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    Use of oligomeric carbodiimides as stabilizers
    1.
    发明授权
    Use of oligomeric carbodiimides as stabilizers 失效
    使用低聚碳二亚胺作为稳定剂

    公开(公告)号：US08623945B2

    公开(公告)日：2014-01-07

    申请号：US13421363

    申请日：2012-03-15

    申请人： Theo Smit ,  Laurence Pottie ,  Simone Schillo ,  Volker Frenz ,  Roelof van der Meer

    发明人： Theo Smit ,  Laurence Pottie ,  Simone Schillo ,  Volker Frenz ,  Roelof van der Meer

    IPC分类号： C08K5/3412 ,  C07D413/12 ,  C08K5/3415 ,  C08K5/353

    CPC分类号： C07D403/12 ,  C07D413/12 ,  C08K5/29 ,  C08K5/3412

    摘要： This invention relates to a process for stabilizing polymers with oligomeric carbodiimides containing at least one heterocyclic end group and stabilizers. The oligomeric carbodiimides may be compounds of the general formula (I): where A1, A2 are each independently, identically or differently, hydrocarbon groups having 2 to 20 carbon atoms, B1, B2 are each independently, identically or differently, heterocycles, C1-C30-alcohols, polyetherols, polyesterols, amines, polyether amines, polyester amines, thioalcohols, polyether thiols, polyester thiols; R1, R2 are each independently, identically or differently: n is an integer from 2 to 100, and A1, A2, B1 and B2 may each be substituted at any desired position by C1-C20-alkyl, C2-C20-alkenyl, C2-C20-alkynyl, C1-C20-alkoxy, carbonyl oxygen (═O) or halogen, with the proviso that at least one B1 or B2 substituent is a heterocyclic end group. The invention also relates to compositions of the oligomeric carbodiimides and mixtures.

    摘要翻译： 本发明涉及一种使含有至少一个杂环端基和稳定剂的低聚碳二亚胺稳定聚合物的方法。 低聚碳二亚胺可以是通式（I）的化合物：其中A1，A2各自独立地，相同地或不同地是具有2-20个碳原子的烃基，B1，B2各自独立地，相同地或不同地是杂环，C1- C30醇，聚醚醚，聚酯醇，胺，聚醚胺，聚酯胺，硫代醇，聚醚硫醇，聚酯硫醇; R 1，R 2各自独立地，相同地或不同地表示：n是2至100的整数，并且A1，A2，B1和B2各自可以在任何所需位置被C 1 -C 20 - 烷基，C 2 -C 20 - 链烯基，C 2 -C 20炔基，C 1 -C 20 - 烷氧基，羰基氧（= O）或卤素，条件是至少一个B1或B2取代基是杂环端基。 本发明还涉及低聚碳二亚胺及其混合物的组合物。

    USE OF OLIGOMERIC CARBODIIMIDES AS STABILIZERS
    3.
    发明申请
    USE OF OLIGOMERIC CARBODIIMIDES AS STABILIZERS 失效
    作为稳定剂使用低聚碳酸酯

    公开(公告)号：US20120238676A1

    公开(公告)日：2012-09-20

    申请号：US13421363

    申请日：2012-03-15

    申请人： THEO SMIT ,  LAURENCE POTTIE ,  SIMONE SCHILLO ,  VOLKER FRENZ ,  ROELOF VAN DER MEER

    发明人： THEO SMIT ,  LAURENCE POTTIE ,  SIMONE SCHILLO ,  VOLKER FRENZ ,  ROELOF VAN DER MEER

    IPC分类号： C08K5/3412 ,  C07D413/12 ,  C08K5/3415 ,  C08K5/353 ,  C08K5/29 ,  C07D403/12 ,  C07C267/00

    CPC分类号： C07D403/12 ,  C07D413/12 ,  C08K5/29 ,  C08K5/3412

    摘要： Oligomeric carbodiimides comprising at least one heterocyclic end group are used as stabilizers for polymers. The oligomeric carbodiimides may be compounds of the general formula (I), where A1, A2 are each independently, identically or differently, hydrocarbon groups having 2 to 20 carbon atoms, B1, B2 are each independently, identically or differently, heterocycles, C1-C30-alcohols, polyetherols, polyesterols, amines, polyether amines, polyester amines, thioalcohols, polyether thiols, polyester thiols, R1, R2 are each independently, identically or differently, n is an integer from 2 to 100, and wherein A1, A2, B1 and B2 may each be substituted at any desired position by C1-C20-alkyl, C2-C20-alkenyl, C2-C20-alkynyl, C1-C20-alkoxy, carbonyl oxygen (═O) or halogen, with the proviso that at least one B1 or B2 substituent is a heterocyclic end group. Processes for stabilizing polymers against hydrolysis using oligomeric carbodiimides are also disclosed.

    摘要翻译： 包含至少一个杂环端基的低聚碳二亚胺用作聚合物的稳定剂。 低聚碳二亚胺可以是通式（I）的化合物，其中A1，A2各自独立地，相同地或不同地是具有2-20个碳原子的烃基，B1，B2各自独立地，相同地或不同地是杂环，C1- C30醇，聚醚，聚酯，胺，聚醚胺，聚酯胺，硫醇，聚醚硫醇，聚酯硫醇，R 1，R 2各自独立地相同或不同，n为2〜100的整数，其中，A1，A2， C 1 -C 20烷基，C 2 -C 20 - 烯基，C 2 -C 20炔基，C 1 -C 20 - 烷氧基，羰基氧（= O）或卤素可以在任何所需位置上被B1和B2取代，条件是在 至少一个B1或B2取代基是杂环端基。 还公开了使用低聚碳二亚胺稳定聚合物抗水解的方法。