公开(公告)号：US08722316B2

公开(公告)日：2014-05-13

申请号：US13333499

申请日：2011-12-21

申请人： Fabio Borbone ,  Antonio Roviello ,  Roberto Centore ,  Antonio Carella ,  Fabio De Matteis ,  Mauro Casalboni ,  Glauco Stracci ,  Massimiliano Dispenza

发明人： Fabio Borbone ,  Antonio Roviello ,  Roberto Centore ,  Antonio Carella ,  Fabio De Matteis ,  Mauro Casalboni ,  Glauco Stracci ,  Massimiliano Dispenza

IPC分类号： G02F1/361 ,  C08G18/10 ,  C08G18/32 ,  C08G18/76

CPC分类号： G02F1/361 ,  C08G18/10 ,  C08G18/32 ,  C08G18/3836 ,  C08G18/384 ,  C08G18/7621 ,  C08G18/7657 ,  G02F1/3615

摘要： The present invention concerns a process for realization of polymeric materials with second order nonlinear electro-optical properties comprising the following steps: mixing of a chromophore with nonlinear optical properties with two or three hydroxy groups; isolation of said pure bi- or tri-isocyanate NLO chromophores obtained according to the above step; dissolution of said bi- or tri-isocyanate NLO chromophores obtained according to the above step in one or more isocyanate group not reactive solvents containing reactive substances; coating of a thin layer of said prepolymer mixture on a substrate and evaporation of said not reactive solvents; cross-linking and poling of said thin layer on substrate, by means of heating and application of an electric field; cooling of said thin cross-linked and poled layer at ambient temperature maintaining the applied poling electric field; switching off the poling electric field.

摘要翻译： 本发明涉及一种用于实现具有二阶非线性电光学特性的聚合物材料的方法，其包括以下步骤：将发色团与非对称光学性质与两个或三个羟基混合; 分离根据上述步骤获得的所述纯的二异氰酸酯或三异氰酸酯NLO发色团; 将根据上述步骤获得的所述二异氰酸酯或三异氰酸酯NLO发色团溶解在一种或多种含反应性物质的异氰酸酯基团不反应性溶剂中; 将所述预聚物混合物的薄层涂覆在基材上并蒸发所述非反应性溶剂; 通过加热和施加电场来在衬底上交联和极化所述薄层; 在环境温度下冷却所述薄的交联和极化层，保持施加的极化电场; 关闭极化电场。

公开(公告)号：US20120211463A1

公开(公告)日：2012-08-23

申请号：US13333499

申请日：2011-12-21

申请人： Fabio Borbone ,  Antonio Roviello ,  Roberto Centore ,  Antonio Carella ,  Fabio De Matteis ,  Mauro Casalboni ,  Glauco Stracci ,  Massimiliano Dispenza

发明人： Fabio Borbone ,  Antonio Roviello ,  Roberto Centore ,  Antonio Carella ,  Fabio De Matteis ,  Mauro Casalboni ,  Glauco Stracci ,  Massimiliano Dispenza

IPC分类号： B05D5/06 ,  B05D5/12 ,  B05D3/10 ,  B05D3/02 ,  B05D3/14

CPC分类号： G02F1/361 ,  C08G18/10 ,  C08G18/32 ,  C08G18/3836 ,  C08G18/384 ,  C08G18/7621 ,  C08G18/7657 ,  G02F1/3615

摘要： The present invention concerns a process for realization of polymeric materials with second order nonlinear electro-optical properties comprising the following steps: mixing of a chromophore with nonlinear optical properties with two or three hydroxy groups; isolation of said pure bi- or tri-isocyanate NLO chromophores obtained according to the above step; dissolution of said bi- or tri-isocyanate NLO chromophores obtained according to the above step in one or more isocyanate group not reactive solvents containing reactive substances; coating of a thin layer of said prepolymer mixture on a substrate and evaporation of said not reactive solvents; cross-linking and poling of said thin layer on substrate, by means of heating and application of an electric field; cooling of said thin cross-linked and poled layer at ambient temperature maintaining the applied poling electric field; switching off the poling electric field.

摘要翻译： 本发明涉及一种用于实现具有二阶非线性电光学特性的聚合物材料的方法，其包括以下步骤：将发色团与非对称光学性质与两个或三个羟基混合; 分离根据上述步骤获得的所述纯的二异氰酸酯或三异氰酸酯NLO发色团; 将根据上述步骤获得的所述二异氰酸酯或三异氰酸酯NLO发色团溶解在一种或多种含反应性物质的异氰酸酯基团不反应性溶剂中; 将所述预聚物混合物的薄层涂覆在基材上并蒸发所述非反应性溶剂; 通过加热和施加电场来在衬底上交联和极化所述薄层; 在环境温度下冷却所述薄的交联和极化层，保持施加的极化电场; 关闭极化电场。