公开(公告)号：US09731975B2

公开(公告)日：2017-08-15

申请号：US14384540

申请日：2012-03-16

申请人： Dimitris E Katsoulis ,  Malcolm E Kenney ,  Plousia E Vassilaras

发明人： Dimitris E Katsoulis ,  Malcolm E Kenney ,  Plousia E Vassilaras

IPC分类号： C01B33/08 ,  C07F7/12 ,  C07C17/26

CPC分类号： C01B33/08 ,  C07C17/26 ,  C07F7/123

摘要： A method of forming chloro-substituted silanes from the reaction of an alkoxysilane with a chlorinating agent in the optional presence of a catalyst is provided. More specifically, chloro-substituted silanes, including but not limited to silicon tetrachloride, are formed by reacting a chlorinating agent, such as thionyl chloride, with an alkylalkoxysilane having the formula (R′O)4-xSiRx, where R and R′ are independently selected alkyl groups comprising one or more carbon atoms and x is 0, 1, 2, or 3. The catalyst may be dimethylformamide, (chloromethylene)dimethyliminium chloride, or triethylamine, among others. The chloro-substituted silane formed in the reaction along with several by-products has the formula (R′O)4-x-ySiRxCly; where x is 0, 1, 2, or 3 and y is 1, 2, 3, or 4. One of the by-products of the reaction is an alkyl chloride.

公开(公告)号：US20150023861A1

公开(公告)日：2015-01-22

申请号：US14384540

申请日：2012-03-16

申请人： Dimitris E Katsoulis ,  Malcolm E Kenney ,  Plousia E Vassilaras

发明人： Dimitris E Katsoulis ,  Malcolm E Kenney ,  Plousia E Vassilaras

IPC分类号： C01B33/08 ,  C07C17/26

CPC分类号： C01B33/08 ,  C07C17/26 ,  C07F7/123

摘要： A method of forming chloro-substituted silanes from the reaction of an alkoxysilane with a chlorinating agent in the optional presence of a catalyst is provided. More specifically, chloro-substituted silanes, including but not limited to silicon tetrachloride, are formed by reacting a chlorinating agent, such as thionyl chloride, with an alkylalkoxysilane having the formula (R′O)4-xSiRx, where R and R′ are independently selected alkyl groups comprising one or more carbon atoms and x is 0, 1, 2, or 3. The catalyst may be dimethylformamide, (chloromethylene)dimethyliminium chloride, or triethylamine, among others. The chloro-substituted silane formed in the reaction along with several by-products has the formula (R′O)4-x-ySiRxCly; where x is 0, 1, 2, or 3 and y is 1, 2, 3, or 4. One of the by-products of the reaction is an alkyl chloride.

摘要翻译： 提供了在任选的催化剂存在下，由烷氧基硅烷与氯化剂的反应形成氯代硅烷的方法。 更具体地说，氯取代的硅烷，包括但不限于四氯化硅，通过使氯化剂如亚硫酰氯与具有式（R'O）4-xSiRx的烷基烷氧基硅烷反应形成，其中R和R'是 独立选择的包含一个或多个碳原子的烷基，x是0,1,2或3.催化剂可以是二甲基甲酰胺，（氯亚甲基）二甲基亚胺氯化物或三乙胺等。 在反应中形成的氯取代的硅烷与几种副产物具有式（R'O）4-x-ySiR x Cly; 其中x是0,1,2或3，y是1,2,3或4.反应的副产物之一是烷基氯。