包含各种金属如铁，锰和钙的氧化物。 本发明的非碳吸附剂可以容易地注入烟气中并与粉煤灰一起回收到颗粒控制装置（PCD）中，而不改变副产物飞灰的性质，使其能够用作水泥添加剂。 本发明的吸附剂材料有效地从烟道气中除去元素和氧化形式的汞，并且可以在高温下使用。 吸附剂将氧化催化剂和吸附剂结合在相同的颗粒中，以使氧化汞，然后固定。

    Method for synthesis of lactic acid and its derivatives
    8.
    发明授权
    Method for synthesis of lactic acid and its derivatives 有权
    乳酸及其衍生物的合成方法

    公开(公告)号：US08835670B2

    公开(公告)日：2014-09-16

    申请号：US13727589

    申请日：2012-12-26

    申请人： Microvast New Materials (Huzhou) Co., Ltd.

    发明人： Xiaoping Zhou ,  Rui Bi

    IPC分类号： C07C69/68 ,  C07C51/00

    CPC分类号： C07C51/00 ,  B01J27/08 ,  B01J27/125 ,  B01J27/132 ,  B01J27/135 ,  B01J27/138 ,  C01F7/56 ,  C01G3/05 ,  C01G9/04 ,  C01G19/00 ,  C01G19/06 ,  C01G19/08 ,  C01G30/007 ,  C01G37/04 ,  C01G51/085 ,  C07C67/00 ,  C07C59/08 ,  C07C69/68

    摘要： A method for synthesis of lactic acid and its derivatives is provided. First, a mixture is prepared, which includes: at least one carbohydrate-containing raw material, at least one alcohol, at least one composite catalyst containing metal chloride(s) (MCln) and tin-containing compound(s), and at least one solvent, wherein M is selected from a group consisting of Li+, Na+ K+, Mg2+, Ca2+, Sr2+, Ga3+, In3+, Sb3+, Bi3+, Cr3+, Mn2+, Fe2+, Co2+, Ni2+, Zn2+, and n represents 1, 2 or 3. Then, the mixture is heated to obtain lactic acid and its derivatives. By using the above catalyst and method, it is capable of converting carbohydrate-containing raw material to lactic acid and its derivatives directly in a more efficient and economical way.

    摘要翻译： 提供了一种合成乳酸及其衍生物的方法。 首先，制备混合物，其包括：至少一种含碳水化合物的原料，至少一种醇，至少一种含有金属氯化物（MCln）和含锡化合物的复合催化剂，至少 一种溶剂，其中M选自Li +，Na + K +，Mg2 +，Ca2 +，Sr2 +，Ga3 +，In3 +，Sb3 +，Bi3 +，Cr3 +，Mn2 +，Fe2 +，Co2 +，Ni2 +，Zn2 +，n表示1,2或 然后，将混合物加热以获得乳酸及其衍生物。 通过使用上述催化剂和方法，能够以更有效和经济的方式将含碳水化合物的原料直接转化成乳酸及其衍生物。