公开(公告)号：US08062619B2

公开(公告)日：2011-11-22

申请号：US12697642

申请日：2010-02-01

申请人： Julien Grandjean ,  Nicolas Ferrando ,  Abdelhakim Koudil ,  P-Louis Carrette

发明人： Julien Grandjean ,  Nicolas Ferrando ,  Abdelhakim Koudil ,  P-Louis Carrette

IPC分类号： C01B17/04 ,  C01B17/05

CPC分类号： B01D53/523 ,  B01D53/002 ,  B01D53/8612 ,  B01D2255/202 ,  C01B17/05

摘要： A process and apparatus for the treatment of a gas that contains hydrogen sulfide and sulfurous anhydride, in which: a) the gas (3) contacts with an organic solvent (1) containing a catalyst in a gas-liquid reactor-contactor (2) so as to recover separately liquid sulfur and; a gas effluent containing sulfur vapor; subjecting the gas effluent to a first condensation zone (7) operating at 70-100° C. to deposit the sulfur in solid form on sufficiently cold walls of the equipment in zone (7), recovering resultant purified gas containing less than 30 ppm by volume of sulfur melting the deposited solid sulfur to regenerate the equipment, and recycling resultant liquefied sulfur to the reactor contactor.

摘要翻译： 一种用于处理含有硫化氢和亚硫酸酐的气体的方法和装置，其中：a）气体（3）在气液反应器 - 接触器（2）中与含有催化剂的有机溶剂（1）接触， 以便单独回收液态硫和; 含有硫蒸汽的气体流出物; 将气体流出物经受在70-100℃操作的第一冷凝区（7），以固体形式将硫沉积在区域（7）中的设备的足够冷的壁上，通过以下步骤回收产生的纯度小于30ppm的气体： 硫的体积溶解沉积的固体硫以再生设备，并将所得液化硫再循环到反应器接触器。

公开(公告)号：US08257467B2

公开(公告)日：2012-09-04

申请号：US12637932

申请日：2009-12-15

申请人： Nicolas Ferrando ,  Julien Grandjean ,  Abdelhakim Koudil ,  Pascal Mougin ,  Jean-Pierre Ballaguet

发明人： Nicolas Ferrando ,  Julien Grandjean ,  Abdelhakim Koudil ,  Pascal Mougin ,  Jean-Pierre Ballaguet

IPC分类号： B01D53/14

CPC分类号： B01D53/263 ,  B01D53/1425 ,  B01D2257/80 ,  C07C7/11 ,  C10K1/08

摘要： A process for partial dehydration of a gas by contact with a solvent that can be regenerated by: a) A stage for absorption of H2O by contact of the gas to be treated and regenerated solvent producing a dehydrated gas effluent and a liquid solvent effluent that is charged with H2O and absorbed gas, b) A stage for cooling the solvent charged with H2O at ambient temperature, c) A stage for separation by segregation during which liquid H2O and the solvent are separated at ambient temperature, d) A stage in which the regenerated solvent that is obtained at the end of stage c) is heated, e) A stage in which the regenerated and heated solvent that is obtained at the end of stage d) is recycled to the absorption stage a).

摘要翻译： 通过与可以通过以下方式再生的溶剂接触的气体部分脱水的方法：a）通过接触待处理气体和再生溶剂吸收H 2 O的阶段，产生脱水气体流出物和液体溶剂流出物，其为 充入H 2 O和吸收的气体，b）在环境温度下用于冷却加入H 2 O的溶剂的阶段，c）在环境温度下分离液体H 2 O和溶剂的分离阶段，d）在 在阶段c）结束时获得的再生溶剂被加热，e）在阶段d）结束时获得的再生和加热溶剂再循环到吸收阶段a）的阶段。

公开(公告)号：US20100196240A1

公开(公告)日：2010-08-05

申请号：US12697642

申请日：2010-02-01

申请人： Julien Grandjean ,  Nicolas Ferrando ,  Abdelhakim Koudil ,  P-Louis Carrette

发明人： Julien Grandjean ,  Nicolas Ferrando ,  Abdelhakim Koudil ,  P-Louis Carrette

IPC分类号： B01D53/48 ,  B01J19/00

CPC分类号： B01D53/523 ,  B01D53/002 ,  B01D53/8612 ,  B01D2255/202 ,  C01B17/05

摘要： The invention has as its object a process for the treatment of a gas that contains hydrogen sulfide and sulfurous anhydride, in which: a) The gas (3) is brought into contact with an organic solvent (1) that contains a catalyst in at least one gas-liquid reactor-contactor (2); a gas effluent that contains vapor sulfur and liquid sulfur is recovered separately, b) Said gas effluent is introduced into a first condensation zone (7) that operates at a temperature of between 70 and 100° C. so that the sulfur that is contained in said gas effluent is deposited in solid form on the so-called cold walls of the equipment of the zone (7), c) When the clogging limit of said equipment of zone (7) is reached, said equipment is regenerated so as to melt the solid sulfur that is deposited inside said equipment for obtaining a liquid effluent, d) Said liquid effluent is recycled in the reactor-contactor, e) A purified gas that contains less than 30 ppm by volume of sulfur is extracted from the zone (7). An installation that allows the implementation of the process is also described.

摘要翻译： 本发明的目的是用于处理包含硫化氢和亚硫酸酐的气体的方法，其中：a）使气体（3）至少与含有催化剂的有机溶剂（1）接触， 一个气液反应器 - 接触器（2）; 含有蒸气硫和液态硫的气体流出物分开回收，b）将所述气体流出物引入第一个冷凝区（7），其在70至100℃的温度下运行，使得 所述气体流出物以固体形式沉积在所述区域（7）的设备的所谓冷壁上，c）当达到所述设备（7）的堵塞极限时，所述设备被再生以便熔化 沉积在所述设备内用于获得液体流出物的固体硫，d）所述液体流出物在反应器 - 接触器中再循环，e）从区域（7）中提取含有少于30ppm体积的硫的净化气体 ）。 还描述了允许执行该过程的安装。

公开(公告)号：US20100154638A1

公开(公告)日：2010-06-24

申请号：US12637932

申请日：2009-12-15

申请人： Nicolas FERRANDO ,  Julien GRANDJEAN ,  Abdelhakim KOUDIL ,  Pascal MOUGIN ,  Jean-Pierre BALLAGUET

发明人： Nicolas FERRANDO ,  Julien GRANDJEAN ,  Abdelhakim KOUDIL ,  Pascal MOUGIN ,  Jean-Pierre BALLAGUET

IPC分类号： B01D53/14

CPC分类号： B01D53/263 ,  B01D53/1425 ,  B01D2257/80 ,  C07C7/11 ,  C10K1/08

摘要： A process for partial dehydration of a gas by contact with a solvent that can be regenerated by: a) A stage for absorption of H2O by contact of the gas to be treated and regenerated solvent producing a dehydrated gas effluent and a liquid solvent effluent that is charged with H2O and absorbed gas, b) A stage for cooling the solvent charged with H2O at ambient temperature, c) A stage for separation by segregation during which liquid H2O and the solvent are separated at ambient temperature, d) A stage in which the regenerated solvent that is obtained at the end of stage c) is heated, e) A stage in which the regenerated and heated solvent that is obtained at the end of stage d) is recycled to the absorption stage a).

摘要翻译： 通过与可以通过以下方式再生的溶剂接触的气体部分脱水的方法：a）通过接触待处理气体和再生溶剂吸收H 2 O的阶段，产生脱水气体流出物和液体溶剂流出物，其为 充入H 2 O和吸收的气体，b）在环境温度下用于冷却加入H 2 O的溶剂的阶段，c）在环境温度下分离液体H 2 O和溶剂的分离阶段，d）在 在阶段c）结束时获得的再生溶剂被加热，e）在阶段d）结束时获得的再生和加热溶剂再循环到吸收阶段a）的阶段。