公开(公告)号：US06865068B1

公开(公告)日：2005-03-08

申请号：US09559073

申请日：2000-04-27

申请人： Kazuyuki Murakami ,  Yasuhiro Mogi ,  Kazuteru Tabayashi ,  Toru Shimoyama ,  Kazuhiko Yamada ,  Yasuo Shinozaki

发明人： Kazuyuki Murakami ,  Yasuhiro Mogi ,  Kazuteru Tabayashi ,  Toru Shimoyama ,  Kazuhiko Yamada ,  Yasuo Shinozaki

IPC分类号： C01B32/336 ,  H01G9/00 ,  H01G9/155 ,  H01G9/55 ,  B01J20/02 ,  C01B31/08

CPC分类号： H01G11/34 ,  C01B32/336 ,  H01G11/24 ,  H01G11/60 ,  H01G11/62 ,  Y02E60/13 ,  Y02T10/7022 ,  Y10T29/417

摘要： A carbonaceous material having a total pore volume of from 0.5 to 1.5 cm3/g per unit mass, a volume of micropores having diameters of from 10 to 20 Å of from 10 to 45% based on the total pore volume, a volume of mesopores having diameters of from 20 to 200 Å of from 35 to 65% based on the total pore volume, a volume of macropores having diameters exceeding 200 Å of not more than 15% based on the total pore volume, and a specific surface area of from 1,000 to 2,500 m2/g. The carbonaceous material is incorporated into an electric double layer capacitor to provide increased capacitance.

摘要翻译： 总孔体积为0.5-1.5cm 3 / g /单位质量的碳质材料，基于总孔体积的直径为10至20的微孔体积为10至45％，体积 的基于总孔体积的具有20至200的直径为35至65％的介孔，基于总孔体积，直径超过200的大孔体积不大于15％，比表面积 为1,000至2,500m 2 / g。 将含碳材料并入双电层电容器中以提供增加的电容。

公开(公告)号：US06485864B1

公开(公告)日：2002-11-26

申请号：US09502458

申请日：2000-02-11

申请人： Kunio Miyazawa ,  Masayasu Nagoshi ,  Kenshi Noda ,  Takaaki Kondo ,  Tetsuo Shiode ,  Hidetoshi Morotomi ,  Hiromi Okamoto ,  Yasuhiro Mogi ,  Kazuteru Tabayashi

发明人： Kunio Miyazawa ,  Masayasu Nagoshi ,  Kenshi Noda ,  Takaaki Kondo ,  Tetsuo Shiode ,  Hidetoshi Morotomi ,  Hiromi Okamoto ,  Yasuhiro Mogi ,  Kazuteru Tabayashi

IPC分类号： C01B3104

CPC分类号： H01M4/587 ,  C01B32/20 ,  C01P2002/60 ,  C01P2002/72 ,  C01P2004/61 ,  C01P2006/80 ,  H01M4/0404

摘要： Boron-substituted graphite, which contains N-bonded boron atoms in a small proportion relative to whole substituted boron atoms, is produced by heating a feed fine particulate mixture of an infusibilized carbonaceous material and a boron compound such that the carbonaceous material is carbonized into a carbon structure, raising a temperature of the resulting heated fine particulate mixture promptly to a graphitization treatment temperature in an inert atmosphere unreactive with boron, retaining the graphitization treatment temperature for a time sufficient to allow graphitization of the carbon structure to proceed to a desired extent, and then quickly cooling the resulting graphitized mixture. The boron-substituted graphite is useful as a negative electrode in a lithium-ion secondary battery.

摘要翻译： 通过加热不熔化的含碳材料和硼化合物的进料精细颗粒混合物来制备硼相对于完全取代的硼原子以小比例含有N键的硼原子的硼取代的石墨，使碳质材料碳化成 碳结构，将所得加热的微粒混合物的温度迅速升高至与硼不反应的惰性气氛中的石墨化处理温度，将石墨化处理温度保持足以使碳结构石墨化进行到所需程度， 然后迅速冷却所得的石墨化混合物。 硼取代石墨可用作锂离子二次电池中的负极。