Abstract:
A gaseous process for reducing the amount of chloropentafluoroethane (CFC 115) impurity present in pentafluoroethane (HFC 125) characterized in that pentafluroethane is allowed to flow on a catalyst formed by a trivalent chromium salt, optionally supported, at temperatures in the range 200° C.-400° C., obtaining the reaction of chloropentafluoroethane with pentafluoroethane with formation of hexafluoroethane (FC 116) and tetrafluorochloroethane (HCFC 124).
Abstract:
A gaseous process for eliminating chlorine atoms from a chlorofluorocarbon (CFC) of formula CnFxCly, wherein n is an integer from 1 to 3 and x+y=2n+2, wherein said compound is reacted with an hydrofluorocarbon of formula Cn′Fx′Hy′, wherein n′, x′, y′ are as above defined, in the presence of a fluorination catalyst in solid phase at temperatures in the range 200° C.-400° C.
Abstract translation:用于从式C n F x Cly的氯氟烃(CFC)中除去氯原子的气态方法,其中n为1至3的整数,x + y = 2n + 2,其中所述化合物与式Cn'Fx'Hy的氢氟烃反应 ',其中n',x',y'如上所定义,在氟化催化剂存在下,在固相中的温度范围为200℃-400℃。