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公开(公告)号：US07214721B2
公开(公告)日：2007-05-08
申请号：US10781067
申请日：2004-02-18
IPC分类号： C07C27/00
CPC分类号： C12C11/02 , B01J8/0407 , B01J8/043 , B01J8/0442 , B01J8/0449 , B01J8/0488 , C07C29/152 , C07C31/04
摘要： A reactor system, plant and a process for the production of methanol from synthesis gas is described in which the reactor system comprises: (a) a first reactor adapted to be maintained under methanol synthesis conditions having inlet means for supply of synthesis gas and outlet means for recovery of a first methanol-containing stream, said first reactor being charged with a first volume of a methanol synthesis catalyst through which the synthesis gas flows and on which in use, partial conversion of the synthesis gas to a product gas mixture comprising methanol and un-reacted synthesis gas will occur adiabatically; and (b) a second reactor adapted to be maintained under methanol synthesis conditions having inlet means for supply of the gaseous first methanol-containing stream, outlet means for recovery of a second methanol-containing stream and cooling means, said second reactor being charged with a second volume of a methanol synthesis catalyst through which the gaseous first methanol-containing stream flows and on which, in use, further conversion of the synthesis gas to a product gas mixture comprising methanol will occur.
摘要翻译： 描述了一种用于从合成气生产甲醇的反应器系统，设备和方法，其中反应器系统包括：（a）适于在甲醇合成条件下保持的第一反应器，其具有用于供应合成气和出口装置的入口装置 用于回收第一含甲醇的物流，所述第一反应器装有第一体积的合成气体流过甲醇合成催化剂，在使用中，合成气部分转化成包含甲醇的产物气体混合物， 未反应的合成气将绝热发生; 和（b）适于在甲醇合成条件下保持的第二反应器，其具有用于供应气体的第一含甲醇流的入口装置，用于回收第二含甲醇流和冷却装置的出口装置，所述第二反应器装有 第二体积的甲醇合成催化剂，气态第一含甲醇流通过该催化剂流动，并且在使用中将进一步将合成气转化为包含甲醇的产物气体混合物。
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公开(公告)号：US06905592B2
公开(公告)日：2005-06-14
申请号：US10158703
申请日：2002-05-30
CPC分类号： C10G25/00
摘要： The invention relates to: a process for the desulphurization of feed streams comprising: supplying a hot process stream to a lead catalyst bed (8) comprising a first sulphur-removing catalyst and a second sulphur-removing catalyst under conditions whereby sulphur is removed from the process stream by the first sulphur-removing catalyst and said second sulphur-removing catalyst does not effectively remove sulphur from the stream at the operating temperature of the lead catalyst bed for the duration of the bed's life; collecting a hot partially sulphur-depleted stream from the lead catalyst bed and cooling said stream; passing said cooled stream through a lag catalyst bed (11) comprising the first sulphur-removing catalyst and the second sulphur-removing catalyst under conditions whereby sulphur is removed from the process stream by the second sulphur-removing catalyst and said first sulphur-removing catalyst removes sulphur less efficiently from the stream at the operating temperature of the lag catalyst bed; and recovering said sulphur-depleted stream from the second catalyst bed. In addition it relates to, apparatus for the desulphurization of feed streams which comprises: a lead catalyst bed (8) comprising a first sulphur-removing catalyst and a second sulphur-removing catalyst capable of operating under conditions whereby sulphur is removed from the process stream by the first sulphur-removing catalyst and said second sulphur-removing catalyst does not effectively remove sulphur from the stream at the operating temperature of the lead catalyst bed (8) throughout the lead bed's operating life; means (9) for collecting a hot partially sulphur-depleted stream from the lead catalyst bed (8) and cooling said stream; a lag catalyst bed (11) comprising the first sulphur-removing catalyst and the second sulphur-removing catalyst capable of operating under conditions whereby sulphur is removed from the process stream by the second sulphur-removing catalyst and said first sulphur-removing catalyst does not efficiently remove sulphur from the stream at the operating temperature of the lag catalyst bed(11).
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公开(公告)号：US20130210938A1
公开(公告)日：2013-08-15
申请号：US13805940
申请日：2011-06-27
IPC分类号： C10L3/08
CPC分类号： C10L3/08
摘要： In a process for the production of substitute natural gas, a feed gas is provided to a first and/or second and/or subsequent bulk methanator. The feed gas is subjected to methanation in the presence of a suitable catalyst. An at least partially reacted stream from the first bulk methanator is removed and supplied to the second and/or subsequent bulk methanator where it is subjected to further methanation. A product stream from the final bulk methanator is passed to a trim methanator train where it is subjected to further methanation. A recycle stream is removed downstream of the first, second or subsequent bulk methanator, and, in any order, passed through a compressor, subjected to cooling and then supplied to a trim and/or recycle methanator for further methanation before being recycled to the first and/or second and/or subsequent methanator.
摘要翻译： 在生产替代天然气的方法中，将进料气体提供给第一和/或第二和/或随后的主体甲烷化器。 进料气体在合适的催化剂存在下进行甲烷化。 去除来自第一批量甲烷化器的至少部分反应的物流并将其供应到第二和/或随后的主体甲烷化器中，在那里进行甲烷化。 来自最终的大量甲烷化器的产物流被送到修剪甲烷化器列，在那里进行进一步甲烷化。 在第一，第二或随后的主体甲烷化器的下游除去再循环流，并以任何顺序通过压缩机，进行冷却，然后供给到装饰和/或再循环甲烷化器中进一步甲烷化，然后再循环至第一 和/或第二和/或其后的甲烷化器。
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公开(公告)号：US08101142B2
公开(公告)日：2012-01-24
申请号：US10158752
申请日：2002-05-30
CPC分类号： C12C11/02 , B01J8/0407 , B01J8/043 , B01J8/0442 , B01J8/0449 , B01J8/0488 , C07C29/152 , C07C31/04
摘要： A reactor system, plant and a process for the production of methanol from synthesis gas is described in which the reactor system comprises: (a) a first reactor adapted to be maintained under methanol synthesis conditions having inlet means for supply of synthesis gas and outlet means for recovery of a first methanol-containing stream, said first reactor being charged with a first volume of a methanol synthesis catalyst through which the synthesis gas flows and on which in use, partial conversion of the synthesis gas to a product gas mixture comprising methanol and un-reacted synthesis gas will occur adiabatically; and (b) a second reactor adapted to be maintained under methanol synthesis conditions having inlet means for supply of the gaseous first methanol-containing stream, outlet means for recovery of a second methanol-containing stream and cooling means, said second reactor being charged with a second volume of a methanol synthesis catalyst through which the gaseous first methanol-containing stream flows and on which, in use, further conversion of the synthesis gas to a product gas mixture comprising methanol will occur.
摘要翻译： 描述了一种用于从合成气生产甲醇的反应器系统，设备和方法，其中反应器系统包括：（a）适于在甲醇合成条件下保持的第一反应器，其具有用于供应合成气和出口装置的入口装置 用于回收第一含甲醇的物流，所述第一反应器装有第一体积的合成气体流过甲醇合成催化剂，在使用中，合成气部分转化成包含甲醇的产物气体混合物， 未反应的合成气将绝热发生; 和（b）适于在甲醇合成条件下保持的第二反应器，其具有用于供应气体的第一含甲醇流的入口装置，用于回收第二含甲醇流和冷却装置的出口装置，所述第二反应器装有 第二体积的甲醇合成催化剂，气态第一含甲醇流通过该催化剂流动，并且在使用中将进一步将合成气转化为包含甲醇的产物气体混合物。
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公开(公告)号：US08969423B2
公开(公告)日：2015-03-03
申请号：US13805940
申请日：2011-06-27
IPC分类号： C10L3/08
CPC分类号： C10L3/08
摘要： In a process for the production of substitute natural gas, a feed gas is provided to a first and/or second and/or subsequent bulk methanator. The feed gas is subjected to methanation in the presence of a suitable catalyst. An at least partially reacted stream from the first bulk methanator is removed and supplied to the second and/or subsequent bulk methanator where it is subjected to further methanation. A product stream from the final bulk methanator is passed to a trim methanator train where it is subjected to further methanation. A recycle stream is removed downstream of the first, second or subsequent bulk methanator, and, in any order, passed through a compressor, subjected to cooling and then supplied to a trim and/or recycle methanator for further methanation before being recycled to the first and/or second and/or subsequent methanator.
摘要翻译： 在生产替代天然气的方法中，将进料气体提供给第一和/或第二和/或随后的主体甲烷化器。 进料气体在合适的催化剂存在下进行甲烷化。 去除来自第一批量甲烷化器的至少部分反应的物流并将其供应到第二和/或随后的主体甲烷化器中，在那里进行甲烷化。 来自最终的大量甲烷化器的产物流被送到修剪甲烷化器列，在那里进行进一步甲烷化。 在第一，第二或随后的主体甲烷化器的下游除去再循环流，并以任何顺序通过压缩机，进行冷却，然后供给到装饰和/或再循环甲烷化器中进一步甲烷化，然后再循环至第一 和/或第二和/或其后的甲烷化器。
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