公开(公告)号：US3911042A

公开(公告)日：1975-10-07

申请号：US49491774

申请日：1974-08-05

申请人： BELOV GENNADY PETROVICH ,  DZHABIEV TAIMURAZ SAVELIEVICH ,  DYACHKOVSKY FRIDRIKH STEPANOVI ,  SMIRNOV VYACHESLAV IVANOVICH ,  KARPOVA NELLI DZHAVKHAROVNA ,  BRIKENSHTEIN KHAIM MORDKHE ARO ,  GERASINA MATRENA PETROVNA ,  KUZMIN VLADIMIR EVGENIEVICH ,  MATKOVSKY PETR EVGENIEVICH ,  RUSSIYAN LJUDMILA NIKOLAEVNA ,  POMOGAILC ANATOLY DMITRIEVICH ,  CHIRKOV NIKOLAI MIKHA ,  CHIRKOV ADMINISTRATOR BY MIKHA

发明人： BELOV GENNADY PETROVICH ,  DZHABIEV TAIMURAZ SAVELIEVICH ,  DYACHKOVSKY FRIDRIKH STEPANOVI ,  SMIRNOV VYACHESLAV IVANOVICH ,  KARPOVA NELLI DZHAVKHAROVNA ,  BRIKENSHTEIN KHAIM-MORDKHE ARO ,  GERASINA MATRENA PETROVNA ,  KUZMIN VLADIMIR EVGENIEVICH ,  MATKOVSKY PETR EVGENIEVICH ,  RUSSIYAN LJUDMILA NIKOLAEVNA ,  POMOGAILC ANATOLY DMITRIEVICH ,  CHIRKOV NIKOLAI MIKHA ,  CHIRKOV ADMINISTRATOR BY MIKHA

IPC分类号： C07C2/30 ,  C07C3/10

CPC分类号： C07C2/30 ,  C07C2531/02 ,  C07C2531/12 ,  C07C2531/14 ,  C07C11/08

摘要： The present invention relates to a method of producing butene-1. According to the invention, the method of producing butene-1 resides in dimerizing ethylene in the presence of a complex organometallic catalyst of the formula (RO)3TiR''.AlR2''''OR + AlR2''''R'', where R is an alkyl radical with the number of carbon atoms from 2 to 4, R'' R or H, R'''' is the same as R, or of a catalyst of the formula Ti(OR)4 + AlR2''''R'' and modifiers such as (C5H5)2TiCl2, oxygen, metaphenylenediamine or N-phenyl- Beta naphthylamine, in the medium of solvents such as n-heptane, ndecane, toluene, diethyl ether, ethyl chloride, vinylbutyl ether, tetrahydrofuran, diphenyl ether, methylphenyl ether and their mixtures. The invention will find application in petrochemical processing.

公开(公告)号：US3882046A

公开(公告)日：1975-05-06

申请号：US32071073

申请日：1973-01-03

申请人： POMOGAILO ANATOLY DMITRIEVICH ,  MAMBETOV URAKBAI ALIMBAEVICH ,  SOKOLSKY DMITRY VLADIMIROVICH ,  BOLSHOV ALEXANDR AVRAAMOVICH ,  GLUZMAN MOISEI KHARITONOVICH ,  KOCHUROVSKAYA GERTA GENNADIEVN ,  GLUZMAN EVGENY MOISEEVICH ,  MATKOVSKY PETR EVGENIEVICH ,  BEIKHOLD GALINA ALBERTOVNA ,  AFANASIEVA IRINA IVANOVNA ,  BURYMCHENKO MIKHAIL IVANOVICH ,  BAISHIGANOV ESENGELDY

发明人： POMOGAILO ANATOLY DMITRIEVICH ,  MAMBETOV URAKBAI ALIMBAEVICH ,  SOKOLSKY DMITRY VLADIMIROVICH ,  BOLSHOV ALEXANDR AVRAAMOVICH ,  GLUZMAN MOISEI KHARITONOVICH ,  KOCHUROVSKAYA GERTA GENNADIEVN ,  GLUZMAN EVGENY MOISEEVICH ,  MATKOVSKY PETR EVGENIEVICH ,  BEIKHOLD GALINA ALBERTOVNA ,  AFANASIEVA IRINA IVANOVNA ,  BURYMCHENKO MIKHAIL IVANOVICH ,  BAISHIGANOV ESENGELDY

IPC分类号： C08F4/64 ,  C08F10/00 ,  B01J11/84

CPC分类号： C08F10/00 ,  C08F4/631

摘要： A catalyst for polymerization and copolymerization of olefins is a binary system consisting of a complex compound formed by a halide of a transition metal belonging to Groups IVA-VA of the periodic system with polyglycolic ethers of mono- or polyfunctional alcohols, or polyglycolic esters of carboxylic acids or their anhydrosorbitols, in combination with aluminumorganic compounds. The said complex compounds are prepared by the interaction between said ethers (esters) and halides of transition metals in organic solvents in an inert medium.

摘要翻译： 用于烯烃的聚合和共聚的催化剂是由属于周期系统的IVA-VA族的过渡金属的卤化物与单官能或多官能醇的聚乙醇醚或羧酸的聚乙醇酸形成的络合物组成的二元体系 酸或它们的脱水山梨糖醇与铝有机化合物的组合。

公开(公告)号：US3879485A

公开(公告)日：1975-04-22

申请号：US43680974

申请日：1974-01-25

申请人： BELOV GENNADY PETROVICH ,  DZHABIEV TAIMURAZ SAVELIEVICH ,  DYACHKOVSKY FRIDRIKH STEPANOVI ,  SMIRNOV VYACHESLAV IVANOVICH ,  KARPOVA NELLI DZHAVKHAROVNA ,  BRIKENSHTEIN KHAIM MORDKHE ARO ,  GERASINA MATRENA PETROVNA ,  KUZMIN VLADIMIR EVGENIEVICH ,  MATKOVSKY PETR EVGENIEVICH ,  RUSSIYAN LJUDMILA NIKOLAEVNA ,  POMOGAILO ANATOLY DMITRIEVICH ,  CHIRKOV NIKOLAI MIKHA

发明人： BELOV GENNADY PETROVICH ,  DZHABIEV TAIMURAZ SAVELIEVICH ,  DYACHKOVSKY FRIDRIKH STEPANOVI ,  SMIRNOV VYACHESLAV

IPC分类号： C07C2/30 ,  C07C3/10

CPC分类号： C07C2/30 ,  C07C2531/02 ,  C07C2531/12 ,  C07C2531/14 ,  Y02P20/52 ,  C07C11/08

摘要： Butene-1 is prepared by dimerizing ethylene in the presence of a complex organometallic catalyst of the formula (RO)3TiR''.AlR2''''OR + AlR2''''R'', where R is an alkyl radical with the number of carbon atoms from 2 to 4, R'' R or H, R'''' is the same as R, or of a catalyst of the formula Ti(OR)4 + AlR2''''R'' and modifiers such as (C5H5)2TiCl2, oxygen, metaphenylenediamine or N-phenyl- Beta napthylamine, in the medium of solvents such as n-heptane, ndecane, toluene, diethyl ether, ethyl chloride, vinylbutyl ether, tetrahydrofuran, diphenyl ether, methylphenyl ether and their mixtures.

摘要翻译： 丁烯-1通过在式（RO）3 TiR'.AlR2''OR + AlR2''R'的复合有机金属催化剂存在下将乙烯二聚制备，其中R是碳原子数为2的烷基 至4，R'= R或H，R“与R相同，或式Ti（OR）4 + AlR2''R'的催化剂和改性剂如（C 5 H 5）2 TiCl 2，氧，间苯二胺或 在n-庚烷，正癸烷，甲苯，二乙醚，乙基氯，乙烯基丁醚，四氢呋喃，二苯基醚，甲基苯基醚及其混合物的溶剂介质中的N-苯基-β-萘胺。