公开(公告)号：US20120016150A1

公开(公告)日：2012-01-19

申请号：US13255943

申请日：2010-04-05

Applicant: Toru Uekawa ,  Jun Ohshita ,  Ichiro Komoto ,  Kouji Yoshikawa

Inventor： Toru Uekawa ,  Jun Ohshita ,  Ichiro Komoto ,  Kouji Yoshikawa

IPC: C07C253/16

CPC classification number: C07C253/30 ,  C07C2601/02 ,  C07C255/31

Abstract: A process for producing comprising reacting a 3-formyl-2,2-dimethylcyclopropanecarboxylate and propionitrile in the presence of a base to obtain 3-(2-cyano-1-propenyl)-2,2-dimethylcyclopropanecarboxylic acid or its salt.

Abstract translation: 一种制备方法，包括在碱存在下使3-甲酰基-2,2-二甲基环丙烷甲酸酯和丙腈反应，得到3-（2-氰基-1-丙烯基）-2,2-二甲基环丙烷甲酸或其盐。

公开(公告)号：US08048916B2

公开(公告)日：2011-11-01

申请号：US12529559

申请日：2008-03-06

Applicant: Toru Uekawa ,  Jun Ohshita

Inventor： Toru Uekawa ,  Jun Ohshita

IPC: A01N53/02 ,  C07C69/74 ,  A01P15/00

CPC classification number: C07C255/31 ,  A01N53/00

Abstract: A compound represented by the formula (I): has an excellent pest controlling activity and therefore is useful for an effective ingredient of a pest control composition.

Abstract translation: 由式（I）表示的化合物具有优异的害虫控制活性，因此可用于害虫防治组合物的有效成分。

公开(公告)号：US08039499B2

公开(公告)日：2011-10-18

申请号：US12440729

申请日：2007-08-24

Applicant: Jun Ohshita ,  Toru Uekawa

Inventor： Jun Ohshita ,  Toru Uekawa

IPC: A61K31/4166 ,  C07D233/72

CPC classification number: C07D233/72

Abstract: An ester compound represented by the formula (I): (wherein, R1 represents a C1-C3 alkyl group, a 2-propenyl group or a 2-propynyl group.) has excellent pest controlling activity and is useful as an active ingredient for a pest controlling agent.

Abstract translation: 由式（I）表示的酯化合物（其中，R1表示C1-C3烷基，2-丙烯基或2-丙炔基）具有优异的害虫控制活性，可用作 害虫控制剂。

公开(公告)号：US08461370B2

公开(公告)日：2013-06-11

申请号：US13255943

申请日：2010-04-05

Applicant: Toru Uekawa ,  Jun Ohshita ,  Ichiro Komoto ,  Kouji Yoshikawa

Inventor： Toru Uekawa ,  Jun Ohshita ,  Ichiro Komoto ,  Kouji Yoshikawa

IPC: C07C255/31 ,  C07C255/39

CPC classification number: C07C253/30 ,  C07C2601/02 ,  C07C255/31

Abstract: A process for producing comprising reacting a 3-formyl-2,2-dimethylcyclopropanecarboxylate and propionitrile in the presence of a base to obtain 3-(2-cyano-1-propenyl)-2,2-dimethylcyclopropanecarboxylic acid or its salt.

Abstract translation: 一种制备方法，包括在碱存在下使3-甲酰基-2,2-二甲基环丙烷甲酸酯和丙腈反应，得到3-（2-氰基-1-丙烯基）-2,2-二甲基环丙烷甲酸或其盐。

公开(公告)号：US20120323034A1

公开(公告)日：2012-12-20

申请号：US13580900

申请日：2011-02-25

Applicant: Kouji Yoshikawa ,  Toshiyuki Kiji ,  Jun Ohshita ,  Toshio Somyo ,  Manabu Kashiwabara ,  Yoko Miyanaga

Inventor： Kouji Yoshikawa ,  Toshiyuki Kiji ,  Jun Ohshita ,  Toshio Somyo ,  Manabu Kashiwabara ,  Yoko Miyanaga

IPC: C07C253/18 ,  C07C249/08

CPC classification number: C07C319/20 ,  C07C249/08 ,  C07C253/00 ,  C07C2601/02 ,  C07C2601/08 ,  C07C2601/14 ,  C07C251/40 ,  C07C255/31 ,  C07C323/16

Abstract: A method comprising an oximation step of reacting a formylalkenylcyclopropanecarboxylic acid ester represented by the formula (1): (wherein, R1 represents an alkyl group optionally having substituent(s) or halogen atom(s), and R2 represents an alkyl group optionally having substituent(s) or a benzyl group optionally having substituent(s)) and hydroxylamine in a solvent in the presence at least one compound selected from the group consisting of carboxylic acids and carboxylic acid metal salts, to produce a hydroxyiminoalkenylcyclopropanecarboxylic acid ester represented by the formula (3): (wherein, R1 and R2 are as defined above).

Abstract translation: 一种方法，其包括使式（1）表示的甲酰基链烯基环丙烷羧酸酯反应的肟化步骤：其中，R 1表示任选具有取代基的烷基或卤素原子，R 2表示任选具有取代基的烷基 或任选具有取代基的苄基）和羟胺在溶剂中在至少一种选自羧酸和羧酸金属盐的化合物存在的情况下进行反应，得到式（I）表示的羟基亚氨基链烯基环丙烷羧酸酯 （3）:(式中，R 1和R 2如上所定义）。

公开(公告)号：US08263797B2

公开(公告)日：2012-09-11

申请号：US12811970

申请日：2008-12-22

Applicant: Toru Uekawa ,  Jun Ohshita ,  Kouji Yoshikawa ,  Ichiro Komoto

Inventor： Toru Uekawa ,  Jun Ohshita ,  Kouji Yoshikawa ,  Ichiro Komoto

IPC: C07C253/30 ,  C07C255/31

CPC classification number: C07C253/30 ,  C07C255/31 ,  C07C2601/02

Abstract: A method for producing a cyclopropanecarboxylic acid compound represented by formula (VI) (wherein R denotes the same as below), which comprising reacting a compound represented by formula (V) (wherein R denotes a chain hydrocarbon group having 1 to 10 carbon atoms or the like, and R1 denotes a chain hydrocarbon group having 1 to 10 carbon atoms optionally substituted with a halogen atom or the like) with an alkali metal borohydride compound in the presence of a solvent.

Abstract translation: 一种制备由式（VI）表示的环丙烷羧酸化合物（其中R表示与下述相同）的方法，其包括使式（V）表示的化合物（其中R表示具有1-10个碳原子的链烃基或 R 1表示具有1〜10个碳原子的任选被卤素原子取代的链烃基）与碱金属硼氢化物在溶剂存在下反应。

公开(公告)号：US20120029227A1

公开(公告)日：2012-02-02

申请号：US13203916

申请日：2010-03-12

Applicant: Jun Ohshita ,  Toru Uekawa

Inventor： Jun Ohshita ,  Toru Uekawa

IPC: C07C69/743

CPC classification number: C07C253/30 ,  C07C2601/02 ,  C07C255/31

Abstract: A method for producing a cyclopropanecarboxylate represented by formula (III): wherein, R represents a chain hydrocarbon group having 1 to 10 carbon atoms optionally having at least one member selected from the group consisting of halogen atoms, acyl groups having 2 to 7 carbon atoms optionally having a substituent, alkoxy groups having 1 to 7 carbon atoms optionally having a substituent, alkylthio groups having 1 to 3 carbon atoms and phenyl groups optionally having a substituent, a cyclic hydrocarbon group having 3 to 10 carbon atoms or a hydrogen atom; comprising reacting a cyclopropanecarboxylate represented by formula (I): wherein, R represents the same meaning as described above; and 2-cyanopropionic acid in the presence of a base.

Abstract translation: 一种由式（III）表示的环丙烷羧酸酯的制备方法：其中，R表示碳原子数1〜10的链状烃基，可以具有选自卤素原子，碳原子数2〜7的酰基中的至少1种 任选具有取代基，可以具有取代基的碳原子数1〜7的烷氧基，碳原子数1〜3的烷硫基和可以具有取代基的苯基，碳原子数3〜10的环状烃基或氢原子。 包括使由式（I）表示的环丙烷羧酸酯反应：其中，R表示与上述相同的含义; 和2-氰基丙酸在碱的存在下反应。

公开(公告)号：US20100280267A1

公开(公告)日：2010-11-04

申请号：US12811970

申请日：2008-12-22

Applicant: Toru Uekawa ,  Jun Ohshita ,  Kouji Yoshikawa ,  Ichiro Komoto

Inventor： Toru Uekawa ,  Jun Ohshita ,  Kouji Yoshikawa ,  Ichiro Komoto

IPC: C07C253/00

CPC classification number: C07C253/30 ,  C07C255/31 ,  C07C2601/02

Abstract: A method for producing a cyclopropanecarboxylic acid compound represented by formula (VI) (wherein R denotes the same as below), which comprising reacting a compound represented by formula (V) (wherein R denotes a chain hydrocarbon group having 1 to 10 carbon atoms or the like, and R1 denotes a chain hydrocarbon group having 1 to 10 carbon atoms optionally substituted with a halogen atom or the like) with an alkali metal borohydride compound in the presence of a solvent.

Abstract translation: 一种制备由式（VI）表示的环丙烷羧酸化合物（其中R表示与下述相同）的方法，其包括使式（V）表示的化合物（其中R表示具有1-10个碳原子的链烃基或 R 1表示具有1〜10个碳原子的任选被卤素原子取代的链烃基）与碱金属硼氢化物在溶剂存在下反应。

公开(公告)号：US20100041750A1

公开(公告)日：2010-02-18

申请号：US12529559

申请日：2008-03-06

Applicant: Toru Uekawa ,  Jun Ohshita

Inventor： Toru Uekawa ,  Jun Ohshita

IPC: A01N53/02 ,  C07C69/74 ,  A01P15/00

CPC classification number: C07C255/31 ,  A01N53/00

Abstract: A compound represented by the formula (I): has an excellent pest controlling activity and therefore is useful for an effective ingredient of a pest control composition.

Abstract translation: 由式（I）表示的化合物具有优异的害虫控制活性，因此可用于害虫防治组合物的有效成分。

公开(公告)号：US20090253763A1

公开(公告)日：2009-10-08

申请号：US12440729

申请日：2007-08-24

Applicant: Jun Ohshita ,  Toru Uekawa

Inventor： Jun Ohshita ,  Toru Uekawa

IPC: A01N43/50 ,  C07D233/72

CPC classification number: C07D233/72

Abstract: An ester compound represented by the formula (I): (wherein, R1 represents a C1-C3 alkyl group, a 2-propenyl group or a 2-propynyl group.) has excellent pest controlling activity and is useful as an active ingredient for a pest controlling agent.

Abstract translation: 由式（I）表示的酯化合物（其中，R1表示C1-C3烷基，2-丙烯基或2-丙炔基）具有优异的害虫控制活性，可用作 害虫控制剂。