公开(公告)号：US06172129B2

公开(公告)日：2001-01-09

申请号：US09240940

申请日：1999-01-29

Applicant: Ming Xin Fan ,  Gary Ceska ,  James P. Horgan ,  Henry C. Miller ,  Edward A. Jurczak

Inventor： Ming Xin Fan ,  Gary Ceska ,  James P. Horgan ,  Henry C. Miller ,  Edward A. Jurczak

IPC: C08F248

CPC classification number: C07D295/15 ,  C09D4/00 ,  C09D11/101 ,  C08F246/00 ,  C08F222/22

Abstract: (Meth)acrylate functional compound which is the reaction product of a cyclic secondary amine and a poly(meth)acrylate having at least three acrylate or methacrylate groups, useful for radiation curable coating or ink composition having low viscosity, low volatility, and high cure rate under radiation. Process of preparing a coating or ink composition using such compound. Radiation cured coating or ink based on such composition. Coated or printed article having such a cured coating or ink based on such composition.

Abstract translation: （甲基）丙烯酸酯官能化合物，它是环状仲胺和具有至少三个丙烯酸酯或甲基丙烯酸酯基的聚（甲基）丙烯酸酯的反应产物，可用于可辐射固化涂料或具有低粘度，低挥发性和高固化性的油墨组合物 辐射率。 使用这种化合物制备涂料或油墨组合物的方法。 基于这种组成的辐射固化涂层或油墨。 基于该组合物，具有这种固化涂层或油墨的涂布或印刷制品。

公开(公告)号：US5169962A

公开(公告)日：1992-12-08

申请号：US583524

申请日：1990-09-17

Applicant: James V. Crivello ,  Ming-Xin Fan

Inventor： James V. Crivello ,  Ming-Xin Fan

IPC: B01J31/20 ,  B01J31/22 ,  B01J31/24 ,  B01J31/30 ,  C07B61/00 ,  C07F7/08 ,  C07F7/21 ,  C08G59/20 ,  C08G59/30 ,  C08G77/38 ,  C08L83/06

CPC classification number: C08G77/38 ,  C07F7/0879 ,  C08L83/06

Abstract: A method for making an epoxyfunctional organosilicon compound is provided, comprising the step of reacting at a temperature of from about 25.degree. to about 100.degree. C. a mixture comprising (A) an ethylenically unsaturated epoxide; (B) an organohydrogenpolysiloxane or organohydrogensilane; and (C) a rhodium complex catalyst selected from the group consisting of:(i) RhX.sub.3 (SR.sub.2).sub.3 ;(ii) RhX.sub.3 .multidot.xH.sub.2 O;(iii) [RhX(norbornadiene)].sub.2 ;(iv) RhX(CO)(R.sub.3 P).sub.3 ;(v) RhX(R.sub.3 P).sub.3 ; and(vi) [RhCl(cyclooctadiene)].sub.2 ;wherein X is a halogen atom, x is a number equal to 3 or 4, and R is an alkyl radical having from 1 to 8 inclusive carbon atoms, aryl, aralkyl, or alkaryl radical or the R.sub.3.sup.1 SiQ-- group in which Q represents a divalent aliphatic hydrocarbon radical having from 1 to 6 inclusive carbon atoms and R.sup.1 represents an alkyl radical having from 1 to 8 inclusive carbon atoms, aryl, aralkyl, or alkaryl radical or a (CH.sub.3).sub.3 Si-- radical.

公开(公告)号：US5412054A

公开(公告)日：1995-05-02

申请号：US159760

申请日：1993-11-30

Applicant: James V. Crivello ,  Ming-Xin Fan

Inventor： James V. Crivello ,  Ming-Xin Fan

IPC: C08G65/02 ,  B01J31/20 ,  C08G65/10 ,  C08G65/12

CPC classification number: B01J31/1608 ,  B01J31/20 ,  C08G65/12 ,  B01J2231/14 ,  B01J2231/323 ,  B01J2531/0211 ,  B01J2531/845

Abstract: A catalyst: mixture for ring-opening polymerization of heterocyclic monomers and polymers includes a catalyst composed of a cobalt carbonyl complex; and a cocatalyst composed of at least one Si-H-containing compound. A curable composition, which may be a two-part kit, is also disclosed and includes the catalyst; the cocatalyst; and at least one polymerizable compound which is a monomer or polymer containing a heterocyclic ring. A method of producing a polymeric product by ring-opening polymerization of heterocyclic monomers and polymers is also disclosed which includes the steps of preparing a mixture including a catalyst composed of a cobalt carbonyl complex, a cocatalyst composed of at least one Si-H-containing compound, and at least one polymerizable compound which is a monomer or polymer containing a heterocyclic ring; and reacting the mixture, preferably at about room temperature, to promote ring-opening polymerization of the at least one polymerizable compound to produce the polymeric product.

Abstract translation: 催化剂：用于杂环单体和聚合物的开环聚合的混合物包括由羰基钴络合物组成的催化剂; 和由至少一种含Si-H的化合物组成的助催化剂。 还公开了可以是两部分试剂盒的可固化组合物，并且包括催化剂; 助催化剂; 以及作为含有杂环的单体或聚合物的至少一种聚合性化合物。 还公开了通过杂环单体和聚合物的开环聚合制备聚合物的方法，其包括以下步骤：制备包含由羰基钴配合物组成的催化剂的催化剂，由至少一种含Si-H 化合物和至少一种可聚合化合物，其是含有杂环的单体或聚合物; 并使混合物优选在约室温下反应，以促进至少一种可聚合化合物的开环聚合以产生聚合产物。