公开(公告)号：US07314544B2

公开(公告)日：2008-01-01

申请号：US11212038

申请日：2005-08-25

申请人： Oliver J. Murphy ,  Adrian J. Denvir ,  Sorin G. Teodorescu ,  Kyle B. Uselton

发明人： Oliver J. Murphy ,  Adrian J. Denvir ,  Sorin G. Teodorescu ,  Kyle B. Uselton

IPC分类号： C25B1/00

CPC分类号： C25B1/00

摘要： A method for the anodic electrochemical synthesis of ammonia gas. The method comprises providing an electrolyte between an anode and a cathode, providing nitrogen and hydrogen gases to the cathode, oxidizing negatively charged nitrogen-containing species and negatively charged hydrogen-containing species present in the electrolyte at the anode to form adsorbed nitrogen species and adsorbed hydrogen species, respectively, and reacting the adsorbed nitrogen species with the adsorbed hydrogen species to form ammonia. Nitrogen and hydrogen gases may be provided through a porous cathode substrate. The negatively charged nitrogen-containing species in the electrolyte may be produced by reducing nitrogen gas at the cathode and/or by supplying a nitrogen-containing salt, such as lithium nitride, into the molten salt electrolyte. Similarly, the negatively charged hydrogen-containing species in the electrolyte may be produced by reducing hydrogen gas at the cathode and/or by supplying a hydrogen-containing salt, such as lithium hydride, into the molten salt electrolyte.

摘要翻译： 一种用于阳极电化学合成氨气的方法。 该方法包括在阳极和阴极之间提供电解质，向阴极提供氮气和氢气，在阳极处氧化带负电荷的含氮物质和存在于电解质中的带负电荷的含氢物质以形成吸附的氮物质并吸附 氢物种，并将吸附的氮物质与吸附的氢物质反应形成氨。 可以通过多孔阴极基底提供氮气和氢气。 电解质中带负电的含氮物质可以通过在阴极处还原氮气和/或通过向熔融盐电解质中提供氮化钠等含氮盐来制备。 类似地，电解质中带负电荷的含氢物质可以通过还原阴极处的氢气和/或通过向熔融盐电解质中提供氢化锂等含氢盐来制备。

公开(公告)号：US06468953B1

公开(公告)日：2002-10-22

申请号：US09631867

申请日：2000-08-03

申请人： G. Duncan Hitchems ,  Steven Drabek ,  Anthony Giletto ,  Charles Blankenburg ,  Kyle B. Uselton ,  Jennifer Schultz-Bathurst ,  Shivaun Archer

发明人： G. Duncan Hitchems ,  Steven Drabek ,  Anthony Giletto ,  Charles Blankenburg ,  Kyle B. Uselton ,  Jennifer Schultz-Bathurst ,  Shivaun Archer

IPC分类号： C11D1700

CPC分类号： C11D3/48 ,  A01N59/00 ,  A61L2/202 ,  C11D7/02 ,  C11D7/261 ,  C11D7/265 ,  A01N37/02 ,  A01N31/02 ,  A01N2300/00

摘要： The invention relates to the formation of antimicrobial solutions formed by ozonating a liquid containing organic precursor molecules. The preferred organic precursor molecules include carboxylic acids, most particularly octanoic acid with or without acetic acid, and alcohols, most particularly greater than 80 weight percent ethanol. The ozonating step is preferably performed with minimal or no water present in the liquid containing the organic precursors. After ozonation is complete, the ozonated liquid may be diluted with water or other solvent to form a use solution for contacting and cleaning a microbially contaminated surface or other medium.

摘要翻译： 本发明涉及通过臭氧化含有有机前体分子的液体形成的抗微生物溶液的形成。 优选的有机前体分子包括羧酸，最特别是具有或不具有乙酸的辛酸，以及醇，最特别地大于80重量％的乙醇。 臭氧化步骤优选在含有有机前体的液体中存在最少或不存在水的情况下进行。 臭氧化完成后，臭氧化液体可以用水或其它溶剂稀释，形成用于接触和清洁微生物污染的表面或其他介质的用途溶液。