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1.发明授权公开(公告)号：US07282615B2
公开(公告)日：2007-10-16
申请号：US10870351
申请日：2004-06-16
CPC分类号： B01J31/0215 , B01J27/04 , B01J27/0576 , B01J31/0218 , B01J31/0244 , B01J31/0271 , B01J31/04 , B01J31/26 , C07C17/12 , C07C25/125 , C07C25/02
摘要： A method for ring-halogenating an aromatic compound comprises contacting the aromatic compound with chlorine or bromine in the presence of a catalyst composition, where the catalyst composition comprises at least one salt comprising a metal selected from the group consisting of Group 13 metal; and a counterion derived from an acid having a pKa relative to water of 0 or greater; and at least one organic sulfur compound.
摘要翻译： 芳族化合物的环卤化方法包括在催化剂组合物存在下使芳族化合物与氯或溴接触，其中催化剂组合物包含至少一种包含选自第13族金属的金属的盐; 以及衍生自相对于水的pKa为0以上的酸的抗衡离子; 和至少一种有机硫化合物。
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公开(公告)号：US07557058B2
公开(公告)日：2009-07-07
申请号：US11305906
申请日：2005-12-19
IPC分类号： B01J31/00
CPC分类号： C07C25/02 , B01J31/0211 , B01J31/0215 , B01J31/04 , B01J31/226 , B01J31/26 , B01J2531/16 , B01J2531/46 , B01J2531/48 , B01J2531/56 , B01J2531/57 , B01J2531/64 , B01J2531/72 , B01J2531/824 , B01J2531/828 , B01J2531/845 , B01J2531/847 , B01J2540/225 , C07C17/12 , C07C25/125
摘要： The present invention provides a catalyst composition prepared by combining (A) at least one salt and (B) at least one organic sulfur compound. The salt includes a metal cation of a metal selected from the group consisting of copper, nickel, cobalt, manganese, molybdenum, zirconium, titanium, vanadium, niobium, palladium, and platinum and an organic counterion to the metal cation, derived from at least one acidic organic compound selected from the group consisting of those with an approximate pKa value relative to water of at least about 3. The catalyst compositions provided by the invention are useful for the selective chlorination of aromatic compounds such as toluene and o-xylene.
摘要翻译： 本发明提供了通过将（A）至少一种盐和（B）至少一种有机硫化合物组合而成的催化剂组合物。 所述盐包括选自铜，镍，钴，锰，钼，锆，钛，钒，铌，钯和铂中的金属的金属阳离子和至少源自金属阳离子的有机抗衡离子 一种酸性有机化合物选自具有至少约3的近似pKa值的那些。本发明提供的催化剂组合物可用于芳族化合物如甲苯和邻二甲苯的选择性氯化。
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公开(公告)号：US07012166B2
公开(公告)日：2006-03-14
申请号：US10391370
申请日：2003-03-18
IPC分类号： C07C17/00
CPC分类号： C07C25/02 , B01J31/0211 , B01J31/0215 , B01J31/04 , B01J31/226 , B01J31/26 , B01J2531/16 , B01J2531/46 , B01J2531/48 , B01J2531/56 , B01J2531/57 , B01J2531/64 , B01J2531/72 , B01J2531/824 , B01J2531/828 , B01J2531/845 , B01J2531/847 , B01J2540/225 , C07C17/12 , C07C25/125
摘要： Aromatic compounds such as toluene and o-xylene are chlorinated in the presence of a catalyst combination prepared by combining (A) at least one salt comprising a metal selected from the group consisting of a Group 4–12 metal, a lanthanide and an actinide; and a counterion; and (B) at least one organic sulfur compound, preferably phenothiazine-N-carbonyl chloride. The catalyst combination may include reaction products of (A) and (B). Under these conditions, production of the p-chloro isomer is optimized. In some embodiments said counterion is an organic counterion derived from at least one acidic organic compound selected from the group consisting of those with an approximate pKa value relative to water of at least about 3.
摘要翻译： 芳族化合物如甲苯和邻二甲苯在存在催化剂组合的情况下进行氯化，所述催化剂组合通过组合（A）至少一种包含选自第4-12族金属，镧系元素和锕系元素的金属的盐; 和反抗; 和（B）至少一种有机硫化合物，优选吩噻嗪-N-碳酰氯。 催化剂组合可以包括（A）和（B）的反应产物。 在这些条件下，优化了对氯异构体的生产。 在一些实施方案中，所述抗衡离子是衍生自至少一种酸性有机化合物的有机抗衡离子，所述酸性有机化合物选自具有至少约3的相对于水的近似pKa值的那些。
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