公开(公告)号：US20120007046A1

公开(公告)日：2012-01-12

申请号：US13179885

申请日：2011-07-11

Applicant: Nanditha Dissanayake ,  Zhaohui Zhong

Inventor： Nanditha Dissanayake ,  Zhaohui Zhong

IPC: H01L51/44 ,  H01L51/48 ,  B82Y40/00 ,  B82Y15/00

CPC classification number: B82Y30/00 ,  B82Y10/00 ,  H01L51/0036 ,  H01L51/0048 ,  H01L51/4253 ,  Y02E10/549

Abstract: Systems, methods and devices for the efficient photocurrent generation in single- or multi-walled carbon nanotubes, which includes (SWNTs)/poly [3-hexylthiophene-2,5-diyl] (P3HT) hybrid photovoltaics, and exhibit the following features: photocurrent measurement at individual SWNT/P3HT heterojunctions indicate that both semiconducting (s-) and metallic (m-) SWNTs function as excellent hole acceptors; electrical transport and gate voltage dependent photocurrent indicate that P3HT p-dopes both s-SWNT and m-SWNT, and exciton dissociation is driven by a built-in voltage at the heterojunction. Some embodiments include a mm2 scale SWNT/P3HT bilayer hybrid photovoltaics using horizontally aligned SWNT arrays, which exhibit greater than 90% effective external quantum efficiency, among other things, which advantageously provide carbon nanomaterial based low cost and high efficiency hybrid photovoltaics.

Abstract translation: 包括（SWNTs）/聚[3-己基噻吩-2,5-二基]（P3HT）混合光伏在单壁或多壁碳纳米管中有效的光电流产生的系统，方法和装置，并且具有以下特征： 单个SWNT / P3HT异质结的光电流测量表明半导体（s-）和金属（m-）SWNTs都用作优异的空穴受体; 电传输和栅极电压依赖光电流表明P3HT p掺杂s-SWNT和m-SWNT，并且激子解离由异质结内的电压驱动。 一些实施例包括使用水平对准的SWNT阵列的mm2尺度的SWNT / P3HT双层混合光伏，其显示出大于90％的有效外部量子效率，其有利地提供基于碳纳米材料的低成本和高效率混合光伏。

公开(公告)号：US08502195B2

公开(公告)日：2013-08-06

申请号：US13179885

申请日：2011-07-11

Applicant: Nanditha Dissanayake ,  Zhaohui Zhong

Inventor： Nanditha Dissanayake ,  Zhaohui Zhong

IPC: H01L29/06

CPC classification number: B82Y30/00 ,  B82Y10/00 ,  H01L51/0036 ,  H01L51/0048 ,  H01L51/4253 ,  Y02E10/549

Abstract: Systems, methods and devices for the efficient photocurrent generation in single- or multi-walled carbon nanotubes, which includes (SWNTs)/poly [3-hexylthiophene-2,5-diyl] (P3HT) hybrid photovoltaics, and exhibit the following features: photocurrent measurement at individual SWNT/P3HT heterojunctions indicate that both semiconducting (s-) and metallic (m-) SWNTs function as excellent hole acceptors; electrical transport and gate voltage dependent photocurrent indicate that P3HT p-dopes both s-SWNT and m-SWNT, and exciton dissociation is driven by a built-in voltage at the heterojunction. Some embodiments include a mm2 scale SWNT/P3HT bilayer hybrid photovoltaics using horizontally aligned SWNT arrays, which exhibit greater than 90% effective external quantum efficiency, among other things, which advantageously provide carbon nanomaterial based low cost and high efficiency hybrid photovoltaics.

Abstract translation: 包括（SWNTs）/聚[3-己基噻吩-2,5-二基]（P3HT）混合光伏在单壁或多壁碳纳米管中有效的光电流产生的系统，方法和装置，并且具有以下特征： 单个SWNT / P3HT异质结的光电流测量表明半导体（s-）和金属（m-）SWNTs都用作优异的空穴受体; 电传输和栅极电压依赖光电流表明P3HT p掺杂s-SWNT和m-SWNT，并且激子解离由异质结内的电压驱动。 一些实施例包括使用水平对准的SWNT阵列的mm2尺度的SWNT / P3HT双层混合光伏，其显示出大于90％的有效外部量子效率，其有利地提供基于碳纳米材料的低成本和高效率混合光伏。