公开(公告)号：US08816104B2

公开(公告)日：2014-08-26

申请号：US12919946

申请日：2009-02-20

Applicant: Michael Anthony Wood ,  Paul Willett ,  Paul Appleton

Inventor： Michael Anthony Wood ,  Paul Willett ,  Paul Appleton

IPC: C07D307/08 ,  B01J23/889

CPC classification number: B01J23/8892 ,  B01J37/18 ,  C07D307/08

Abstract: A process for activating a reduced manganese copper catalyst comprising treating the catalyst at a temperature of more than 300° C. to about 400° C. with hydrogen.

Abstract translation: 一种活化还原锰铜催化剂的方法，包括用氢气在大于300℃至约400℃的温度下处理催化剂。

公开(公告)号：US20110092721A1

公开(公告)日：2011-04-21

申请号：US12919946

申请日：2009-02-20

Applicant: Michael Anthony Wood ,  Paul Willett ,  Paul Appleton

Inventor： Michael Anthony Wood ,  Paul Willett ,  Paul Appleton

IPC: C07D307/08 ,  B01J37/08 ,  B01J23/889

CPC classification number: B01J23/8892 ,  B01J37/18 ,  C07D307/08

Abstract: A process for activating a reduced manganese copper catalyst comprising treating the catalyst at a temperature of more than 300° C. to about 400° C. with hydrogen.

Abstract translation: 一种活化还原锰铜催化剂的方法，包括用氢气在大于300℃至约400℃的温度下处理催化剂。

公开(公告)号：US5414159A

公开(公告)日：1995-05-09

申请号：US174320

申请日：1993-12-30

Applicant: Paul Appleton ,  Michael A. Wood

Inventor： Paul Appleton ,  Michael A. Wood

IPC: B01J23/889 ,  C07B61/00 ,  C07C27/02 ,  C07C29/149 ,  C07C31/27 ,  C07C35/14 ,  C07C29/136 ,  C07C31/20

CPC classification number: C07C35/14 ,  C07C29/149 ,  C07C2101/14

Abstract: A process is described for the production of cyclohexanedimethanol by hydrogenation of a dialkyl cyclohexanedicarboxylate which comprises the steps of:(a) providing a hydrogenation zone containing a charge of a granular reduced manganese promoted copper catalyst;(b) forming a vaporous feed stream of a hydrogenatable material comprising a dialkyl cyclohexanedicarboxylate and from about 0.1 wt % up to about 15 wt % of an acidic material at a feed temperature which is in the range of from about 150.degree. C. to about 350.degree. C. and which is above the dew point of the feed stream and at a feed pressure which is in the range of from about 150 psia (about 10.34 bar) up to about 2000 psia (about 137.90 bar), said vaporous mixture having a known hydrogen-containing gas:dialkyl cyclohexanedicarboxylate ratio;(c) supplying the vaporous feed stream to the hydrogenation zone;(d) maintaining hydrogenation conditions in the hydrogenation zone which are effective to maintain the reaction mixture in contact with the catalyst above its dew point;(e) passing the vaporous feed stream through the hydrogenation zone: and(f) recovering from the hydrogenation zone a product stream comprising cyclohexanedimethanol.

Abstract translation: 描述了通过氢化环己烷二羧酸二烷基酯制备环己烷二甲醇的方法，该方法包括以下步骤：（a）提供含有粒状还原锰促进铜催化剂装料的氢化区; （b）在约150℃至约20℃的进料温度下，形成包含环己烷二羧酸二烷基酯和约0.1重量％至约15重量％酸性物质的可氢化材料的气态进料流 350℃，高于进料流的露点，进料压力在约150psia（约10.34巴）至约2000psia（约137.90巴）的范围内，所述蒸气混合物具有 已知的含氢气体：环己烷二羧酸二烷基酯比例; （c）将蒸气进料流供应到氢化区; （d）保持加氢区中的氢化条件，其有效地使反应混合物与催化剂接触高于其露点; （e）使气态进料流通过氢化区;和（f）从氢化区回收包含环己烷二甲醇的产物流。