公开(公告)号：US06828269B2

公开(公告)日：2004-12-07

申请号：US09745441

申请日：2000-12-26

Applicant: Dominique Commereuc ,  Sébastien Drochon ,  Lucien Saussine

Inventor： Dominique Commereuc ,  Sébastien Drochon ,  Lucien Saussine

IPC: C08F200

CPC classification number: B01J31/2234 ,  B01J31/0214 ,  B01J31/143 ,  B01J31/34 ,  B01J2231/20 ,  B01J2531/62 ,  C07C2/30 ,  C07C2531/02 ,  C07C2531/14 ,  C08F10/00 ,  Y02P20/52 ,  C08F4/69

Abstract: A catalytic composition is obtained by mixing at least one chromium compound with at least one aryloxy compound of an element M selected from the group formed by magnesium, calcium, strontium and barium, with general formula M(RO)2-nXn, where RO is an aryloxy radical containing 6 to 80 carbon atoms, X is a halogen or a hydrocarbyl radical containing 1 to 30 carbon atoms and n is a whole number that can take values of 0 to 2, and with at least one aluminum compound selected from hydrocarbylaluminum compounds (tris(hydrocarbyl)-aluminum, chlorinated or brominated hydrocarbylaluminum compounds) and aluminoxanes. The catalytic composition can be used in an ethylene oligomerization process, in particular to produce 1-hexene.

Abstract translation: 通过将至少一种铬化合物与选自由镁，钙，锶和钡形成的基团的至少一种芳氧基化合物与通式M（RO）2-nXn混合，得到催化组合物，其中RO为 含有6〜80个碳原子的芳氧基，X是卤素或含有1至30个碳原子的烃基，n是可以取0至2的整数，并且与至少一种选自烃基铝化合物的铝化合物 （三（烃基）铝，氯化或溴化烃基铝化合物）和铝氧烷。 催化组合物可用于乙烯低聚方法，特别是生产1-己烯。

公开(公告)号：US06903042B2

公开(公告)日：2005-06-07

申请号：US10309336

申请日：2002-12-04

Applicant: Sébastien Drochon ,  Séverine Guibert ,  Lucien Saussine

Inventor： Sébastien Drochon ,  Séverine Guibert ,  Lucien Saussine

IPC: B01J31/04 ,  B01J31/12 ,  B01J31/14 ,  B01J31/00

CPC classification number: B01J31/143 ,  B01J31/0214 ,  B01J31/04 ,  B01J31/128 ,  B01J2231/20

Abstract: A catalytic composition for oligomerizing ethylene, in particular to 1-hexene, is obtained by mixing at least one chromium carboxylate characterized in that it also contains a free carboxylic acid in a set proportion, with at least one aryloxy compound of an element M selected from the group formed by magnesium, calcium, strontium and barium, with general formula M(RO)2-nXn in which RO is an aryloxy radical containing 6 to 80 carbon atoms, X is a halogen atom or a hydrocarbyl radical containing 1 to 30 carbon atoms and n is a whole number that can take the values 0 or 1, and with at least one hydrocarbylaluminum compound selected from the group formed by tris(hydrocarbyl)-aluminum compounds, chlorinated or brominated hydrocarbylaluminum compounds and aluminoxanes.

Abstract translation: 通过混合至少一种羧酸铬，其特征在于其还含有一定比例的游离羧酸，与至少一种选自以下的元素M的芳氧基化合物混合，得到用于使乙烯，特别是1-己烯低聚的催化组合物： 由镁，钙，锶和钡形成的基团，其通式为M（RO）2-n X X N，其中RO是含有6至80个碳的芳氧基 原子，X是卤素原子或含有1至30个碳原子的烃基，n是可以取0或1的整数，并且与至少一种烃基铝化合物选自由三（烃基） - 铝化合物，氯化或溴化烃基铝化合物和铝氧烷。