利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

181 条记录 (耗时 0.036 秒)

    METHOD OF MAKING ALPHA, OMEGA-DIIODOPERFLUOROALKANES
    4.
    发明申请
    METHOD OF MAKING ALPHA, OMEGA-DIIODOPERFLUOROALKANES 有权
    制备ALPHA，OMEGA-DIIODOPERFLUOROKANES的方法

    公开(公告)号：US20150259270A1

    公开(公告)日：2015-09-17

    申请号：US14434981

    申请日：2013-10-09

    申请人： 3M INNOVATIVE PROPERTIES COMPANY

    发明人： Steven J. Martin ,  Luke T. Dressel ,  Aaron E. Hutt ,  Eric A. Schotz ,  Terence D. Spawn ,  Miguel A. Guerra ,  Tatsuo Fukushi ,  Jeremy A. Miller ,  Christopher M. Geise ,  James A. McDonell

    IPC分类号： C07C45/58 ,  C07C17/26

    CPC分类号： C07C45/58 ,  C07C17/00 ,  C07C17/093 ,  C07C17/26 ,  C07C19/16

    摘要： A method of making α,ω-diiodoperfluoroalkanes includes combining: diatomic iodine, at least one perfluoroalkylene oxide represented by the formula wherein Rf represents a perfluoroalkyl group; and at least one of: a) a first metallic compound comprising nickel, and a second metallic compound comprising molybdenum that is compositionally different from the first metallic compound; or b) a metallic alloy comprising from 50 to 70 percent by weight of nickel and from 20 to 40 percent by weight of molybdenum, based on the total weight of the metallic alloy, thereby producing at least one product represented by the formula I(CF2)nI, wherein n independently represents an integer in the range of from 1 to 11. The total weight of the at least one product wherein n is 3 or greater exceeds the total weight of the at least one product wherein n is 1 or 2 by a factor of at least 4.

    摘要翻译： 制备α，ω-二碘全氟烷烃的方法包括组合：双原子碘，至少一种由下式表示的全氟氧化烯，其中Rf表示全氟烷基; 和至少一种：a）包含镍的第一金属化合物和包含与第一金属化合物成分不同的钼的第二金属化合物; 或b）金属合金，其包含基于金属合金的总重量的50-70重量％的镍和20至40重量％的钼，由此产生至少一种由式I表示的产物（CF 2 ）nI，其中n独立地表示1至11范围内的整数。其中n为3或更大的至少一种产物的总重量超过至少一种产物的总重量，其中n为1或2，其中n为1或2， 至少4的因素。

    ALTERNATIVE METHODS FOR THE SYNTHESIS OF ORGANOSILICON COMPOUNDS
    8.
    发明申请
    ALTERNATIVE METHODS FOR THE SYNTHESIS OF ORGANOSILICON COMPOUNDS 有权
    用于合成有机硅化合物的替代方法

    公开(公告)号：US20150023861A1

    公开(公告)日：2015-01-22

    申请号：US14384540

    申请日：2012-03-16

    申请人： Dimitris E Katsoulis ,  Malcolm E Kenney ,  Plousia E Vassilaras

    发明人： Dimitris E Katsoulis ,  Malcolm E Kenney ,  Plousia E Vassilaras

    IPC分类号： C01B33/08 ,  C07C17/26

    CPC分类号： C01B33/08 ,  C07C17/26 ,  C07F7/123

    摘要： A method of forming chloro-substituted silanes from the reaction of an alkoxysilane with a chlorinating agent in the optional presence of a catalyst is provided. More specifically, chloro-substituted silanes, including but not limited to silicon tetrachloride, are formed by reacting a chlorinating agent, such as thionyl chloride, with an alkylalkoxysilane having the formula (R′O)4-xSiRx, where R and R′ are independently selected alkyl groups comprising one or more carbon atoms and x is 0, 1, 2, or 3. The catalyst may be dimethylformamide, (chloromethylene)dimethyliminium chloride, or triethylamine, among others. The chloro-substituted silane formed in the reaction along with several by-products has the formula (R′O)4-x-ySiRxCly; where x is 0, 1, 2, or 3 and y is 1, 2, 3, or 4. One of the by-products of the reaction is an alkyl chloride.

    摘要翻译： 提供了在任选的催化剂存在下，由烷氧基硅烷与氯化剂的反应形成氯代硅烷的方法。 更具体地说，氯取代的硅烷，包括但不限于四氯化硅，通过使氯化剂如亚硫酰氯与具有式（R'O）4-xSiRx的烷基烷氧基硅烷反应形成，其中R和R'是 独立选择的包含一个或多个碳原子的烷基，x是0,1,2或3.催化剂可以是二甲基甲酰胺，（氯亚甲基）二甲基亚胺氯化物或三乙胺等。 在反应中形成的氯取代的硅烷与几种副产物具有式（R'O）4-x-ySiR x Cly; 其中x是0,1,2或3，y是1,2,3或4.反应的副产物之一是烷基氯。