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公开(公告)号:US08932446B1
公开(公告)日:2015-01-13
申请号:US13891308
申请日:2013-05-10
IPC分类号: G01N27/333 , G01N27/26
CPC分类号: G01N27/333 , G01N27/26 , G01N2033/0093 , G01N2223/626
摘要: An apparatus for the real-time, in-situ monitoring of actinide-ion concentrations. A working electrolyte is positioned within the interior of a container. The working electrolyte is separated from a reference electrolyte by a separator. A working electrode is at least partially in contact with the working electrolyte. A reference electrode is at least partially in contact with the reference electrolyte. A voltmeter is electrically connected to the working electrode and the reference electrode. The working electrolyte comprises an actinide-ion of interest. The separator is ionically conductive to the actinide-ion of interest. The separator comprises an actinide, Zr, and Nb. Preferably, the actinide of the separator is Am or Np, more preferably Pu. In one embodiment, the actinide of the separator is the actinide of interest. In another embodiment, the separator further comprises P and O.
摘要翻译: 一种用于实时,原位监测锕系离子浓度的装置。 工作电解质位于容器的内部。 工作电解质通过分离器与参比电解质分离。 工作电极至少部分地与工作电解质接触。 参考电极至少部分地与参考电解质接触。 电压表电连接到工作电极和参考电极。 工作电解质包含感兴趣的锕系离子。 分离器对感兴趣的锕系离子导电。 分离器包括锕系元素,Zr和Nb。 优选地,分离器的锕系元素为Am或Np,更优选为Pu。 在一个实施方案中,分离器的锕系元素是感兴趣的锕系元素。 在另一个实施方案中,分离器还包含P和O.