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公开(公告)号:US4217431A
公开(公告)日:1980-08-12
申请号:US2330
申请日:1979-01-10
IPC分类号: C08F10/00 , C08F2/34 , C08F210/02 , C08F6/00
CPC分类号: C08F210/02
摘要: A continuous process for the manufacture of ethylene copolymers under high pressure and at high temperature in a polymerization zone, with transfer of the reaction mixture into a high pressure product isolation zone and from there into a low pressure product isolation zone, and recycling of the unconverted gas from the high pressure product isolation zone into the polymerization zone and from the low pressure product isolation zone into a low temperature separator, from where the comonomer separated off is recycled to the polymerization process, while the ethylene is discharged as off-gas. The gas taken off the low pressure product isolation zone is preferably compressed to from 10 to 20 bar and cooled to from -10.degree. to -30.degree. C. before it is fed into the low temperature separator. There is a substantial improvement in the efficiency of separating off the comonomer.
摘要翻译: 在高压和高温下在聚合区中制造乙烯共聚物的连续方法,将反应混合物转移到高压产物隔离区,并从那里转移到低压产物隔离区,并将未转化的 气体从高压产物隔离区进入聚合区,从低压产物隔离区进入低温分离器,从分离出的共聚单体再循环到聚合过程中,而乙烯作为废气排出。 从低压产品隔离区取出的气体优选压缩至10〜20巴,冷却至-10〜-30℃,然后送入低温分离器。 分离共聚单体的效率有显着改善。
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公开(公告)号:US4260722A
公开(公告)日:1981-04-07
申请号:US97838
申请日:1979-11-27
申请人: Klaus Pfleger , Wieland Zacher , Klaus Boettcher , Ronald Skorczyk , Oskar Buechner , Franz G. Mietzner
发明人: Klaus Pfleger , Wieland Zacher , Klaus Boettcher , Ronald Skorczyk , Oskar Buechner , Franz G. Mietzner
IPC分类号: C08F2/00 , C08F2/02 , C08F8/00 , C08F10/00 , C08F210/02
CPC分类号: C08F210/02
摘要: A process for the continuous production of an ethylene copolymer by compressing a mixture of ethylene and comonomer in a pre-compressor and a post-compressor, copolymerizing the mixture in a polymerization zone at a high temperature and high pressure, transferring the reaction mixture into a high pressure product isolation zone, from there into a low pressure product isolation zone and thereafter into a discharge extruder, and recycling the greater part of the unconverted monomer into the polymerization process and passing a small part of the unconverted gas into a low temperature isolation zone, in which process a small part of the gas recycled from the high pressure product isolation zone is passed into the low temperature isolation zone, which is preferably under a pressure of from 10 to 30 bar and at from -10.degree. to -50.degree. C., and all the gas taken off the low pressure product isolation zone is fed to the pre-compressor. Using the novel process, the separating-off of the comonomer which has remained unconverted in the polymerization process can be improved.
摘要翻译: 通过在预压缩机和后压缩机中压缩乙烯和共聚单体的混合物来连续生产乙烯共聚物的方法,在高温高压下将混合物在聚合区中共聚,将反应混合物转移到 高压产品隔离区,从那里进入低压产品隔离区,然后进入排出挤出机,并将大部分未转化的单体再循环到聚合过程中,并将未转化的气体的一小部分通入低温隔离区 在该方法中,将从高压产物隔离区再循环的少量气体通入低温隔离区,优选在10〜30巴的压力和-10℃〜-50℃ 将从低压产品隔离区取出的全部气体送入预压缩机。 使用该新方法,可以提高在聚合过程中保持未转化的共聚单体的分离。
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公开(公告)号:US4087601A
公开(公告)日:1978-05-02
申请号:US786406
申请日:1977-04-11
申请人: Klaus Pfleger , Wieland Zacher , Klaus Boettcher , Ronald Skorczyk , Oskar Buechner , Franz Georg Mietzner
发明人: Klaus Pfleger , Wieland Zacher , Klaus Boettcher , Ronald Skorczyk , Oskar Buechner , Franz Georg Mietzner
IPC分类号: G03C1/00 , C08F6/00 , C08F6/06 , C08F6/26 , C08F10/00 , C08F210/00 , C08F210/02 , C08F210/12 , G03F7/004
CPC分类号: C08F210/02 , C08F210/12
摘要: A process for the manufacture of copolymers of ethylene with n-butyl acrylate in a polymerization zone at pressures above 800 atmospheres and at from 150.degree. to 350.degree. C, wherein the reaction mixture obtained is transferred, via a cooling zone which is at a pressure below 500 atmospheres and at from 150.degree. to 250.degree. C, into the high pressure product isolation zone, the mean residence time of the reaction mixture in the two zones being from 2 to 10 minutes. A copolymer which gives good films is obtained.
摘要翻译: 一种在高于800大气压和150-350℃的压力下在聚合区中制造乙烯与丙烯酸正丁酯的共聚物的方法,其中所获得的反应混合物通过冷却区转移,该冷却区处于压力 低于500个大气压和150℃至250℃进入高压产物分离区,反应混合物在两个区域中的平均停留时间为2至10分钟。 得到得到良好膜的共聚物。
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