公开(公告)号：US20090093656A1

公开(公告)日：2009-04-09

申请号：US12245598

申请日：2008-10-03

申请人： Ralf Bonmann ,  Werner Pompetzki ,  Markus Weber

发明人： Ralf Bonmann ,  Werner Pompetzki ,  Markus Weber

IPC分类号： C07C29/143 ,  C07C29/80 ,  C07C37/08

CPC分类号： C07C409/10 ,  C07C29/145 ,  C07C37/08 ,  C07C45/53 ,  C07C407/00 ,  Y02P20/125 ,  C07C49/08 ,  C07C31/10 ,  C07C39/04

摘要： The present invention relates to a process for the production of iso-propanol by liquid phase hydrogenation of acetone to iso-propanol in at least two hydrogenation reaction stages, each reaction stage comprising a hydrogenation reaction zone, wherein the hydrogenation reaction product leaving the reaction zone of the first reaction stage contains unreacted acetone and a product stream comprising acetone and iso-propanol is transferred to the reaction zone of a subsequent reaction stage said product stream having at the inlet to the reaction zone of said subsequent reaction stage a temperature of 60 to 100° C., wherein the temperature of the product stream leaving the reaction zone of said subsequent reaction stage at the outlet from said reaction zone is at most 40° C. higher than the temperature of the product stream entering said reaction zone at the inlet to said reaction zone and the temperature in said subsequent reaction zone does not exceed 125° C., to a process of purifying an iso-propanol raw product containing less than 1,000 wppm acetone comprising subjecting the iso-propanol raw product to a distillation in a dividing wall distillation column to obtain purified iso-propanol and to an integrated process for the production of phenol employing the above hydrogenation process.

摘要翻译： 本发明涉及通过在至少两个氢化反应阶段中将丙酮液相氢化成异丙醇来生产异丙醇的方法，每个反应阶段包括氢化反应区，其中离开反应区的氢化反应产物 的第一反应阶段包含未反应的丙酮，并且将包含丙酮和异丙醇的产物流转移到随后反应阶段的反应区，所述产物流在所述后续反应阶段的反应区的入口处具有60至 其中从所述反应区出口离开所述后续反应阶段的反应区的产物流的温度比在入口处进入所述反应区的产物流的温度高至多40℃ 至所述反应区，并且所述后续反应区中的温度不超过125℃ 包括含有少于1,000wppm丙酮的异丙醇原料，包括使异丙醇原料在分隔壁蒸馏塔中进行蒸馏以获得纯化的异丙醇，并使用上述氢化方法生产苯酚的综合方法 。

公开(公告)号：US07799958B2

公开(公告)日：2010-09-21

申请号：US12245598

申请日：2008-10-03

申请人： Ralf Bonmann ,  Werner Pompetzki ,  Markus Weber

发明人： Ralf Bonmann ,  Werner Pompetzki ,  Markus Weber

IPC分类号： C07C29/143 ,  C07C29/145 ,  C07C37/08

CPC分类号： C07C409/10 ,  C07C29/145 ,  C07C37/08 ,  C07C45/53 ,  C07C407/00 ,  Y02P20/125 ,  C07C49/08 ,  C07C31/10 ,  C07C39/04

摘要： The present invention relates to a process for the production of iso-propanol by liquid phase hydrogenation of acetone to iso-propanol in at least two hydrogenation reaction stages, each reaction stage comprising a hydrogenation reaction zone, wherein the hydrogenation reaction product leaving the reaction zone of the first reaction stage contains unreacted acetone and a product stream comprising acetone and iso-propanol is transferred to the reaction zone of a subsequent reaction stage said product stream having at the inlet to the reaction zone of said subsequent reaction stage a temperature of 60 to 100° C., wherein the temperature of the product stream leaving the reaction zone of said subsequent reaction stage at the outlet from said reaction zone is at most 40° C. higher than the temperature of the product stream entering said reaction zone at the inlet to said reaction zone and the temperature in said subsequent reaction zone does not exceed 125° C., to a process of purifying an iso-propanol raw product containing less than 1,000 wppm acetone comprising subjecting the iso-propanol raw product to a distillation in a dividing wall distillation column to obtain purified iso-propanol and to an integrated process for the production of phenol employing the above hydrogenation process.

摘要翻译： 本发明涉及通过在至少两个氢化反应阶段中将丙酮液相氢化成异丙醇来生产异丙醇的方法，每个反应阶段包括氢化反应区，其中离开反应区的氢化反应产物 的第一反应阶段包含未反应的丙酮，将包含丙酮和异丙醇的产物流转移到后续反应阶段的反应区，所述产物流在所述后续反应阶段的反应区的入口处具有60至 其中从所述反应区出口离开所述后续反应阶段的反应区的产物流的温度比在入口处进入所述反应区的产物流的温度高至多40℃ 至所述反应区，并且所述后续反应区中的温度不超过125℃ 包括含有少于1,000wppm丙酮的异丙醇原料，包括使异丙醇原料在分隔壁蒸馏塔中进行蒸馏以获得纯化的异丙醇，并使用上述氢化方法生产苯酚的综合方法 。