公开(公告)号：US09156927B2

公开(公告)日：2015-10-13

申请号：US13642851

申请日：2011-04-22

申请人： Mingzhi Gao ,  Changxiu Li ,  Haitao Liu ,  Xiaofan Zhang ,  Jianhua Chen ,  Jing Ma ,  Xiaoxia Cai ,  Xianzhong Li ,  Jixing Ma

发明人： Mingzhi Gao ,  Changxiu Li ,  Haitao Liu ,  Xiaofan Zhang ,  Jianhua Chen ,  Jing Ma ,  Xiaoxia Cai ,  Xianzhong Li ,  Jixing Ma

IPC分类号： B01J21/00 ,  B01J23/00 ,  B01J25/00 ,  B01J29/00 ,  B01J31/00 ,  B01J37/00 ,  C08F4/02 ,  C08F4/60 ,  C08F110/06

CPC分类号： C08F110/06 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/651

摘要： A catalyst component for olefin polymerization comprising magnesium, titanium, halogen and electron donor, wherein the electron donor is selected from at least one of the diol diester compounds, when the diol diester comprised contains a certain amount of isomer with Fischer projection formula as shown in Formula (II), the activity and stereospecificity of the catalyst are greatly improved, especially in the production of polymers with high melt index, the isotactic index of the obtained polymers is improved substantially.

摘要翻译： 一种用于烯烃聚合的催化剂组分，包括镁，钛，卤素和电子给体，其中当二醇二酯包含含有一定量的具有Fischer投影式的异构体时，电子给体选自至少一种二醇二酯化合物，如 式（II）中，催化剂的活性和立体定向性大大提高，特别是在生产具有高熔体指数的聚合物的情况下，得到的聚合物的全同立构指数得到显着提高。

公开(公告)号：US20130041120A1

公开(公告)日：2013-02-14

申请号：US13642851

申请日：2011-04-22

申请人： Mingzhi Gao ,  Changxiu Li ,  Haitao Liu ,  Xiaofan Zhang ,  Jianhua Chen ,  Jing Ma ,  Xiaoxia Cai ,  Xianzhong Li ,  Jixing Ma

发明人： Mingzhi Gao ,  Changxiu Li ,  Haitao Liu ,  Xiaofan Zhang ,  Jianhua Chen ,  Jing Ma ,  Xiaoxia Cai ,  Xianzhong Li ,  Jixing Ma

IPC分类号： C08F4/649 ,  C08F10/06

CPC分类号： C08F110/06 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/651

摘要： A catalyst component for olefin polymerization comprising magnesium, titanium, halogen and electron donor, wherein the electron donor is selected from at least one of the diol diester compounds, when the diol diester comprised contains a certain amount of isomer with Fischer projection formula as shown in Formula (II), the activity and stereospecificity of the catalyst are greatly improved, especially in the production of polymers with high melt index, the isotactic index of the obtained polymers is improved substantially.

摘要翻译： 一种用于烯烃聚合的催化剂组分，包括镁，钛，卤素和电子给体，其中当二醇二酯包含含有一定量的具有Fischer投影式的异构体时，电子给体选自至少一种二醇二酯化合物，如 式（II）中，催化剂的活性和立体定向性大大提高，特别是在生产具有高熔体指数的聚合物的情况下，得到的聚合物的全同立构指数得到显着提高。

公开(公告)号：US20130225773A1

公开(公告)日：2013-08-29

申请号：US13816367

申请日：2011-08-12

申请人： Mingzhi Gao ,  Changxiu Li ,  Haitao Liu ,  Xianzhong Li ,  Xiaofan Zhang ,  Xiaoxia Cai ,  Jianhua Chen ,  Jing Ma ,  Jixing Ma

发明人： Mingzhi Gao ,  Changxiu Li ,  Haitao Liu ,  Xianzhong Li ,  Xiaofan Zhang ,  Xiaoxia Cai ,  Jianhua Chen ,  Jing Ma ,  Jixing Ma

IPC分类号： C08F4/10

CPC分类号： C08F4/10 ,  C08F110/06 ,  C08F4/651 ,  C08F4/6492 ,  C08F2500/04 ,  C08F2500/15

摘要： A catalyst component for olefin polymerization which contains magnesium, titanium, halogen and electron donors is provided in the present invention. The electron donors are selected from at least one succinate compounds of following general formula (I), and the content of said succinate compounds with the structure as shown in Formula (II) in said succinate compounds (I) is less than 100%, but not less than 51.0 wt %. Compared with the mesomer whose content with the structure as shown in Formula (II) is 100%, the catalyst component provided by the present invention not only greatly decreases the manufacturing cost, but also improves certain properties of the catalyst, for example the molecular weight distribution of polymer obtained by catalytic reaction using said catalyst is wider, which is beneficial for improving processing properties of polymers. The corresponding catalyst is also provided.

摘要翻译： 在本发明中提供了含有镁，钛，卤素和电子给体的烯烃聚合用催化剂组分。 电子给体选自至少一种以下通式（I）的琥珀酸酯化合物，并且所述琥珀酸酯化合物（I）中所述的具有式（II）所示结构的所述琥珀酸酯化合物的含量小于100％，但是 不小于51.0重量％。 与式（II）所示结构的含量为100％的本身相比，本发明提供的催化剂成分不仅大大降低了制造成本，而且提高了催化剂的某些性能，例如分子量 使用所述催化剂通过催化反应获得的聚合物的分布较宽，这有利于改善聚合物的加工性能。 也提供了相应的催化剂。