公开(公告)号：US06894127B2

公开(公告)日：2005-05-17

申请号：US10416803

申请日：2001-11-14

Applicant: Patrick Daniel Yves Behue ,  Gacem Benazzouz ,  Laurent Coupier ,  David Heslop ,  Sebastien Huchette ,  Jean-Pierre Isnard ,  Willy Lemesle ,  Renaud Viguier

Inventor： Patrick Daniel Yves Behue ,  Gacem Benazzouz ,  Laurent Coupier ,  David Heslop ,  Sebastien Huchette ,  Jean-Pierre Isnard ,  Willy Lemesle ,  Renaud Viguier

IPC: C08F2/00 ,  C08F2/34 ,  C08F10/00 ,  C08F110/02 ,  C08F4/40

CPC classification number: C08F10/00 ,  C08F2/34 ,  C08F110/02 ,  C08F2410/01 ,  Y10S526/901 ,  C08F2/005 ,  C08F4/7042

Abstract: The present invention relates to a process for the gas-phase (co-)polymerization of olefins in a fluidised bed reactor using a late transition metal catalyst characterised in that the polymerization is performed in the presence of a process aid additive.

Abstract translation: 本发明涉及使用后过渡金属催化剂的流化床反应器中的烯烃的气相（共）聚合方法，其特征在于在加工助剂添加剂的存在下进行聚合。

公开(公告)号：US06936674B2

公开(公告)日：2005-08-30

申请号：US10148596

申请日：2000-11-30

Applicant: Patrick Daniel Yves Behue ,  Marianne Gil ,  Susan Katherine Christie ,  John Norman Reid Samson

Inventor： Patrick Daniel Yves Behue ,  Marianne Gil ,  Susan Katherine Christie ,  John Norman Reid Samson

IPC: C08F2/00 ,  C08F4/642 ,  C08F4/68 ,  C08F4/695 ,  C08F4/70 ,  C08F8/00 ,  C08F10/00 ,  C08J5/18 ,  C08F110/02 ,  C08F210/16

CPC classification number: C08J5/18 ,  C08F10/00 ,  C08J2323/04 ,  Y10T428/24 ,  Y10T428/269 ,  C08F4/7042

Abstract: A process for producing a poly-olefin is disclosed, which comprises contacting at least one 1-olefin under polymerisation conditions with a polymerisation catalyst or catalyst system comprising (1) a compound having the Formula (I) wherein M is Fe[II], Fe[III], Co[I], Co[II], Co[III], Mn[I], Mn[II], Mn[III], Mn[IV], Ru[II], Ru[III], Ru[IV], V[II], V[III], V[IV], or V[V], Ti[II], Ti[III] or Ti[IV]; X represents an atom or group covalently or ionically bonded to the transition metal M; T is the oxidation state of the transition metal M and b is the valency of the atom or group X; R1, R2, R3, R4, R5, R6 and R7 are independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl; and when any two or more of R1-R7 are hydrocarbyl, substited hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl, said two or more can be linked to form one or more cyclic substituents; and optionally (2) an activating quantity of an activator compound comprising a Lewis acid capable of activating the catalyst for olefin polymerisation; and then subjecting the resulting polyolefin to crosslinking conditions. The polymer produced can be formed into shaped articles or films with desirable physical properties

Abstract translation: 公开了一种生产聚烯烃的方法，其包括使聚合条件下的至少一种1-烯烃与聚合催化剂或催化剂体系接触，所述聚合催化剂或催化剂体系包含（1）具有式（I）的化合物，其中M为Fe [II] Fe [III]，Co [I]，Co [II]，Co [III]，Mn [I]，Mn [II]，Mn [III]，Mn [IV]，Ru [II]，Ru [ Ru [IV]，V [II]，V [III]，V [IV]或V [V]，Ti [II]，Ti [III]或Ti [IV] X表示与过渡金属M共价或离子键合的原子或基团; T是过渡金属M的氧化态，b是原子或基团X的化合价; R 1，R 2，R 3，R 4，R 5， R 6和R 7独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂烃基; 并且当R 1〜R 2中的任何两个或多个是烃基，取代的烃基，杂烃基或取代的杂烃基时，所述两个或更多个可以连接形成一个或多个环状 取代基 和任选地（2）活化量的活化剂化合物，其包含能够活化用于烯烃聚合的催化剂的路易斯酸; 然后将所得聚烯烃进行交联条件。 所生产的聚合物可以形成具有所需物理性质的成型制品或膜