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1.发明授权Absorbent solution based on N, N, N′, N′-tetramethylhexane-1,6-diamine and on a particular amine comprising primary or secondary amine functions and method for removing acid compounds from a gaseous effluent 有权基于N，N，N'，N'-四甲基己烷-1,6-二胺和包含伯胺或仲胺的特定胺的吸收剂溶液和从气态流出物中除去酸化合物的方法公开(公告)号：US08845787B2
公开(公告)日：2014-09-30
申请号：US13056507
申请日：2009-07-21
申请人： Marc Jacquin , Julien Grandjean , Thierry Huard
发明人： Marc Jacquin , Julien Grandjean , Thierry Huard
IPC分类号： B01D53/14 , C10L3/10 , C07C211/12 , C07C215/08 , B01D53/62 , B01D53/77
CPC分类号： B01D53/62 , B01D53/1493 , B01D53/77 , B01D2251/80 , B01D2257/30 , B01D2257/504 , B01D2258/05 , B01D2258/06 , C07C211/12 , C07C215/08 , C10L3/10 , C10L3/102 , Y02C10/04 , Y02C10/06 , Y02P20/152
摘要： Acid compounds are removed from a gaseous effluent in an absorption method using an aqueous solution of N,N,N′,N′-tetramethylhexane-1,6-diamine formulated with a particular primary or secondary amine, allowing to obtain a single-phase absorbent solution under the absorption conditions of acid gases such as CO2.The method is advantageously applied to the treatment of natural gas and of gas of industrial origin.
摘要翻译： 使用与特定的伯胺或仲胺配制的N，N，N'，N'-四甲基己烷-1,6-二胺的水溶液，使用吸收法从气态流出物中除去酸化合物，从而获得单相 吸收剂溶液在酸性气体如二氧化碳的吸收条件下。 该方法有利地应用于工业原料天然气和天然气的处理。
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2.发明授权Process and device for desulfurization of a gas, comprising a stage for elimination of sulfur by cooling a gas stream 有权用于气体脱硫的方法和装置，包括通过冷却气流来消除硫的阶段公开(公告)号：US08062619B2
公开(公告)日：2011-11-22
申请号：US12697642
申请日：2010-02-01
CPC分类号： B01D53/523 , B01D53/002 , B01D53/8612 , B01D2255/202 , C01B17/05
摘要： A process and apparatus for the treatment of a gas that contains hydrogen sulfide and sulfurous anhydride, in which: a) the gas (3) contacts with an organic solvent (1) containing a catalyst in a gas-liquid reactor-contactor (2) so as to recover separately liquid sulfur and; a gas effluent containing sulfur vapor; subjecting the gas effluent to a first condensation zone (7) operating at 70-100° C. to deposit the sulfur in solid form on sufficiently cold walls of the equipment in zone (7), recovering resultant purified gas containing less than 30 ppm by volume of sulfur melting the deposited solid sulfur to regenerate the equipment, and recycling resultant liquefied sulfur to the reactor contactor.
摘要翻译： 一种用于处理含有硫化氢和亚硫酸酐的气体的方法和装置，其中：a）气体（3）在气液反应器 - 接触器（2）中与含有催化剂的有机溶剂（1）接触， 以便单独回收液态硫和; 含有硫蒸汽的气体流出物; 将气体流出物经受在70-100℃操作的第一冷凝区（7），以固体形式将硫沉积在区域（7）中的设备的足够冷的壁上，通过以下步骤回收产生的纯度小于30ppm的气体： 硫的体积溶解沉积的固体硫以再生设备，并将所得液化硫再循环到反应器接触器。
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3.发明申请ABSORBENT SOLUTION BASED ON A TERTIARY OR HINDERED AMINE AND ON A PARTICULAR ACTIVATOR AND METHOD FOR REMOVING ACID COMPOUNDS FROM A GASEOUS EFFLUENT 审中-公开基于仲胺或异丁胺和特定活化剂的吸收溶液和从气体洗脱液中除去酸化合物的方法公开(公告)号：US20110176981A1
公开(公告)日：2011-07-21
申请号：US13056446
申请日：2009-07-21
申请人： Marc Jacquin , Julien Grandjean , Thierry Huard
发明人： Marc Jacquin , Julien Grandjean , Thierry Huard
CPC分类号： B01D53/62 , B01D53/1493 , B01D53/77 , B01D2251/80 , B01D2257/30 , B01D2257/504 , B01D2258/05 , B01D2258/06 , C07C211/12 , C07C215/08 , C10L3/10 , C10L3/102 , Y02C10/04 , Y02C10/06 , Y02P20/152
摘要： The invention relates to the removal of acid compounds from a gaseous effluent In an absorption method using an aqueous solution comprising a tertiary amine or a sterically hindered amine in admixture with a primary or secondary amine meeting the general formula as follows: The invention is advantageously applied to the treatment of natural gas and of gas of industrial origin.
摘要翻译： 本发明涉及从气态流出物中除去酸性化合物。在使用包含叔胺或空间位阻胺的水溶液的吸收方法中，其与伯胺或仲胺混合，满足以下通式：本发明有利地应用于 对天然气和工业气体的处理。
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4.发明申请METHOD OF REMOVING ACID COMPOUNDS FROM A GASEOUS EFFLUENT WITH AN ABSORBENT SOLUTION BASED ON I/II/III TRIAMINES 审中-公开从基于I / II / III三聚体的吸收溶液中除去酸性化合物的方法公开(公告)号：US20130023712A1
公开(公告)日：2013-01-24
申请号：US13515340
申请日：2010-11-25
IPC分类号： B01D53/14
CPC分类号： B01D53/1493 , B01D53/1462 , B01D2252/103 , B01D2252/20415 , B01D2252/20426 , B01D2252/20431 , B01D2252/20442 , B01D2252/20452 , B01D2257/304 , B01D2257/504 , C10L3/102
摘要： The invention relates to the removal of acid compounds from a gaseous effluent in an absorption method using an aqueous solution containing one or more triamines wherein the three amine functions are not connected to each other by rings and whose amine functions in the a and the co positions are always tertiary, and the amine function in central position is always secondary, more or less sterically hindered, and which have the general formula (I) as follows:
摘要翻译： 本发明涉及使用含有一种或多种三胺的水溶液的吸收方法从气态流出物中除去酸性化合物，其中三个胺官能团不通过环彼此连接并且其胺在a和co位置上起作用 总是为叔，中心位置的胺官能团总是次要的，或多或少是空间阻碍的，并具有如下通式（I）：
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5.发明申请METHOD OF REMOVING ACID COMPOUNDS FROM A GASEOUS EFFLUENT WITH AN ABSORBENT SOLUTION BASED ON I, II/III DIAMINES 审中-公开从基于I，II / III二元素的吸收溶液中除去酸性化合物的酸性化合物的方法公开(公告)号：US20130011314A1
公开(公告)日：2013-01-10
申请号：US13515334
申请日：2010-11-25
CPC分类号： B01D53/1462 , B01D53/1493 , B01D2252/2041 , B01D2252/20426 , B01D2252/20431 , B01D2252/20452 , B01D2257/304 , C10L3/102
摘要： The invention relates to the removal of acid compounds from a gaseous effluent in an absorption method using an aqueous solution containing one or more diamines whose two amine functions are not connected to each other by rings and whose amine function in the α position is always tertiary and the amine function in the ω position is always either primary or secondary, more or less sterically hindered, and with have the general formula (I) as follows:
摘要翻译： 本发明涉及使用含有一种或多种二胺的水溶液的吸收方法从气态流出物中除去酸性化合物，所述二胺的两个胺官能团不通过环彼此连接，并且其在α位上的胺官能团总是三级和 ω位置中的胺官能团始终是初级或次级的，或多或少是空间位阻，并具有如下通式（I）：
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6.发明申请PROCESS FOR PARTIAL DEHYDRATION OF A GAS BY ABSORPTION ON A SOLVENT THAT CAN BE REGENERATED BY SEGREGATION AT AMBIENT TEMPERATURE 失效通过在环境温度下分离可以重新吸收的溶剂对气体进行部分脱气的方法公开(公告)号：US20100154638A1
公开(公告)日：2010-06-24
申请号：US12637932
申请日：2009-12-15
申请人： Nicolas FERRANDO , Julien GRANDJEAN , Abdelhakim KOUDIL , Pascal MOUGIN , Jean-Pierre BALLAGUET
发明人： Nicolas FERRANDO , Julien GRANDJEAN , Abdelhakim KOUDIL , Pascal MOUGIN , Jean-Pierre BALLAGUET
IPC分类号： B01D53/14
CPC分类号： B01D53/263 , B01D53/1425 , B01D2257/80 , C07C7/11 , C10K1/08
摘要： A process for partial dehydration of a gas by contact with a solvent that can be regenerated by: a) A stage for absorption of H2O by contact of the gas to be treated and regenerated solvent producing a dehydrated gas effluent and a liquid solvent effluent that is charged with H2O and absorbed gas, b) A stage for cooling the solvent charged with H2O at ambient temperature, c) A stage for separation by segregation during which liquid H2O and the solvent are separated at ambient temperature, d) A stage in which the regenerated solvent that is obtained at the end of stage c) is heated, e) A stage in which the regenerated and heated solvent that is obtained at the end of stage d) is recycled to the absorption stage a).
摘要翻译： 通过与可以通过以下方式再生的溶剂接触的气体部分脱水的方法：a）通过接触待处理气体和再生溶剂吸收H 2 O的阶段，产生脱水气体流出物和液体溶剂流出物，其为 充入H 2 O和吸收的气体，b）在环境温度下用于冷却加入H 2 O的溶剂的阶段，c）在环境温度下分离液体H 2 O和溶剂的分离阶段，d）在 在阶段c）结束时获得的再生溶剂被加热，e）在阶段d）结束时获得的再生和加热溶剂再循环到吸收阶段a）的阶段。
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7.发明申请ABSORBENT SOLUTION BASED ON N, N, N', N' - TETRAMETHYLHEXANE - 1,6-DIAMINE AND ON A PARTICULAR AMINE COMPRISING PRIMARY OR SECONDARY AMINE FUNCTIONS AND MEHTOD FOR REMOVING ACID COMPOUNDS FROM A GASEOUS EFFLUENT 有权基于N，N，N'，N'-四甲基己烷-1,6-二胺和包含主要或次要胺功能的特定胺和从气体洗涤剂中除去酸化合物的METEC的吸收溶液公开(公告)号：US20110185901A1
公开(公告)日：2011-08-04
申请号：US13056507
申请日：2009-07-21
申请人： Marc Jacquin , Julien Grandjean , Thierry Huard
发明人： Marc Jacquin , Julien Grandjean , Thierry Huard
CPC分类号： B01D53/62 , B01D53/1493 , B01D53/77 , B01D2251/80 , B01D2257/30 , B01D2257/504 , B01D2258/05 , B01D2258/06 , C07C211/12 , C07C215/08 , C10L3/10 , C10L3/102 , Y02C10/04 , Y02C10/06 , Y02P20/152
摘要： The invention relates to the removal of acid compounds from a gaseous effluent in an absorption method using an aqueous solution of N,N,N′,N′-tetramethylhexane-1,6-diamine formulated with a particular primary or secondary amine, allowing to obtain a single-phase absorbent solution under the absorption conditions of acid gases such as CO2.The invention is advantageously applied to the treatment of natural gas and of gas of industrial origin.
摘要翻译： 本发明涉及使用与特定的伯胺或仲胺配制的N，N，N'，N'-四甲基己烷-1,6-二胺的水溶液的吸收方法从气态流出物中除去酸化合物， 在酸性气体如二氧化碳的吸收条件下获得单相吸收剂溶液。 本发明有利地应用于天然气和工业气体的处理。
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8.发明申请PROCESS FOR DESULPHURIZATION OF A GASEOUS EFFLUENT COMPRISING A DEVICE FOR ON-LINE ANALYSIS AND CONTROL 有权包含用于在线分析和控制的设备的气体流的脱硫方法公开(公告)号：US20100266483A1
公开(公告)日：2010-10-21
申请号：US12760752
申请日：2010-04-15
IPC分类号： C01B17/02
CPC分类号： C01B17/0404 , B01D53/52 , B01D53/8612 , B01D2257/302 , B01D2257/304 , C01B17/0439 , C01B17/0452 , C01B17/0456 , Y10S423/05
摘要： The invention concerns a process for desulphurization of a gaseous effluent containing hydrogen sulphide using a Claus treatment unit followed by a Claus tail gas treatment unit (TGT), said process comprising using a device for on-line analysis of the ratio H2S/SO2 at the outlet from the TGT unit and a feed-back loop which can maintain said H2S/SO2 molar ratio at the outlet from the TGT unit to a value close to 2 and generally in the range 1.5 to 2.5.
摘要翻译： 本发明涉及使用克劳斯处理单元和克劳斯尾气处理单元（TGT）对含有硫化氢的气态流出物进行脱硫的方法，所述方法包括使用在线分析H2S / SO2比例的装置 来自TGT单元的出口和能够将来自TGT单元的出口处的所述H 2 S / SO 2摩尔比保持在接近2并且通常在1.5至2.5的范围内的反馈回路。
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9.发明授权Process for partial dehydration of a gas by absorption on a solvent that can be regenerated by segregation at ambient temperature 失效通过在环境温度下通过分离再生的溶剂上吸收气体来部分脱水的方法公开(公告)号：US08257467B2
公开(公告)日：2012-09-04
申请号：US12637932
申请日：2009-12-15
申请人： Nicolas Ferrando , Julien Grandjean , Abdelhakim Koudil , Pascal Mougin , Jean-Pierre Ballaguet
发明人： Nicolas Ferrando , Julien Grandjean , Abdelhakim Koudil , Pascal Mougin , Jean-Pierre Ballaguet
IPC分类号： B01D53/14
CPC分类号： B01D53/263 , B01D53/1425 , B01D2257/80 , C07C7/11 , C10K1/08
摘要： A process for partial dehydration of a gas by contact with a solvent that can be regenerated by: a) A stage for absorption of H2O by contact of the gas to be treated and regenerated solvent producing a dehydrated gas effluent and a liquid solvent effluent that is charged with H2O and absorbed gas, b) A stage for cooling the solvent charged with H2O at ambient temperature, c) A stage for separation by segregation during which liquid H2O and the solvent are separated at ambient temperature, d) A stage in which the regenerated solvent that is obtained at the end of stage c) is heated, e) A stage in which the regenerated and heated solvent that is obtained at the end of stage d) is recycled to the absorption stage a).
摘要翻译： 通过与可以通过以下方式再生的溶剂接触的气体部分脱水的方法：a）通过接触待处理气体和再生溶剂吸收H 2 O的阶段，产生脱水气体流出物和液体溶剂流出物，其为 充入H 2 O和吸收的气体，b）在环境温度下用于冷却加入H 2 O的溶剂的阶段，c）在环境温度下分离液体H 2 O和溶剂的分离阶段，d）在 在阶段c）结束时获得的再生溶剂被加热，e）在阶段d）结束时获得的再生和加热溶剂再循环到吸收阶段a）的阶段。
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10.发明授权Process for desulphurization of a gaseous effluent comprising a device for on-line analysis and control 有权包含用于在线分析和控制的装置的气态流出物的脱硫方法公开(公告)号：US08071068B2
公开(公告)日：2011-12-06
申请号：US12760752
申请日：2010-04-15
IPC分类号： C01B17/04
CPC分类号： C01B17/0404 , B01D53/52 , B01D53/8612 , B01D2257/302 , B01D2257/304 , C01B17/0439 , C01B17/0452 , C01B17/0456 , Y10S423/05
摘要： The invention concerns a process for desulphurization of a gaseous effluent containing hydrogen sulphide using a Claus treatment unit followed by a Claus tail gas treatment unit (TGT), said process comprising using a device for on-line analysis of the ratio H2S/SO2 at the outlet from the TGT unit and a feed-back loop which can maintain said H2S/SO2 molar ratio at the outlet from the TGT unit to a value close to 2 and generally in the range 1.5 to 2.5.
摘要翻译： 本发明涉及使用克劳斯处理单元和克劳斯尾气处理单元（TGT）对含有硫化氢的气态流出物进行脱硫的方法，所述方法包括使用在线分析H2S / SO2比例的装置 来自TGT单元的出口和能够将来自TGT单元的出口处的所述H 2 S / SO 2摩尔比保持在接近2并且通常在1.5至2.5的范围内的反馈回路。
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