公开(公告)号：US20090029043A1

公开(公告)日：2009-01-29

申请号：US12194834

申请日：2008-08-20

申请人： Haitao RONG ,  Jurgen GROLL ,  Peter GREIWE ,  Gallus SCHECHNER ,  Christine MOHR ,  Martin MOLLER

发明人： Haitao RONG ,  Jurgen GROLL ,  Peter GREIWE ,  Gallus SCHECHNER ,  Christine MOHR ,  Martin MOLLER

IPC分类号： B05D1/12 ,  B05D3/02 ,  B05D3/12 ,  C08G77/14 ,  C08G77/26 ,  C08L83/06

CPC分类号： C08G65/336 ,  A61K8/91 ,  A61K2800/544 ,  A61K2800/94 ,  A61Q5/12 ,  C08F8/42 ,  C08G18/10 ,  C08G18/485 ,  C08G18/5045 ,  C08G18/5096 ,  C08G18/718 ,  C08G2210/00 ,  C09D171/02 ,  C09D201/10 ,  C11D3/373 ,  C08G18/302

摘要： The present invention relates to coatings that possess a dynamic contact angle hysteresis in water, measured by means of a Wilhelmy balance according to DIN EN 14370, of at most 15°, and are can be manufactured from star-shaped prepolymers and/or star-shaped prepolymer-nanoparticle complexes that are cross-linkable with one another and with the surface of the substrate to be coated, the star-shaped prepolymers and/or star-shaped prepolymer-nanoparticle complexes possessing, before being cross-linked, at least three hydrophilic polymer arms that, considered of themselves, are soluble in water, and that carry on all or on some of their free ends R1 silyl terminal groups of the following general formula (I): R1 is —CRa2—Si(ORb)r(Rc)3-r, where Ra denotes hydrogen or a linear or branched alkyl group having 1 to 6 carbon atoms, ORb denotes a hydrolyzable group, Rc denotes a linear or branched alkyl group having 1 to 6 carbon atoms, and r denotes a number from 1 to 3, and that carry, on the optionally present ends not carrying silyl terminal groups, reactive groups that are reactive with respect to themselves, the substrate to be coated, entities optionally introduced into the coating, and/or with the silyl terminal groups. The present invention furthermore relates to a method for manufacturing such coatings, and to star-shaped prepolymers that are used in the coatings. The invention moreover relates to use of the star-shaped prepolymers as additives to various agents for temporary or permanent anti-soiling finishing of surfaces.

摘要翻译： 本发明涉及在水中具有动态接触角滞后的涂层，其通过根据DIN EN 14370的Wilhelmy平衡测量为至多15°，并且可以由星形预聚物和/或星形预制物制造， 形状预聚物 - 纳米颗粒复合物，其彼此可交联并与待涂覆的基底的表面，星形预聚物和/或星形预聚物 - 纳米颗粒络合物在交联之前具有至少三个 亲水性聚合物臂，其本身可以溶于水，并且在其一部分自由端上进行。其中R 1是-CR a 2 -Si（OR b）r（OR b）r Rc）3-r，其中Ra表示氢或具有1至6个碳原子的直链或支链烷基，ORb表示可水解基团，Rc表示具有1至6个碳原子的直链或支链烷基，r表示数 从1到3，并携带，在 任选地存在不携带甲硅烷基端基的末端，对其自身具有反应性的反应性基团，待涂布的基材，任选地引入涂层中的实体和/或甲硅烷基末端基团。 本发明还涉及制造这种涂层的方法以及用于涂层中的星形预聚物。 此外，本发明涉及使用星形预聚物作为各种试剂的添加剂用于表面的临时或永久性防污整理。