公开(公告)号：US5914422A

公开(公告)日：1999-06-22

申请号：US966482

申请日：1997-11-07

申请人： Yutaka Furukawa ,  Mami Kotera ,  Seisaku Kumai ,  Kazuya Oharu ,  Toshihiko Toma

发明人： Yutaka Furukawa ,  Mami Kotera ,  Seisaku Kumai ,  Kazuya Oharu ,  Toshihiko Toma

IPC分类号： C08G77/385 ,  C07F7/08

CPC分类号： C08G77/385

摘要： A method for producing a fluorine-containing silicone compound, which comprises subjecting a compound of the following formula (I) and a hydrosilicone compound having at least one hydrogen atom bonded to a silicon atom to hydrosilylation to obtain a fluorine-containing silicone compound having a R.sup.f --Q--CR.sup.1 R.sup.2 CR.sup.3 HCR.sup.4 R.sup.5 -- group bonded to the silicon atom:R.sup.f --Q--CR.sup.1 R.sup.2 CR.sup.3 .dbd.CR.sup.4 R.sup.5(I)wherein R.sup.f is a monovalent fluorine-containing organic group, Q is a single bond or a bivalent organic group containing no fluorine atom, and each of R.sup.1 to R.sup.5 which are independent of one another, is a hydrogen atom or a monovalent organic group.

摘要翻译： 一种含氟硅氧烷化合物的制造方法，其特征在于，使下述式（I）的化合物与具有至少一个与硅原子键合的氢原子的氢硅氧烷化合物进行氢化硅烷化，得到具有 Rf-Q-CR1R2CR3HCR4R5-键合到硅原子上：Rf-Q-CR1R2CR3 = CR4R5（Ⅰ）其中Rf是一价含氟有机基团，Q是单键或不含氟原子的二价有机基团，和 彼此独立的R 1至R 5中的每一个为氢原子或一价有机基团。

公开(公告)号：US5663399A

公开(公告)日：1997-09-02

申请号：US547923

申请日：1995-10-25

申请人： Yutaka Furukawa ,  Mami Kotera ,  Seisaku Kumai ,  Kazuya Oharu ,  Toshihiko Toma

发明人： Yutaka Furukawa ,  Mami Kotera ,  Seisaku Kumai ,  Kazuya Oharu ,  Toshihiko Toma

IPC分类号： C08G77/385 ,  C07F7/08

CPC分类号： C08G77/385

摘要： A method for producing a fluorine-containing silicone compound, which comprises subjecting a compound of the following formula (I) and a hydrosilicone compound having at least one hydrogen atom bonded to a silicon atom to hydrosilylation to obtain a fluorine-containing silicone compound having a R.sup.f --Q--CR.sup.1 R.sup.2 CR.sup.3 HCR.sup.4 R.sup.5 -- group bonded to the silicon atom:R.sup.f --Q--CR.sup.1 R.sup.2 CR.sup.3 =CR.sup.4 R.sup.5 (I)wherein R.sup.f is a monovalent fluorine-containing organic group, Q is a single bond or a bivalent organic group containing no fluorine atom, and each of R.sup.1 to R.sup.5 which are independent of one another, is a hydrogen atom or a monovalent organic group.

摘要翻译： 一种含氟硅氧烷化合物的制造方法，其特征在于，使下述式（I）的化合物与具有至少一个与硅原子键合的氢原子的氢硅氧烷化合物进行氢化硅烷化，得到具有 Rf-Q-CR1R2CR3HCR4R5-键合到硅原子上：Rf-Q-CR1R2CR3 = CR4R5（Ⅰ）其中Rf是一价含氟有机基团，Q是单键或不含氟原子的二价有机基团，和 彼此独立的R 1至R 5中的每一个为氢原子或一价有机基团。

公开(公告)号：US06197989B1

公开(公告)日：2001-03-06

申请号：US09147542

申请日：1999-03-17

申请人： Yutaka Furukawa ,  Mami Kotera ,  Seisaku Kumai ,  Robert E. Ruckle, Jr. ,  Gerald J. Murphy

发明人： Yutaka Furukawa ,  Mami Kotera ,  Seisaku Kumai ,  Robert E. Ruckle, Jr. ,  Gerald J. Murphy

IPC分类号： C07F702

CPC分类号： C08G77/385 ,  C08G77/24 ,  C08G77/46

摘要： A fluorine-containing organic silicon compound represented by the following formula 1, which is useful as various industrial base materials required to have performances such as water and oil repellency, anti-fouling properties or release properties and as raw materials therefor. Here, Af represents a specific polyfluorohydrocarbon group-containing organic group; R1 and R2 which are independent of each other, represent bivalent organic groups; R3 to R9 which are independent of one another, represent monovalent organic groups; a is an integer of at least 1, and b is an integer of at least 0:

摘要翻译： 由下式1表示的含氟有机硅化合物，其可用作要具有防斥油性，防污性或脱模性等性能的各种工业基材，作为其原料。 这里，Af表示具体的含多氟烃基的有机基团， 彼此独立的R 1和R 2表示二价有机基团; 彼此独立的R3至R9表示一价有机基团; a是至少为1的整数，b是至少为0的整数：

公开(公告)号：US5834614A

公开(公告)日：1998-11-10

申请号：US847454

申请日：1997-04-23

申请人： Yutaka Furukawa ,  Mami Kotera ,  Seisaku Kumai ,  Gerald J. Murphy

发明人： Yutaka Furukawa ,  Mami Kotera ,  Seisaku Kumai ,  Gerald J. Murphy

IPC分类号： C08G77/22 ,  C08G77/385 ,  C07F7/08

CPC分类号： C08G77/385

摘要： A method for producing a fluorine-containing silicone compound, which comprises subjecting a fluorine-containing unsaturated compound of the following formula (1) and a hydrosilicone compound having at least one hydrogen atom bonded to a silicon atom to hydrosilylation in the presence of a catalyst to obtain a fluorine-containing silicone compound having a R.sup.f --Q--CR.sup.1 R.sup.2 --CHR.sup.3 --CR.sup.4 R.sup.5 -- group bonded to the silicon atom: R.sup.f --Q--CR.sup.1 R.sup.2 --CR.sup.3 .dbd.CR.sup.4 R.sup.5( 1) wherein R.sup.f is a monovalent fluorine-containing organic group, Q is a single bond or a bivalent organic group, and each of R.sup.1 to R.sup.5 which are independent of one another, is a hydrogen atom or a monovalent organic group, wherein the hydrosilylation is carried out substantially in the absence of a solvent.

摘要翻译： 一种含氟硅氧烷化合物的制造方法，其特征在于，将下述式（1）所示的含氟不饱和化合物与至少一个与硅原子键合的氢原子的氢硅氧烷化合物在催化剂存在下进行氢化硅烷化 得到具有与硅原子键合的Rf-Q-CR1R2-CHR3-CR4R5-基团的含氟硅氧烷化合物：Rf-Q-CR1R2-CR3 = CR4R5（1）其中Rf是一价含氟有机基团， Q是单键或二价有机基团，R 1〜R 5彼此独立的是氢原子或一价有机基团，其中氢化硅烷化基本上在没有溶剂的情况下进行。

公开(公告)号：US5728903A

公开(公告)日：1998-03-17

申请号：US779370

申请日：1997-01-06

申请人： Yutaka Furukawa ,  Mami Kotera ,  Seisaku Kumai ,  Kazuya Oharu ,  Toshihiko Toma

发明人： Yutaka Furukawa ,  Mami Kotera ,  Seisaku Kumai ,  Kazuya Oharu ,  Toshihiko Toma

IPC分类号： C08G77/385 ,  C07C17/15

CPC分类号： C08G77/385

摘要： A method for producing a fluorine-containing silicone compound, which comprises subjecting a compound of the following formula (I) and a hydrosilicone compound having at least one hydrogen atom bonded to a silicon atom to hydrosilylation to obtain a fluorine-containing silicone compound having a R.sup.f --Q--CR.sup.1 R.sup.2 CR.sup.3 HCR.sup.4 R.sup.5 -- group bonded to the silicon atom: R.sup.f --Q--CR.sup.1 R.sup.2 CR.sup.3 .dbd.CR.sup.4 R.sup.5(I) wherein R.sup.f is a monovalent fluorine-containing organic group, Q is a single bond or a bivalent organic group containing no fluorine atom, and each of R.sup.1 to R.sup.5 which are independent of one another, is a hydrogen atom or a monovalent organic group.

摘要翻译： 一种含氟硅氧烷化合物的制造方法，其特征在于，使下述式（I）的化合物与具有至少一个与硅原子键合的氢原子的氢硅氧烷化合物进行氢化硅烷化，得到具有 Rf-Q-CR1R2CR3HCR4R5-键合到硅原子上：Rf-Q-CR1R2CR3 = CR4R5（Ⅰ）其中Rf是一价含氟有机基团，Q是单键或不含氟原子的二价有机基团，和 彼此独立的R 1至R 5中的每一个为氢原子或一价有机基团。