公开(公告)号：US20140235891A1

公开(公告)日：2014-08-21

申请号：US14131496

申请日：2012-07-06

Applicant: Wenpeng Li ,  Fengshou Xiao ,  Haicheng Xiao ,  Fujian Liu ,  Yinghui Li ,  Xiangju Meng ,  Xianming Xu ,  Xiangmin Yu ,  Wei Zhang ,  Kezhong Xu ,  Guoquan Song ,  Haotian Pei ,  Fangwei Li ,  Qunying Zeng ,  Zhixiang Zhang ,  Yeman Li

Inventor： Wenpeng Li ,  Fengshou Xiao ,  Haicheng Xiao ,  Fujian Liu ,  Yinghui Li ,  Xiangju Meng ,  Xianming Xu ,  Xiangmin Yu ,  Wei Zhang ,  Kezhong Xu ,  Guoquan Song ,  Haotian Pei ,  Fangwei Li ,  Qunying Zeng ,  Zhixiang Zhang ,  Yeman Li

IPC: C07C67/08 ,  C07C45/65

CPC classification number: C07C45/65 ,  B01J27/055 ,  B01J31/10 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/10 ,  C07C45/46 ,  C07C67/08 ,  C07C2601/14 ,  C08F8/36 ,  C08F112/36 ,  C07C49/84 ,  C07C69/14 ,  C07C69/24

Abstract: The invention relates to an application of organic framework porous solid acid. A catalyst for catalytic esterification and acylation reaction is prepared by the steps of adding a divinyl benzene monomer into a solvent prepared by mixing azobisisobutyronitrile, tetrahydrofuran and water, performing hydrothermal treatment at the normal temperature under the constant pressure, and volatilizing the solvent at the room temperature to obtain polydivinylbenzene; grinding the polydivinylbenzene into 200-mesh powder and performing degassing treatment under the nitrogen condition; adding polydivinylbenzene blocks into 1,1′,2-methyl chloroform to explode and crack into small blocks, wherein the small blocks swell; evenly mixing 1,1′,2-methyl chloroform and concentrated sulfuric acid, adding silver sulfate serving as a catalyst, adding processed polydivinylbenzene, performing sulfonation, filtering and washing with dioxane and water till it is neutral, performing drying, using dilute sulphuric acid to activate, performing washing till the it is neutral and performing drying. The catalyst is used for the catalytic esterification and the acylation reaction and has high catalytic activity and conversion rate.

Abstract translation: 本发明涉及有机骨架多孔固体酸的应用。 通过以下步骤制备催化酯化和酰化反应的催化剂：将二乙烯基苯单体加入到通过混合偶氮二异丁腈，四氢呋喃和水制备的溶剂中，在常压下在恒定压力下进行水热处理，并在室温下挥发溶剂 温度得到聚二乙烯基苯; 将聚二乙烯基苯研磨成200目粉末，并在氮气条件下进行脱气处理; 将聚二乙烯基苯嵌段加入到1,1'，2-甲基氯仿中，将其破碎成小块，其中小块膨胀; 均匀混合1,1'，2-甲基氯仿和浓硫酸，加入硫酸银作为催化剂，加入加工的聚二乙烯基苯，进行磺化，过滤并用二恶烷和水洗涤至中性，用稀硫酸 激活，进行洗涤直至其中性并进行干燥。 该催化剂用于催化酯化和酰化反应，具有较高的催化活性和转化率。

公开(公告)号：US09056823B2

公开(公告)日：2015-06-16

申请号：US14131496

申请日：2012-07-06

Applicant: Wenpeng Li ,  Fengshou Xiao ,  Haicheng Xiao ,  Fujian Liu ,  Yinghui Li ,  Xiangju Meng ,  Xianming Xu ,  Xiangmin Yu ,  Wei Zhang ,  Kezhong Xu ,  Guoquan Song ,  Haotian Pei ,  Fangwei Li ,  Qunying Zeng ,  Zhixiang Zhang ,  Yueman Li

Inventor： Wenpeng Li ,  Fengshou Xiao ,  Haicheng Xiao ,  Fujian Liu ,  Yinghui Li ,  Xiangju Meng ,  Xianming Xu ,  Xiangmin Yu ,  Wei Zhang ,  Kezhong Xu ,  Guoquan Song ,  Haotian Pei ,  Fangwei Li ,  Qunying Zeng ,  Zhixiang Zhang ,  Yueman Li

IPC: C07C67/08 ,  C07C45/65 ,  B01J31/10 ,  B01J37/10 ,  C07C45/46 ,  C08F112/36 ,  C08F8/36 ,  B01J27/055 ,  B01J35/02 ,  B01J37/00

CPC classification number: C07C45/65 ,  B01J27/055 ,  B01J31/10 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/10 ,  C07C45/46 ,  C07C67/08 ,  C07C2601/14 ,  C08F8/36 ,  C08F112/36 ,  C07C49/84 ,  C07C69/14 ,  C07C69/24

Abstract: The invention relates to a catalyst for the catalytic esterification and acylation reaction. The catalyst is prepared by the steps of adding a divinyl benzene monomer into a solvent prepared by mixing azobisisobutyronitrile, tetrahydrofuran and water, performing hydrothermal treatment at the normal temperature under the constant pressure, and volatilizing the solvent at the room temperature to obtain polydivinylbenzene; grinding the polydivinylbenzene into 200-mesh powder and performing degassing treatment under the nitrogen condition; adding polydivinylbenzene blocks into 1,1′,2-trichloroethane to explode and crack into small blocks, wherein the small blocks swell; evenly mixing 1,1′,2-trichloroethane and concentrated sulfuric acid, adding silver sulfate serving as a catalyst, adding processed polydivinylbenzene, performing sulfonation, filtering and washing with dioxane and water till it is neutral, performing drying, using dilute sulphuric acid to activate, performing washing till the it is neutral and performing drying. The catalyst has high catalytic activity and conversion rate.

Abstract translation: 本发明涉及催化酯化和酰化反应的催化剂。 该催化剂通过以下步骤制备：将二乙烯基苯单体加入到通过混合偶氮二异丁腈，四氢呋喃和水制备的溶剂中，在常压下恒温进行水热处理，并在室温下挥发溶剂得到聚二乙烯基苯; 将聚二乙烯基苯研磨成200目粉末，并在氮气条件下进行脱气处理; 将聚二乙烯基苯嵌段加入到1,1'，2-三氯乙烷中，爆炸裂成小块，其中小块膨胀; 均匀混合1,1'，2-三氯乙烷和浓硫酸，加入硫酸银作为催化剂，加入加工的聚二乙烯基苯，进行磺化，过滤并用二恶烷和水洗涤至中性，进行干燥，用稀硫酸 激活，进行洗涤直到它是中性的并进行干燥。 该催化剂具有较高的催化活性和转化率。