公开(公告)号：US07078560B2

公开(公告)日：2006-07-18

申请号：US10982890

申请日：2004-11-08

申请人： Jochen Houben ,  Ralph Eickwinkel ,  Oliver Hoppe ,  Bernd Kubiak ,  Erich Kuester

发明人： Jochen Houben ,  Ralph Eickwinkel ,  Oliver Hoppe ,  Bernd Kubiak ,  Erich Kuester

IPC分类号： C07C67/02

CPC分类号： C07C213/06 ,  C07C219/08

摘要： A process for the preparation of aminoalkyl (meth)acrylates by transesterification from C1–C4-alkyl (meth)acrylates and aminoalcohols is described, in which process the transesterification is carried out in the presence of at least one distannoxane of the general formula (1) wherein R=linear, cyclic or branched alkyl radical having from 1 to 6 carbon atoms, phenyl radical, and the radicals R may be identical or different from one another, Y=halogen, preferably Cl, Br; pseudo-halogen, preferably SCN; OH, OAc or OR, the radicals Y being identical or different from one another, as catalyst, and the use of the aminoalkyl (meth)acrylates prepared according to the process in the preparation of cationic monomers.

摘要翻译： 描述了通过从C 1 -C 4烷基（甲基）丙烯酸酯和氨基醇的酯交换制备氨基烷基（甲基）丙烯酸酯的方法，其中酯交换是 在至少一种通式（1）的二锡氧烷的存在下进行，其中R =具有1至6个碳原子的直链，环状或支链烷基，苯基，并且基团R可以彼此相同或不同 ，Y =卤素，优选Cl，Br; 假卤素，优选SCN; OH，OAc或OR，基团Y彼此相同或不同，作为催化剂，以及根据制备阳离子单体的方法制备的（甲基）丙烯酸氨基烷基酯的用途。

公开(公告)号：US20050085660A1

公开(公告)日：2005-04-21

申请号：US10982890

申请日：2004-11-08

申请人： Jochen Houben ,  Ralph Eickwinkel ,  Oliver Hoppe ,  Bernd Kubiak ,  Erich Kuester

发明人： Jochen Houben ,  Ralph Eickwinkel ,  Oliver Hoppe ,  Bernd Kubiak ,  Erich Kuester

IPC分类号： B01J31/12 ,  C07B61/00 ,  C07C67/03 ,  C07C69/54 ,  C07C213/06 ,  C07C219/08 ,  C07F7/24 ,  C07C229/06

CPC分类号： C07C213/06 ,  C07C219/08

摘要： A process for the preparation of aminoalkyl (meth)acrylates by transesterification from C1-C4-alkyl (meth)acrylates and aminoalcohols is described, in which process the trans-esterification is carried out in the presence of at least one distannoxane of the general formula (1) wherein R=linear, cyclic or branched alkyl radical having from 1 to 6 carbon atoms, phenyl radical, and the radicals. R may be identical or different from one another, Y=halogen, preferably Cl, Br; pseudo-halogen, preferably SCN; OH, OAc or OR, the radicals Y being identical or different from one another, as catalyst, and the use of the aminoalkyl (meth)acrylates prepared according to the process in the preparation of cationic monomers.

摘要翻译： 描述了通过从C 1 -C 4烷基（甲基）丙烯酸酯和氨基醇的酯交换制备氨基烷基（甲基）丙烯酸酯的方法，其中反式 - 酯化反应在至少一种通式（1）的二锡氧烷存在下进行，其中R =具有1至6个碳原子的直链，环状或支链烷基，苯基和基团。 R可以相同或不同，Y =卤素，优选Cl，Br; 假卤素，优选SCN; OH，OAc或OR，基团Y彼此相同或不同，作为催化剂，以及根据制备阳离子单体的方法制备的（甲基）丙烯酸氨基烷基酯的用途。

公开(公告)号：US06979748B2

公开(公告)日：2005-12-27

申请号：US10311600

申请日：2001-06-01

申请人： Jochen Houben ,  Ralph Eickwinkel ,  Oliver Hoppe ,  Bernd Kubiak ,  Erich Kuester

发明人： Jochen Houben ,  Ralph Eickwinkel ,  Oliver Hoppe ,  Bernd Kubiak ,  Erich Kuester

IPC分类号： B01J31/12 ,  C07B61/00 ,  C07C67/03 ,  C07C69/54 ,  C07C213/06 ,  C07C219/08 ,  C07C69/52

CPC分类号： C07C213/06 ,  C07C219/08

摘要： A process for the preparation of aminoalkyl (meth)acrylates by transesterification from C1-C4-alkyl (meth)acrylates and aminoalcohols is described, in which process the transesterification is carried out in the presence of at least one distannoxane of the general formula (1) wherein R=linear, cyclic or branched alkyl radical having from 1 to 6 carbon atoms, phenyl radical, and the radicals R may be identical or different from one another, Y=halogen, preferably Cl, Br; pseudo-halogen, preferably SCN; OH, OAc or OR, the radicals Y being identical or different from one another, as catalyst, and the use of the aminoalkyl(meth)acrylates prepared according to the process in the preparation of cationic monomers.

摘要翻译： 描述了通过从C 1 -C 4烷基（甲基）丙烯酸酯和氨基醇的酯交换制备氨基烷基（甲基）丙烯酸酯的方法，其中酯交换是 在至少一种通式（1）的二锡氧烷的存在下进行，其中R =具有1至6个碳原子的直链，环状或支链烷基，苯基，并且基团R可以彼此相同或不同 ，Y =卤素，优选Cl，Br; 假卤素，优选SCN; OH，OAc或OR，基团Y彼此相同或不同，作为催化剂，以及根据制备阳离子单体的方法制备的（甲基）丙烯酸氨基烷基酯的用途。