公开(公告)号：US4115440A

公开(公告)日：1978-09-19

申请号：US788722

申请日：1977-04-19

Applicant: Ming Nan Sheng ,  Jar-lin Kao

Inventor： Ming Nan Sheng ,  Jar-lin Kao

IPC: C07C51/00 ,  C07C51/25 ,  C07C409/24 ,  C07C409/38 ,  C07C51/32 ,  C07C57/04

CPC classification number: C07C51/252 ,  C07C407/00 ,  C07C51/00

Abstract: A process for the preparation of acrylic acid or methacrylic acid which comprises catalytically decomposing or converting in the presence of selenium the peroxide (peroxy) compounds formed during autoxidation or contained in the oxidate solution derived from the autoxidation of the respective acrolein or methacrolein, particularly, the conversion of permethacrylic acid and methacrolein monopermethacrylate to methacrylic acid.

Abstract translation: 一种制备丙烯酸或甲基丙烯酸的方法，其包括在硒存在下催化分解或转化过氧化物（过氧化物）化合物，其在自氧化过程中形成或包含在衍生自相应的丙烯醛或甲基丙烯醛的自氧化的氧化物溶液中， 甲基丙烯酸和甲基丙烯醛单甲基丙烯酸酯转化为甲基丙烯酸。

公开(公告)号：US4022681A

公开(公告)日：1977-05-10

申请号：US644252

申请日：1975-12-24

Applicant: Ming Nan Sheng ,  Walter Anthony Mameniskis ,  Patrick Walter Ryan

Inventor： Ming Nan Sheng ,  Walter Anthony Mameniskis ,  Patrick Walter Ryan

IPC: B01J29/18 ,  C10G47/16 ,  C10G65/12 ,  C10G37/06

CPC classification number: B01J29/18 ,  C10G2400/30

Abstract: A light gas oil, consisting predominantly of alkylated naphthalenes plus minor amounts of thiophene, quinoline, indan, and related naphthalene type carbonaceous compounds, derived from the liquid by-product from olefin production by pyrolysis in steam of a hydrocarbon fraction, is converted to mononuclear aromatic hydrocarbons by a two stage process in which said naphthalene type carbonaceous compounds are first hydrogenated at tetralinizing conditions saturating only one of the two aromatic rings of the feedstock. Said first stage hydrogenation also hydrodesulfurizes and hydrodecontaminates said feedstock. The tetralanized desulfurized normally liquid effluent from the first stage hydrogenation is hydrocracked in the second stage, said hydrocracking being in the presence of a catalyst featuring a stabilizing metal component on an acid-modified mordenite having a silica to alumina unit mol ratio within the range from 15 to 70 as a result of acid leaching of mordenite.

Abstract translation: 主要由烷基化萘加少量噻吩，喹啉，茚满和相关萘型碳质化合物组成的轻瓦斯油转化成单核，其衍生自通过在烃馏分的蒸汽中裂解产生的烯烃的液体副产物 芳族烃通过两阶段方法，其中所述萘型碳质化合物首先在仅饱和原料的两个芳环中的一个芳环的四氢化条件下氢化。 所述第一阶段氢化还加氢脱硫并对所述原料进行水合氯化。 在第二阶段加氢裂化来自第一阶段氢化的四氢化脱硫的正常液体流出物，所述加氢裂化在催化剂存在下，其特征在于在酸改性的丝光沸石上具有稳定的金属组分，其二氧化硅与氧化铝的单位摩尔比在 15〜70是丝光沸石酸浸的结果。

公开(公告)号：US3997578A

公开(公告)日：1976-12-14

申请号：US576414

申请日：1975-05-12

Applicant: Ming Nan Sheng

Inventor： Ming Nan Sheng

IPC: C07C51/285 ,  C07C51/26 ,  C07C51/24 ,  C07C51/28

CPC classification number: C07C51/285

Abstract: A process for the preparation of fatty acids by the oxidation of alcohols, particularly, primary alcohols, such as, octanol-1 and vicinal-diols, such as cyclohexane-1,2-diol, in which the alcohol is contacted with a peracid as an oxidizing agent in the presence of a ruthenium catalyst, such as, ruthenium chloride, ruthenium dioxide, etc., and an inert organic solvent, such as, heptane, hexane, chloroform, carbon tetrachloride, etc. If desired the process may include the addition of an organic or inorganic base, such as amines, and alkali metal and alkaline earth metal hydroxides, carbonates, phosphates, etc.

Abstract translation: 通过醇，特别是伯醇，如辛醇-1和邻二醇如环己烷-1,2-二醇的氧化制备脂肪酸的方法，其中醇与过酸接触作为 在钌催化剂如氯化钌，二氧化钌等存在下的氧化剂和惰性有机溶剂如庚烷，己烷，氯仿，四氯化碳等。如果需要，该方法可以包括 添加有机或无机碱如胺，碱金属和碱土金属氢氧化物，碳酸盐，磷酸盐等