公开(公告)号：US20090011236A1

公开(公告)日：2009-01-08

申请号：US11817190

申请日：2006-02-21

Applicant: Hisashi Kimura ,  Shinji Ono ,  Michio Higashijima

Inventor： Hisashi Kimura ,  Shinji Ono ,  Michio Higashijima

IPC: B32B5/16 ,  C08G63/183

CPC classification number: C08G63/826 ,  C08G63/80 ,  C08G63/85 ,  Y10T428/2982

Abstract: A problem of the invention is to provide a process for producing a polyester with high molecular weight and high quality and having practicality as a container material, etc., which is able to achieve the production for a relatively short period of time of solid phase polycondensation without using a complicated melt polycondensation reaction device and consequently at a low cost and with good efficiency.The invention is concerned with a continuous production process for continuously producing a polyester including an esterification step, a melt polycondensation step, a granulation step and a solid phase polycondensation step, wherein at least two kinds of a catalyst 1 and a catalyst 2 which are satisfied with the following requirements (1) to (3) are successively added as catalysts in two arbitrary different places prior to the granulation step; an intrinsic viscosity of the polyester prepolymer granule obtained in the granulation step is 0.18 dL/g or more and not more than 0.35 dL/g; and an intrinsic viscosity of the polyester obtained in the solid phase polycondensation step is 0.70 dL/g or more: (1) an activity ratio (K1) of the catalyst 1 is 0.5 or more, (2) an activity ratio (K2) of the catalyst 2 is less than 0.6, and (3) K1>K2 wherein the catalytic activity ratio is an index of a ratio of esterification reaction catalytic activity to the total sum of esterification reaction catalytic activity and ester exchange reaction catalytic activity of the catalyst and is defined according to a method described in the description.

Abstract translation: 本发明的问题是提供一种高分子量，高质量的聚酯的制造方法，作为容器材料等具有实用性的方法，其能够在相对短的时间内实现固相缩聚 而不使用复杂的熔融缩聚反应装置，因此以低成本和高效率。 本发明涉及连续生产聚酯的连续生产方法，包括酯化步骤，熔融缩聚步骤，造粒步骤和固相缩聚步骤，其中满足了至少两种催化剂1和催化剂2 在造粒步骤之前，在两个任意不同的地方连续添加以下要求（1）至（3）作为催化剂; 在造粒步骤中获得的聚酯预聚物颗粒的特性粘度为0.18dL / g以上且不大于0.35dL / g; 在固相缩聚工序中得到的聚酯的特性粘度为0.70dL / g以上：（1）催化剂1的活性比（K1）为0.5以上，（2）活性比（K2）为 催化剂2小于0.6，和（3）K1> K2，其中催化活性比是酯化反应催化活性与酯化反应催化活性和酯交换反应的总和之比的指标，催化剂的催化活性和 根据描述中描述的方法来定义。

公开(公告)号：US20110301322A1

公开(公告)日：2011-12-08

申请号：US13210781

申请日：2011-08-16

Applicant: Michio HIGASHIJIMA ,  Yutaka Yatsugi ,  Naoki Yukita ,  Motohiro Munakata

Inventor： Michio HIGASHIJIMA ,  Yutaka Yatsugi ,  Naoki Yukita ,  Motohiro Munakata

IPC: C08G63/85

CPC classification number: C08G63/83 ,  C08G63/85

Abstract: The invention provides: a polycondensation catalyst for polyester production, which contains titanium atoms, alkaline earth metal atoms and phosphorus atoms, has high reactivity and excellent long-term storage stability, can be easily produced industrially, and has an advantage in cost; a polyester resin obtained with the catalyst; and a molded article. These are: a polymerization catalyst for polyester production containing titanium atoms, alkaline earth metal atoms and phosphorus atoms and having a specific constitution; a polyester resin obtained with the catalyst; and a molded article.

Abstract translation: 本发明提供：含有钛原子，碱土金属原子和磷原子的聚酯制造用缩聚催化剂具有高反应性和优异的长期保存稳定性，可以容易地在工业上生产，并具有成本优势; 用催化剂得到的聚酯树脂; 和模制品。 它们是：含有钛原子，碱土金属原子和磷原子并具有特定构成的聚酯制造用聚合催化剂; 用催化剂得到的聚酯树脂; 和模制品。

公开(公告)号：US20090221420A1

公开(公告)日：2009-09-03

申请号：US12414891

申请日：2009-03-31

Applicant: Michio HIGASHIJIMA ,  Yutaka YATSUGI ,  Naoki YUKITA ,  Motohiro MUNAKATA

Inventor： Michio HIGASHIJIMA ,  Yutaka YATSUGI ,  Naoki YUKITA ,  Motohiro MUNAKATA

IPC: B01J31/12 ,  B01J31/02

CPC classification number: C08G63/85

Abstract: The invention relates to a liquid catalyst solution containing a polycondensation catalyst for polyester production, which contains titanium atoms, alkaline earth metal atoms and phosphorus atoms, has high reactivity and excellent long-term storage stability, can be easily produced industrially, and has an advantage in cost.

Abstract translation: 本发明涉及含有含钛原子，碱土金属原子和磷原子的聚酯生产缩聚催化剂的液体催化剂溶液，具有高反应性和优异的长期储存稳定性，可以容易地在工业上生产，并具有优势 在成本上。

公开(公告)号：US20090076242A1

公开(公告)日：2009-03-19

申请号：US11814454

申请日：2006-01-20

Applicant: Michio Higashijima ,  Yutaka Yatsugi ,  Naoki Yukita ,  Motohiro Munakata

Inventor： Michio Higashijima ,  Yutaka Yatsugi ,  Naoki Yukita ,  Motohiro Munakata

IPC: C08G63/83 ,  B01J31/12

CPC classification number: C08G63/85

Abstract: The invention provides: a polycondensation catalyst for polyester production, which contains titanium atoms, alkaline earth metal atoms and phosphorus atoms, has high reactivity and excellent long-term storage stability, can be easily produced industrially, and has an advantage in cost; a polyester resin obtained with the catalyst; and a molded article. These are: a polymerization catalyst for polyester production containing titanium atoms, alkaline earth metal atoms and phosphorus atoms and having a specific constitution; a polyester resin obtained with the catalyst; and a molded article.

Abstract translation: 本发明提供：含有钛原子，碱土金属原子和磷原子的聚酯制造用缩聚催化剂具有高反应性和优异的长期保存稳定性，可以容易地在工业上生产，并具有成本优势; 用催化剂得到的聚酯树脂; 和模制品。 它们是：含有钛原子，碱土金属原子和磷原子并具有特定构成的聚酯制造用聚合催化剂; 用催化剂得到的聚酯树脂; 和模制品。

公开(公告)号：US20110301020A1

公开(公告)日：2011-12-08

申请号：US13210755

申请日：2011-08-16

Applicant: Michio HIGASHIJIMA ,  Yutaka Yatsugi ,  Naoki Yukita ,  Motohiro Munakata

Inventor： Michio HIGASHIJIMA ,  Yutaka Yatsugi ,  Naoki Yukita ,  Motohiro Munakata

IPC: B01J31/02

CPC classification number: C08G63/83 ,  C08G63/85

Abstract: The invention provides: a polycondensation catalyst for polyester production, which contains titanium atoms, alkaline earth metal atoms and phosphorus atoms, has high reactivity and excellent long-term storage stability, can be easily produced industrially, and has an advantage in cost; a polyester resin obtained with the catalyst; and a molded article. These are: a polymerization catalyst for polyester production containing titanium atoms, alkaline earth metal atoms and phosphorus atoms and having a specific constitution; a polyester resin obtained with the catalyst; and a molded article.

公开(公告)号：US08039416B2

公开(公告)日：2011-10-18

申请号：US11814454

申请日：2006-01-20

Applicant: Michio Higashijima ,  Yutaka Yatsugi ,  Naoki Yukita ,  Motohiro Munakata

Inventor： Michio Higashijima ,  Yutaka Yatsugi ,  Naoki Yukita ,  Motohiro Munakata

IPC: B01J23/00

CPC classification number: C08G63/85

Abstract: The invention provides: a polycondensation catalyst for polyester production, which contains titanium atoms, alkaline earth metal atoms and phosphorus atoms, has high reactivity and excellent long-term storage stability, can be easily produced industrially, and has an advantage in cost; a polyester resin obtained with the catalyst; and a molded article. These are: a polymerization catalyst for polyester production containing titanium atoms, alkaline earth metal atoms and phosphorus atoms and having a specific constitution; a polyester resin obtained with the catalyst; and a molded article.

Abstract translation: 本发明提供：含有钛原子，碱土金属原子和磷原子的聚酯制造用缩聚催化剂具有高反应性和优异的长期保存稳定性，可以容易地在工业上生产，并具有成本优势; 用催化剂得到的聚酯树脂; 和模制品。 它们是：含有钛原子，碱土金属原子和磷原子并具有特定构成的聚酯制造用聚合催化剂; 用催化剂得到的聚酯树脂; 和模制品。

公开(公告)号：US08476183B2

公开(公告)日：2013-07-02

申请号：US13210755

申请日：2011-08-16

Applicant: Michio Higashijima ,  Yutaka Yatsugi ,  Naoki Yukita ,  Motohiro Munakata

Inventor： Michio Higashijima ,  Yutaka Yatsugi ,  Naoki Yukita ,  Motohiro Munakata

IPC: B01J23/00

CPC classification number: C08G63/83 ,  C08G63/85

Abstract: The invention provides: a polycondensation catalyst for polyester production, which contains titanium atoms, alkaline earth metal atoms and phosphorus atoms, has high reactivity and excellent long-term storage stability, can be easily produced industrially, and has an advantage in cost; a polyester resin obtained with the catalyst; and a molded article. These are: a polymerization catalyst for polyester production containing titanium atoms, alkaline earth metal atoms and phosphorus atoms and having a specific constitution; a polyester resin obtained with the catalyst; and a molded article.

Abstract translation: 本发明提供：含有钛原子，碱土金属原子和磷原子的聚酯制造用缩聚催化剂具有高反应性和优异的长期保存稳定性，可以容易地在工业上生产，并具有成本优势; 用催化剂得到的聚酯树脂; 和模制品。 它们是：含有钛原子，碱土金属原子和磷原子并具有特定构成的聚酯制造用聚合催化剂; 用催化剂得到的聚酯树脂; 和模制品。

公开(公告)号：US20110301019A1

公开(公告)日：2011-12-08

申请号：US13210685

申请日：2011-08-16

Applicant: Michio HIGASHIJIMA ,  Yutaka Yatsugi ,  Naoki Yukita ,  Motohiro Munakata

Inventor： Michio HIGASHIJIMA ,  Yutaka Yatsugi ,  Naoki Yukita ,  Motohiro Munakata

IPC: C08F4/00 ,  C08F4/16 ,  C08F4/10

CPC classification number: C08G63/85

Abstract: The invention provides: a polycondensation catalyst for polyester production, which contains titanium atoms, alkaline earth metal atoms and phosphorus atoms, has high reactivity and excellent long-term storage stability, can be easily produced industrially, and has an advantage in cost; a polyester resin obtained with the catalyst; and a molded article. These are: a polymerization catalyst for polyester production containing titanium atoms, alkaline earth metal atoms and phosphorus atoms and having a specific constitution; a polyester resin obtained with the catalyst; and a molded article.

公开(公告)号：US08039417B2

公开(公告)日：2011-10-18

申请号：US12414891

申请日：2009-03-31

Applicant: Michio Higashijima ,  Yutaka Yatsugi ,  Naoki Yukita ,  Motohiro Munakata

Inventor： Michio Higashijima ,  Yutaka Yatsugi ,  Naoki Yukita ,  Motohiro Munakata

IPC: B01J23/00

CPC classification number: C08G63/85

Abstract: The invention relates to a liquid catalyst solution containing a polycondensation catalyst for polyester production, which contains titanium atoms, alkaline earth metal atoms and phosphorus atoms, has high reactivity and excellent long-term storage stability, can be easily produced industrially, and has an advantage in cost.

Abstract translation: 本发明涉及含有含钛原子，碱土金属原子和磷原子的聚酯生产缩聚催化剂的液体催化剂溶液，具有高反应性和优异的长期储存稳定性，可以容易地在工业上生产，并具有优势 在成本上。