公开(公告)号：US3988290A

公开(公告)日：1976-10-26

申请号：US572957

申请日：1975-04-30

申请人： Melville W. Uffner

发明人： Melville W. Uffner

IPC分类号： C08K3/10 ,  C08F283/01 ,  C08F299/00 ,  C08F299/04 ,  C08K3/20 ,  C08K3/22 ,  C08L67/00 ,  C08L67/06

CPC分类号： C08F299/0464 ,  C08K3/22

摘要： This invention relates to an improvement in a process for preparing unsaturated polyester resins which are chemically thickened with a Group II metal oxide or hydroxide and the resulting product. The improvement for extending the shelf life of said molding compound while providing for enhanced curing rates at the molding temperature comprises:Incorporating at least an effective proportion of a cobaltic promotor in said molding compound for selectively extending the shelf life of said molding compound and for providing enhanced cure rate.

摘要翻译： 本发明涉及一种用II族金属氧化物或氢氧化物化学增稠的不饱和聚酯树脂的制备方法和所得产品的改进。 提高所述模塑料的保质期同时在成型温度下提供增强的固化速度的改进包括：

公开(公告)号：US4032596A

公开(公告)日：1977-06-28

申请号：US734295

申请日：1976-10-20

申请人： Melville W. Uffner ,  Burton D. Beitchman

发明人： Melville W. Uffner ,  Burton D. Beitchman

IPC分类号： C08F299/04 ,  C08L67/06

CPC分类号： C08F299/0457

摘要： Certain quaternary ammonium salts are incorporated in unsaturated polyester thermosetting molding compositions containing peroxyketal initiators to accelerate free radical initiated curing of these compositions.

公开(公告)号：US4309511A

公开(公告)日：1982-01-05

申请号：US045446

申请日：1979-06-04

申请人： Donald E. Jefferson ,  Charles G. Coe ,  Burton D. Beitchman ,  Melville W. Uffner

发明人： Donald E. Jefferson ,  Charles G. Coe ,  Burton D. Beitchman ,  Melville W. Uffner

IPC分类号： B01J31/02 ,  B01J31/04 ,  B01J31/30 ,  C08F299/04 ,  B01J31/12

CPC分类号： C08F299/0464 ,  B01J31/0237 ,  B01J31/04 ,  B01J31/06 ,  B01J31/182 ,  B01J31/30 ,  B01J2531/16 ,  B01J2531/845

摘要： This invention relates to an improved three component promoter for enhancing the cure rate of a molding compound comprising an unsaturated polyester resin and an unsaturated monomer copolymerizable therewith. The presence of the three component promoter system substantially enhances the cure rate of the molding compound while at the same time substantially lengthening the shelf life of the prepromoted resin. The three component system comprises a cobalt salt in the plus 2 valence state with the cobalt being present in an amount to provide from about 0.0005-0.06 parts cobalt metal per 100 parts unsaturated polyester resin (including unsaturated monomer), a copper salt, the salt being present in an amount to provide from 0.01-1.times.10.sup.-6 parts copper metal per 100 parts of unsaturated polyester resin (including unsaturated monomer), and an amine selected from the group consisting of tertiary amino alkyl acrylates and methacrylates, heterocyclic amines, para substituted aromatic amines and lower alkyl and alkanol amines (C.sub.1 -C.sub.6) and phenolic amines, the amine being present in an amount to provide from about 0.0001 to 0.05 moles per 100 parts of unsaturated polyester resin, including unsaturated monomer.

摘要翻译： 本发明涉及用于提高包含不饱和聚酯树脂和可与其共聚的不饱和单体的模塑料的固化速率的改进的三组分促进剂。 三组分促进剂体系的存在大大提高了模塑料的固化速率，同时基本上延长了预浸树脂的保质期。 三组分体系包括加2价态的钴盐，钴的存在量为每100份不饱和聚酯树脂（包括不饱和单体），铜盐，盐提供约0.0005-0.06份钴金属 以每100份不饱和聚酯树脂（包括不饱和单体）的0.01-1×10 -6份铜金属和选自叔氨基烷基丙烯酸酯和甲基丙烯酸酯，杂环胺，对位取代基 芳族胺和低级烷基和链烷醇胺（C1-C6）和酚胺，胺的存在量为每100份不饱和聚酯树脂（包括不饱和单体）提供约0.0001至0.05摩尔。

公开(公告)号：US4048086A

公开(公告)日：1977-09-13

申请号：US583500

申请日：1975-06-03

申请人： Melville W. Uffner

发明人： Melville W. Uffner

IPC分类号： C08F299/04 ,  C08K3/22 ,  C08G63/12

CPC分类号： C08F299/0464 ,  C08K3/22

摘要： This invention relates to an accelerator composition particularly adapted for providing extended shelf life to sheet and bulk molding compound while providing for accelerated cure rates at molding temperatures. The accelerator composition comprises in combination:A cobaltic promotor selected from the group consisting of cobaltic halides, cobaltic salts of monocarboxylic acids having from 2 to 20 carbon atoms, cobaltic sulfate, and cobaltic beta-diketones; andFrom about 1 to 4,500 parts, per part of cobaltic metal in said cobaltic promoter, of a coupler selected from the group consisting of oxides and hydroxides of calcium and magnesium.

摘要翻译： 本发明涉及一种促进剂组合物，特别适合于在片状和体积模塑料中提供延长的保存期限，同时在成型温度下提供加速的固化速率。 加速剂组合物组合包括：

公开(公告)号：US4138385A

公开(公告)日：1979-02-06

申请号：US830182

申请日：1977-09-02

申请人： Melville W. Uffner ,  Donald E. Jefferson ,  Charles G. Coe ,  Burton D. Beitchman

发明人： Melville W. Uffner ,  Donald E. Jefferson ,  Charles G. Coe ,  Burton D. Beitchman

IPC分类号： C08F299/04 ,  C08L67/00 ,  C08L67/06

CPC分类号： C08F299/0464

摘要： This invention relates to an improvement in a process for curing unsaturated polyester resins, preferably chemically thickened with a Group II metal oxide or hydroxide, and to the resulting product. The improvement resides in the use of an acetylacetonate ligand of cobalt III, which is mono, di, or tri-substituted with an electron withdrawing group, e.g. a nitro, phenyl or halogen atom.

摘要翻译： 本发明涉及用于固化不饱和聚酯树脂，优选用第II族金属氧化物或氢氧化物化学增稠的方法和所得产物的改进。 改进在于使用由吸电子基团单，二或三取代的钴III的乙酰丙酮配体。 硝基，苯基或卤原子。