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    Process for producing unsaturated aldehydes, and unsaturated fatty acids
    3.
    发明授权
    Process for producing unsaturated aldehydes, and unsaturated fatty acids 失效
    生产不饱和醛和不饱和脂肪酸的方法

    公开(公告)号：US4111984A

    公开(公告)日：1978-09-05

    申请号：US667371

    申请日：1976-03-16

    申请人： Hiromichi Ishii ,  Hideo Matsuzawa ,  Masao Kobayashi ,  Kantaro Yamada

    发明人： Hiromichi Ishii ,  Hideo Matsuzawa ,  Masao Kobayashi ,  Kantaro Yamada

    IPC分类号： B01J23/887 ,  C07C45/34 ,  C07C45/37 ,  C07C51/25 ,  C07C51/24 ,  C07C51/32

    CPC分类号： C07C45/37 ,  B01J23/8876 ,  C07C45/35 ,  C07C51/252 ,  B01J2523/00

    摘要： At least one compound from the group of unsaturated hydrocarbons of three to four carbon atoms and t-butyl alcohol is oxidized catalytically in the gas phase in the presence of molecular oxygen at 200.degree.-450.degree. C to produce the corresponding aldehyde or acid over a calcined catalyst of the formula Mo.sub.a Sb.sub.b Bi.sub.c Fe.sub.d Ni.sub.e Sn.sub.f X.sub.g Y.sub.h O.sub.i wherein X is at least one of potassium, rubidium or cesium, Y is at least one of cobalt, uranium, germanium, tungsten or titanium, a to h are atomic ratios wherein a=12, b=0.2 to 20, c=0.2 to 12, d=0.2 to 12, e=0.2 to 12, f=0 to 20, g=0.01 to 4 and h=0 to 6 and i is a value determined by the oxidation state of the metal atoms in the catalyst.An embodiment of the calcined catalyst of the invention has the formula Mo.sub.a Sb.sub.b Bi.sub.c Fe.sub.d Ni.sub.e Sn.sub.f X.sub.g Y.sub.h Z.sub.j O.sub.i wherein X and y are as defined above and Z is palladium and a to j are atomic ratios wherein a=12, b=0.2 to 20, c=0.2 to 12, d=0.2 to 12, e=0.2 to 12, f=0 to 20, g=0.01 to 4, h=0.01 to 3, j=0.01 to 3 and i assumes a value determined by the oxidation states of the metal atoms in the catalyst.

    摘要翻译： 在200-450℃的分子氧存在下，气相中氧化至少一种来自三至四个碳原子的不饱和烃基的化合物和叔丁醇，以产生相应的醛或酸 其中X为钾，铷或铯中的至少一种，Y为钴，铀，锗，钨或钛中的至少一种，a至h为原子比，其中a = 12，b = 0.2〜 20，c = 0.2〜12，d = 0.2〜12，e = 0.2〜12，f = 0〜20，g = 0.01〜4，h = 0〜6，i为金属的氧化态 本发明的煅烧催化剂的一个实施方案具有式MoaSbbBicFedNieSnfXgYhZjOi其中X和y如上所定义，Z是钯，a至j是原子比，其中a = 12，b = 0.2至20，c = 0.2〜12，d = 0.2〜12，e = 0.2〜12，f = 0〜20，g = 0.01〜4，h = 0.01〜3，j = 0.01〜3， 由催化剂中的金属原子的氧化态引起。

    Oxidation catalyst
    5.
    发明授权
    Oxidation catalyst 失效
    氧化催化剂

    公开(公告)号：US3985680A

    公开(公告)日：1976-10-12

    申请号：US623155

    申请日：1975-10-16

    申请人： George C. Allen

    发明人： George C. Allen

    IPC分类号： B01J23/34 ,  C07C51/25 ,  B01J29/16 ,  C07C51/24

    CPC分类号： C07C51/25 ,  B01J23/34 ,  C07C51/252

    摘要： Disclosed is an oxidation catalyst which is particularly useful for the conversion of unsaturated aldehydes to the corresponding unsaturated carboxylic acid. The catalyst has the following empirical formula Mo.sub.a V.sub.b W.sub.c Mn.sub.d O.sub.e.

    摘要翻译： 公开了一种氧化催化剂，其特别可用于将不饱和醛转化为相应的不饱和羧酸。 催化剂具有以下经验式MoaVbWcMndOe。

    Production of adipic acid from acidic wash waters
    9.
    发明授权
    Production of adipic acid from acidic wash waters 失效
    从酸性洗涤水中生产己二酸

    公开(公告)号：US4227021A

    公开(公告)日：1980-10-07

    申请号：US901235

    申请日：1978-04-28

    申请人： Otto-Alfred Grosskinsky ,  Norbert Petri ,  Johannes Hein ,  Hans Leitner

    发明人： Otto-Alfred Grosskinsky ,  Norbert Petri ,  Johannes Hein ,  Hans Leitner

    IPC分类号： C07C55/14 ,  C07C51/00 ,  C07C51/42 ,  C07C51/487 ,  C07C67/00 ,  C07C51/24

    CPC分类号： C07C51/487

    摘要： An improved process for producing adipic acid from the acidic wash waters which arise in the process for oxidizing cyclohexane with air, by treatment with nitric acid at from 10.degree. to 50.degree. C., with removal of the heat of reaction by external cooling, wherein the reaction mixture is led, at a flow velocity of at least 2.0 m/sec, as a thin layer spirally in counter-current to the coolant, under conditions which do not perturb the flow of the reaction mixture.

    摘要翻译： 通过在10℃至50℃下用硝酸处理，通过外部冷却除去反应热而在由空气氧化环己烷的过程中产生的酸性洗涤水中生产己二酸的改进方法，其中 在不干扰反应混合物的流动的条件下，反应混合物以至少2.0m / sec的流速被引导为与冷却剂逆流螺旋形的薄层。

    Catalyst for producing methacrylic acid
    10.
    发明授权
    Catalyst for producing methacrylic acid 失效
    用于生产甲基丙烯酸的催化剂

    公开(公告)号：US4172051A

    公开(公告)日：1979-10-23

    申请号：US826185

    申请日：1977-08-19

    申请人： Mutsumi Matsumoto ,  Atsushi Sudo ,  Hideki Sugi

    发明人： Mutsumi Matsumoto ,  Atsushi Sudo ,  Hideki Sugi

    IPC分类号： B01J23/16 ,  B01J23/00 ,  B01J23/28 ,  B01J23/887 ,  B01J27/00 ,  B01J27/14 ,  B01J27/199 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/04 ,  C07C57/055 ,  C07C67/00 ,  C07C51/24

    CPC分类号： B01J27/199 ,  B01J23/002 ,  B01J23/28 ,  B01J23/8877 ,  C07C51/252 ,  B01J2523/00

    摘要： This invention relates to a process and catalyst for producing methacrylic acid by the oxidation of methacrolein. More specifically, it relates to a process for producing methacrylic acid from methacrolein by oxidizing the same with molecular oxygen or molecular oxygen-containing gas, which is characterized by the use of a composition, as a catalyst, having a heteropolyacid structure and the general formula:Mo.sub.a V.sub.b P.sub.c Al.sub.d Y.sub.e O.sub.fwherein Mo, V, P, Al and O represent respectively molybdenum, vanadium, phosphorus, aluminum and oxygen, Y represents one or more elements selected from the groups consisting of copper, tine, cobalt, iron, zirconium, thorium, lead and cerium, and suffixes a, b, c, d, e and f represent the atomic ratio of the elements where, a is 10, b is a number of 3 or less than 3 excluding 0 and, preferably, 0.5 to 2, c is a number of 0.5 to 10 and, preferably, 0.5 to 3, d is a number of 3 or less than 3 excluding 0, preferably, 0.01 to 1.0, e is a number of 0 to 3, preferably, 0.01 to 0.5, and f is usually a number of 35 to 80 being determined depending on the valency and the ratio of number of atoms of other elements.

    摘要翻译： 本发明涉及通过甲基丙烯醛氧化生产甲基丙烯酸的方法和催化剂。 更具体地说，本发明涉及由甲基丙烯醛生产甲基丙烯酸的方法，其通过用分子氧或含分子氧的气体进行氧化，其特征在于使用具有杂多酸结构的组合物作为催化剂，通式 ：