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公开(公告)号：US20050234217A1
公开(公告)日：2005-10-20
申请号：US10518693
申请日：2003-06-17
申请人： Daniele Bigiavi , Nicolo Arich De Finetti , Gabriele Mei , Giuseppe Penzo , Massimo Covezzi , Pietro Baita , Maria Silvia Tonti
发明人： Daniele Bigiavi , Nicolo Arich De Finetti , Gabriele Mei , Giuseppe Penzo , Massimo Covezzi , Pietro Baita , Maria Silvia Tonti
CPC分类号： C08F6/003 , Y02P20/544 , C08L23/20
摘要： Method for continuously removing the unreacted butene-1, and optionally other volatile components, from a polymeric solution obtained by liquid phase (co)polymerization of butene-1, the method comprising the steps of: subjecting the polymeric solution to heating and mixing conditions such that a mixture is formed consisting substantially of: (1) a polybutene melt containing entrapped butene-1 and (2) supercritical gaseous butene-1; subjecting the above mixture to a sequence of devolatilization steps operating at decreasing pressures.
摘要翻译： 从通过丁烯-1的液相（共）聚合获得的聚合物溶液中连续除去未反应的丁烯-1和任选的其它挥发性组分的方法，所述方法包括以下步骤：将聚合物溶液加热和混合条件如 形成的混合物基本上由以下组成：（1）含有截留的丁烯-1和（2）超临界气态丁烯-1的聚丁烯熔体; 使上述混合物经历在降低的压力下操作的一系列脱挥发分步骤。
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2.发明授权公开(公告)号：US07985812B2
公开(公告)日：2011-07-26
申请号：US12734406
申请日：2008-10-20
IPC分类号： C08F2/04 , C08F210/16
CPC分类号： C08F10/00 , C08F10/06 , C08F210/06 , C08F2400/02 , C08F2/06 , C08F2/00 , C08F210/16 , C08F2500/12 , C08F2500/17
摘要： A method for controlling a solution process for the polymerisation of olefins is disclosed. The method is based on an algorithm that calculates predicted operating parameters of the process, including calculation of the extent of reaction (ξ), as a function of the solution density (ρ), and then calculation of the whole composition of the solution. The algorithm resolves a system of equations comprising the equation of state in the PC-SAFT form, the Lewis-Mayo equation for monomer incorporation into a copolymer, and the stoichiometry equation. Predicted parameters are compared to target parameters to detect possible deviations and implement corresponding compensation in the feed.
摘要翻译： 公开了一种用于控制烯烃聚合的溶液方法的方法。 该方法基于计算过程的预测操作参数的算法，包括计算反应程度（＆xgr），作为溶液密度（＆rgr;）的函数，然后计算溶液的整体组成 。 该算法解决了包含PC-SAFT形式的状态方程，单体掺入共聚物的Lewis-Mayo方程式和化学计量方程式的方程组。 将预测参数与目标参数进行比较，以检测可能的偏差并在进料中实现相应的补偿。
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3.发明申请公开(公告)号：US20100311921A1
公开(公告)日：2010-12-09
申请号：US12734406
申请日：2008-10-20
IPC分类号： C08F2/00
CPC分类号： C08F10/00 , C08F10/06 , C08F210/06 , C08F2400/02 , C08F2/06 , C08F2/00 , C08F210/16 , C08F2500/12 , C08F2500/17
摘要： A method for controlling a solution process for the polymerisation of olefins is disclosed. The method is based on an algorithm that calculates predicted operating parameters of the process, including calculation of the extent of reaction (ξ), as a function of the solution density (π), and then calculation of the whole composition of the solution. The algorithm resolves a system of equations comprising the equation of state in the PC-SAFT form, the Lewis-Mayo equation for monomer incorporation into a copolymer, and the stoichiometry equation. Predicted parameters are compared to target parameters to detect possible deviations and implement corresponding compensation in the feed.
摘要翻译： 公开了一种用于控制烯烃聚合的溶液方法的方法。 该方法基于计算过程的预测操作参数的算法，包括计算反应程度（＆xgr），作为溶液密度（＆pgr）的函数，然后计算溶液的整体组成 。 该算法解决了包含PC-SAFT形式的状态方程，单体掺入共聚物的Lewis-Mayo方程式和化学计量方程式的方程组。 将预测参数与目标参数进行比较，以检测可能的偏差并在进料中实现相应的补偿。
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公开(公告)号：US07160964B2
公开(公告)日：2007-01-09
申请号：US10518885
申请日：2003-06-17
申请人： Daniele Bigiavi , Gabriele Mei , Nicolo' Arich De Finetti , Giuseppe Penzo , Gianni Vitale , Massimo Covezzi
发明人： Daniele Bigiavi , Gabriele Mei , Nicolo' Arich De Finetti , Giuseppe Penzo , Gianni Vitale , Massimo Covezzi
IPC分类号： C08F4/44
CPC分类号： C08F110/08 , Y10S526/903 , C08F2/001 , C08F2/06 , C08F2/42 , C08F2500/12 , C08F2/01 , C08F2/00
摘要： A liquid-phase process for polymerizing α-olefins of the formula CH2═CHR, where R is H or an alkyl radical C1–C6, to produce a polymer that is soluble in the reaction medium, comprising the steps of: a) continuously polymerizing in liquid phase the α-olefin in the presence of a catalyst system based on a transition metal compound; b) continuously withdrawing from step a) a solution of polymer in the liquid reaction medium; c) mixing in one or more mixing stages said solution of polymer in the reaction medium with an organic deactivator having: at least a hydroxy group, a boiling point higher than 150° C., and a ratio between the molecular weight (MW) and the number of hydroxy groups (OH) comprised between 20 and 100.
摘要翻译： 用于聚合式CH 2 -CHR的α-烯烃的液相方法，其中R是H或烷基C1-C6，以产生可溶于反应介质的聚合物，包括 步骤：a）在基于过渡金属化合物的催化剂体系的存在下，在液相中连续聚合α-烯烃; b）连续地从步骤a）中取出聚合物在液体反应介质中的溶液; c）在一个或多个混合阶段将所述聚合物在反应介质中的溶液与有机失活剂混合，所述有机失活剂具有至少羟基，沸点高于150℃，分子量（MW）和 羟基（OH）的数目在20和100之间。
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公开(公告)号：US20050250917A1
公开(公告)日：2005-11-10
申请号：US10518885
申请日：2003-06-17
申请人： Daniele Bigiavi , Gabriele Mei , Nicolo Arich De Finetti , Giuseppe Penzo , Gianni Vitale , Massimo Covezzi
发明人： Daniele Bigiavi , Gabriele Mei , Nicolo Arich De Finetti , Giuseppe Penzo , Gianni Vitale , Massimo Covezzi
CPC分类号： C08F110/08 , Y10S526/903 , C08F2/001 , C08F2/06 , C08F2/42 , C08F2500/12 , C08F2/01 , C08F2/00
摘要： A liquid-phase process for polymerizing α-olefins of the formula CH2═CHR, where R is H or an alkyl radical C1-C6, to produce a polymer that is soluble in the reaction medium, comprising the steps of: a) continuously polymerizing in liquid phase the α-olefin in the presence of a catalyst system based on a transition metal compound; b) continuously withdrawing from step a) a solution of polymer in the liquid reaction medium; c) mixing in one or more mixing stages said solution of polymer in the reaction medium with an organic deactivator having: at least a hydroxy group, a boiling point higher than 150° C., and a ratio between the molecular weight (MW) and the number of hydroxy groups (OH) comprised between 20 and 100.
摘要翻译： 用于聚合式CH 2 -CHR的α-烯烃的液相方法，其中R是H或烷基C1-C6，以产生可溶于反应介质的聚合物，包括 步骤：a）在基于过渡金属化合物的催化剂体系的存在下，在液相中连续聚合α-烯烃; b）连续地从步骤a）中取出聚合物在液体反应介质中的溶液; c）在一个或多个混合阶段将所述聚合物在反应介质中的溶液与有机失活剂混合，所述有机失活剂具有至少羟基，沸点高于150℃，分子量（MW）和 羟基（OH）的数目在20和100之间。
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