公开(公告)号：US20090147446A1

公开(公告)日：2009-06-11

申请号：US12292485

申请日：2008-11-20

申请人： Yasuhisa Sugawara ,  Masako Ohya ,  Kazuyuki Katoh

发明人： Yasuhisa Sugawara ,  Masako Ohya ,  Kazuyuki Katoh

IPC分类号： H01G9/02 ,  C23C28/00

CPC分类号： H01G9/028 ,  H01G9/15 ,  Y10T29/417

摘要： The present invention provides a solid electrolytic capacitor having sufficiently low impedance at high frequencies in which a conductive polymer formed on a dielectric oxide film has good adherence to the dielectric oxide film, and a manufacturing method of the solid electrolytic capacitor. The solid electrolytic capacitor of the present invention includes a valve metal; a dielectric oxide film layer formed on a surface of the valve metal; and a solid electrolyte layer, comprising a conductive polymer layer, formed on the dielectric oxide film layer. The conductive polymer layer contains, as an additive, 0.1 wt % to 30 wt % of an organic oligomer having an average degree of polymerization of 2 to 100.

摘要翻译： 本发明提供一种固体电解电容器，其在高频下具有足够低的阻抗，其中在电介质氧化物膜上形成的导电聚合物对电介质氧化膜具有良好的粘附性，以及固体电解电容器的制造方法。 本发明的固体电解电容器包括阀金属; 形成在所述阀金属的表面上的电介质氧化物膜层; 以及形成在电介质氧化物膜层上的包含导电聚合物层的固体电解质层。 导电性聚合物层含有0.1重量％〜30重量％的平均聚合度为2〜100的有机低聚物作为添加剂。

公开(公告)号：US08295032B2

公开(公告)日：2012-10-23

申请号：US12292485

申请日：2008-11-20

申请人： Yasuhisa Sugawara ,  Masako Ohya ,  Kazuyuki Katoh

发明人： Yasuhisa Sugawara ,  Masako Ohya ,  Kazuyuki Katoh

IPC分类号： H01G9/02 ,  C23C28/00

CPC分类号： H01G9/028 ,  H01G9/15 ,  Y10T29/417

摘要： The present invention provides a solid electrolytic capacitor having sufficiently low impedance at high frequencies in which a conductive polymer formed on a dielectric oxide film has good adherence to the dielectric oxide film, and a manufacturing method of the solid electrolytic capacitor. The solid electrolytic capacitor of the present invention includes a valve metal; a dielectric oxide film layer formed on a surface of the valve metal; and a solid electrolyte layer, comprising a conductive polymer layer, formed on the dielectric oxide film layer. The conductive polymer layer contains, as an additive, 0.1 wt % to 30 wt % of an organic oligomer having an average degree of polymerization of 2 to 100.

摘要翻译： 本发明提供一种固体电解电容器，其在高频下具有足够低的阻抗，其中在电介质氧化物膜上形成的导电聚合物对电介质氧化膜具有良好的粘附性，以及固体电解电容器的制造方法。 本发明的固体电解电容器包括阀金属; 形成在所述阀金属的表面上的电介质氧化物膜层; 以及形成在电介质氧化物膜层上的包含导电聚合物层的固体电解质层。 导电性聚合物层含有0.1重量％〜30重量％的平均聚合度为2〜100的有机低聚物作为添加剂。

公开(公告)号：US07835138B2

公开(公告)日：2010-11-16

申请号：US12044337

申请日：2008-03-07

申请人： Daisuke Yamashita ,  Kazuhiro Koike ,  Kazuyuki Kato ,  Masako Ohya ,  Kunihiko Shimizu

发明人： Daisuke Yamashita ,  Kazuhiro Koike ,  Kazuyuki Kato ,  Masako Ohya ,  Kunihiko Shimizu

IPC分类号： H01G9/00

CPC分类号： H01G9/012 ,  H01G9/028 ,  Y10T29/41 ,  Y10T29/417

摘要： A solid electrolytic capacitor is provided in which volume efficiency of its capacitor element is improved. A converting substrate having an anode terminal forming portion and cathode terminal portion obtained by forming notches on faces exposed on outside faces of the anode and cathode portions and performing plating in the notches in portions in which the anode and cathode portions of a lower-face electrode type solid electrolytic capacitor is connected to the capacitor element and, after a sheathing resin is formed therein, the sheathed portion and converting substrate are cut along cutting planes to form fillet forming faces on the outside faces of the anode portion and cathode portion of the lower-face electrode type solid electrolytic capacitor.

摘要翻译： 提供了其电容器元件的体积效率提高的固体电解电容器。 一种具有阳极端子形成部分和阴极端子部分的转换基板，其通过在阳极和阴极部分的外表面上暴露的表面上形成凹口而获得，并且在凹部中进行电镀，其中下面电极的阳极部分和阴极部分 型固体电解电容器连接到电容器元件，并且在其中形成护套树脂之后，沿着切割平面切割护套部分和转换基板，以在下部的阳极部分和阴极部分的外表面上形成圆角形成面 表面电极型固体电解电容器。

公开(公告)号：US07717967B2

公开(公告)日：2010-05-18

申请号：US12205049

申请日：2008-09-05

申请人： Yasuhisa Sugawara ,  Masako Ohya ,  Katsuhiro Yoshida

发明人： Yasuhisa Sugawara ,  Masako Ohya ,  Katsuhiro Yoshida

IPC分类号： H01G9/00

CPC分类号： H01G9/15 ,  H01G9/0029 ,  H01G9/0032 ,  Y10T29/417

摘要： A method for manufacturing a solid electrolytic capacitor has the steps of: mixing valve metal powders with organic binder for granulation, press-molding granulated powders embedded with a valve metal lead, sintering a press-molded compact in vacuum to produce a sintered body, and anodizing the sintered body to form a dielectric oxide film layer. The method further has a step of performing a cathode electrolytic cleaning to the sintered body before the step of forming the dielectric oxide film layer. The cathode electrolytic cleaning is performed in an acid solution, which is a mixed acid solution of hydrofluoric acid, nitric acid, and sulfuric acid.

摘要翻译： 一种固体电解电容器的制造方法，是将阀金属粉末与造粒用有机粘合剂混合，嵌入阀金属引线的压制成粒粉末，在真空中烧结压制成型体以制造烧结体， 阳极氧化烧结体以形成电介质氧化物膜层。 该方法还具有在形成电介质氧化物膜层的步骤之前对烧结体进行阴极电解清洗的步骤。 阴极电解清洗是在氢氟酸，硝酸和硫酸的混合酸溶液的酸溶液中进行的。

公开(公告)号：US06532144B2

公开(公告)日：2003-03-11

申请号：US09949246

申请日：2001-09-07

申请人： Masako Ohya ,  Susumu Saitou

发明人： Masako Ohya ,  Susumu Saitou

IPC分类号： H01G9004

CPC分类号： H01G11/82 ,  H01G11/12 ,  H01G11/80 ,  Y02E60/13 ,  Y10T29/417

摘要： In an electric double layer capacitor, at least three frame-shaped gaskets are stacked. A cell member of a pair of polarized electrodes sandwiching a porous separator is accommodated within a central gasket so as to be sandwiched between a pair of current collectors. Upper and lower frame shaped gaskets are adhered on both side edges of the central gasket such that the current collectors are sandwiched and held with two gaskets confronting to seal the inside of the central gasket. A step portion is formed in an inner peripheral end surface of at least one of the gaskets confronting such that each of the side edges of the collectors is received in this step portion, whereby making it easy to position the current collector in the gasket. This step portion also makes it possible to bond the current collector to the gasket at a low stress. All surfaces of the side edges of the current collectors are contacted with the gaskets to improve the reliability of the electric double layer capacitor by preventing leaking of the electrolytic solution from the capacitor cell under the high temperature environment.

摘要翻译： 在双电层电容器中，堆叠至少三个框状垫片。 夹着多孔隔板的一对极化电极的电池部件容纳在中央密封垫内，夹在一对集电体之间。 上框架和下框架形垫片粘附在中央垫圈的两侧边缘上，使得集流器被夹持并保持两个垫圈以密封中心垫圈的内部。 在至少一个垫圈的内周端面上形成台阶部，面对这样的集合体的各边缘被容纳在该台阶部，由此容易将集电体定位在垫圈中。 该台阶部分也使得能够以低应力将集电体结合到垫圈。 集电器的侧边缘的所有表面都与垫片接触，以防止电解液在高温环境下从电容器电池泄漏而提高双电层电容器的可靠性。

公开(公告)号：US06377441B1

公开(公告)日：2002-04-23

申请号：US09362674

申请日：1999-07-29

申请人： Masako Ohya ,  Yoshiki Inoue

发明人： Masako Ohya ,  Yoshiki Inoue

IPC分类号： H01G9004

CPC分类号： H01G9/155 ,  H01G11/12 ,  H01G11/70 ,  H01G11/72 ,  H01G11/80 ,  H01G11/82 ,  Y02E60/13

摘要： An electric double-layer capacitor has a porous separator, a pair of polarizable electrodes confronting each other with the separator interposed therebetween, and an electrolytic solution, all accommodated in a gasket frame. The separator is electrically non-conductive and ion-permeable, and is impregnated with the electrolytic solution. The gasket frame has an opening sealed by a collector held against the surface of the polarizable electrode which faces away from the separator. The collector which seals the opening in the gasket frame comprises two laminated collector sheets. Since there is almost no possibility that both the two laminated collector sheets will crack or break, the electrolytic solution is reliably prevented from leaking out of the gasket.

摘要翻译： 电双层电容器具有多孔分离器，一对彼此面对的可分极化电极和分离器之间的电极，电解液全部容纳在垫圈框架中。 隔膜是非导电的和离子可渗透的，并且被电解液浸渍。 垫圈框架具有由集电器密封的开口，该收集器保持抵靠可偏振电极的远离分离器的表面。 密封垫片框架中的开口的收集器包括两个层压收集板。 由于两层叠集电体板几乎不会发生裂纹或断裂，电解液被可靠地防止从垫圈泄漏。

公开(公告)号：US20090059479A1

公开(公告)日：2009-03-05

申请号：US12044337

申请日：2008-03-07

申请人： Daisuke YAMASHITA ,  Kazuhiro Koike ,  Kazuyuki Kato ,  Masako Ohya ,  Kunihiko Shimizu

发明人： Daisuke YAMASHITA ,  Kazuhiro Koike ,  Kazuyuki Kato ,  Masako Ohya ,  Kunihiko Shimizu

IPC分类号： H01G9/012

CPC分类号： H01G9/012 ,  H01G9/028 ,  Y10T29/41 ,  Y10T29/417

摘要： A solid electrolytic capacitor is provided in which volume efficiency of its capacitor element is improved. A converting substrate having an anode terminal forming portion and cathode terminal portion obtained by forming notches on faces exposed on outside faces of the anode and cathode portions and performing plating in the notches in portions in which the anode and cathode portions of a lower-face electrode type solid electrolytic capacitor is connected to the capacitor element and, after a sheathing resin is formed therein, the sheathed portion and converting substrate are cut along cutting planes to form fillet forming faces on the outside faces of the anode portion and cathode portion of the lower-face electrode type solid electrolytic capacitor.

摘要翻译： 提供了其电容器元件的体积效率提高的固体电解电容器。 一种具有阳极端子形成部分和阴极端子部分的转换基板，其通过在阳极和阴极部分的外表面上暴露的表面上形成凹口而获得，并且在凹部中进行电镀，其中下面电极的阳极部分和阴极部分 型固体电解电容器连接到电容器元件，并且在其中形成护套树脂之后，沿着切割平面切割护套部分和转换基板，以在下部的阳极部分和阴极部分的外表面上形成圆角形成面 表面电极型固体电解电容器。

公开(公告)号：US06392868B1

公开(公告)日：2002-05-21

申请号：US09792056

申请日：2001-02-26

申请人： Masako Ohya ,  Kazuya Mimura ,  Yutaka Nakazawa ,  Satoshi Abe ,  Satoshi Arai ,  Takashi Yasuda ,  Toshihisa Nagasawa ,  Koji Sakata ,  Mitsuru Ogawa

发明人： Masako Ohya ,  Kazuya Mimura ,  Yutaka Nakazawa ,  Satoshi Abe ,  Satoshi Arai ,  Takashi Yasuda ,  Toshihisa Nagasawa ,  Koji Sakata ,  Mitsuru Ogawa

IPC分类号： H01G900

摘要： An electric double-layer capacitor has a pair of thrust plates for thrusting a stacked cell pair and a gasket for encapsulating the stacked cell pair together with the thrust plates. The thrust plate has slanted side surfaces for effecting a close contact with a packaging overcoat. The thrust plates and the mounting gasket are coupled together by an interdigitaion relationship.

公开(公告)号：US20100065434A1

公开(公告)日：2010-03-18

申请号：US12557612

申请日：2009-09-11

申请人： Yasuhisa SUGAWARA ,  Kazuyuki Katoh ,  Masako Ohya

发明人： Yasuhisa SUGAWARA ,  Kazuyuki Katoh ,  Masako Ohya

IPC分类号： C23C22/06

CPC分类号： H01G9/0036 ,  H01G9/028 ,  H01G9/15

摘要： In a method of manufacturing a solid electrolytic capacitor in which an electrolyte layer containing a conductive polymer is formed by chemical oxidative polymerization on a dielectric oxide film layer formed by anodizing surfaces of a valve metal, an ammonium peroxodisulfate solution adjusted to pH 6 to 8 is used as an oxidant in forming the conductive polymer layer.

摘要翻译： 在通过在通过阳极氧化阀金属表面形成的电介质氧化膜层上进行化学氧化聚合而形成含有导电性聚合物的电解质层的固体电解电容器的制造方法中，调节至pH6〜8的过二硫酸铵溶液为 在形成导电聚合物层时用作氧化剂。

公开(公告)号：US20090056093A1

公开(公告)日：2009-03-05

申请号：US12205049

申请日：2008-09-05

申请人： Yasuhisa Sugawara ,  Masako Ohya ,  Katsuhiro Yoshida

发明人： Yasuhisa Sugawara ,  Masako Ohya ,  Katsuhiro Yoshida

IPC分类号： H01G9/15

CPC分类号： H01G9/15 ,  H01G9/0029 ,  H01G9/0032 ,  Y10T29/417

摘要： A method for manufacturing a solid electrolytic capacitor has the steps of: mixing valve metal powders with organic binder for granulation, press-molding granulated powders embedded with a valve metal lead, sintering a press-molded compact in vacuum to produce a sintered body, and anodizing the sintered body to form a dielectric oxide film layer. The method further has a step of performing a cathode electrolytic cleaning to the sintered body before the step of forming the dielectric oxide film layer. The cathode electrolytic cleaning is performed in an acid solution, which is a mixed acid solution of hydrofluoric acid, nitric acid, and sulfuric acid.

摘要翻译： 一种固体电解电容器的制造方法，是将阀金属粉末与造粒用有机粘合剂混合，嵌入阀金属引线的压制成粒粉末，在真空中烧结压制成型体以制造烧结体， 阳极氧化烧结体以形成电介质氧化物膜层。 该方法还具有在形成电介质氧化物膜层的步骤之前对烧结体进行阴极电解清洗的步骤。 阴极电解清洗是在氢氟酸，硝酸和硫酸的混合酸溶液的酸溶液中进行的。