摘要:
Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.
摘要:
A process for treating a gas mixture containing at least an organic compound gas or vapor and a second gas, such as natural gas, refinery off-gas or air. The process uses two sequential membrane separation steps, one using membrane selective for the organic compound over the second gas, the other selective for the second gas over the organic vapor. The second-gas-selective membranes use a selective layer made from a polymer having repeating units of a fluorinated polymer, and demonstrate good resistance to plasticization by the organic components in the gas mixture under treatment, and good recovery after exposure to liquid aromatic hydrocarbons. The membrane steps can be combined in either order.
摘要:
A process for manufacturing cumene by reacting propylene with benzene, including treating a vent stream from the reaction zone, to recover propylene for return to the reactor. The process involves using a gas separation membrane to separate propylene from propane in the reactor vent stream. The membrane separation step results in a residue stream typically containing as much as 30%, 40% or more propane, which is vented from the process, and a permeate stream containing 95% or less propylene, which is recirculated to the reactor.
摘要:
A process for manufacturing isopropyl alcohol by reacting propylene with a reagent, including treating a vent stream from the reaction zone, to recover propylene for return to the reactor. The process involves using a gas separation membrane to separate propylene from propane in the reactor vent stream. The membrane separation step results in a residue stream typically containing as much as 30% propane or more, which is vented from the process, and a permeate stream typically containing 95% or less propylene, which is recirculated to the reactor.
摘要:
A process for separating a gas from a gas mixture containing an organic compound gas or vapor, using gas-separation membranes selective for the gas over the organic compound. The membranes use a selective layer made from a polymer having repeating units of a fluorinated cyclic structure of an at least 5-member ring, and demonstrate good resistance to plasticization by the organic components in the gas mixture under treatment.
摘要:
A membrane-based gas separation process for treating gas streams that contain methane in low concentrations. The invention involves flowing the stream to be treated across the feed side of a membrane and flowing a sweep gas stream, usually air, across the permeate side. Carbon dioxide permeates the membrane preferentially and is picked up in the sweep air stream on the permeate side; oxygen permeates in the other direction and is picked up in the methane-containing stream. The resulting residue stream is enriched in methane as well as oxygen and has an EMC value enabling it to be either flared or combusted by mixing with ordinary air.
摘要:
A process for separating hydrogen from a multicomponent gas mixture containing hydrogen and a hydrocarbon, using gas-separation membranes selective for hydrogen over the hydrocarbon. The membranes use a selective layer made from a polymer having repeating units of a fluorinated polymer, and demonstrate good resistance to plasticization by the organic components in the gas mixture under treatment, and good recovery after exposure to liquid aromatic hydrocarbons.
摘要:
Disclosed herein are combustion systems, power plants, and flue gas treatment systems that incorporate sweep-based membrane separation units to remove carbon dioxide from combustion gases. In its most basic embodiment, the invention is a combustion system that includes three discrete units: a combustion unit, a carbon dioxide capture unit, and a sweep-based membrane separation unit. In a preferred embodiment, the invention is a power plant including a combustion unit, a power generation system, a carbon dioxide capture unit, and a sweep-based membrane separation unit. In yet another embodiment, the invention is a flue gas treatment system that incorporates three membrane separation units with a carbon dioxide liquefaction unit.
摘要:
A gas separation process for treating flue gases from combustion processes, and combustion processes including such gas separation. The invention involves flowing the flue gas stream to be treated across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas to the combustor.
摘要:
A membrane-based gas separation process for treating gas streams that contain methane in low concentrations. The invention involves flowing the stream to be treated across the feed side of a membrane and flowing a sweep gas stream, usually air, across the permeate side. Carbon dioxide permeates the membrane preferentially and is picked up in the sweep air stream on the permeate side; oxygen permeates in the other direction and is picked up in the methane-containing stream. The resulting residue stream is enriched in methane as well as oxygen and has an EMC value enabling it to be either flared or combusted by mixing with ordinary air.