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1.发明授权Titanium (III) bases and .beta.-diketonate coordinated catalyst composition for preparing high-syndiotacticity polystyrene and processes using the same 失效用于制备高间同立构聚苯乙烯的钛（III）碱和β-二酮配位体配位催化剂组合物及其使用方法
公开(公告)号：US5756610A
公开(公告)日：1998-05-26
申请号：US781705
申请日：1997-01-10
申请人： Jing-Chemg Tsai , Kuang Kai Liu , Shu-Ling Peng , Shian-Jy Wang
发明人： Jing-Chemg Tsai , Kuang Kai Liu , Shu-Ling Peng , Shian-Jy Wang
摘要： A novel titanium (III)-based .beta.-diketonate-coordinated compound is disclosed for catalyzing the polymerization reaction of syndiotactic polystyrenes. The titanium (III)-based compound is represented by the following formula 1: ##STR1## wherein X is a C.sub.1 .about.C.sub.12 alkoxy or amine group, or a halogen atom; R is a C.sub.1 .about.C.sub.12 alkyl, aryl, or alkylsilane group. Preferably, X is N(SiMe.sub.3).sub.2 -- or OMe--, and R is phenyl, methyl, or t-butyl. The titanium (III)-based compounds are prepared by reacting titanium trichloride with diketone and tetrahydrofuran to form an intermediate product, then reacting the intermediate product Ti(AcAc)Cl.sub.2 (THF).sub.2 with either aminosilane or alcohol.
摘要翻译： 公开了一种新型的基于钛（III）的β-二酮配位化合物，用于催化间同立构聚苯乙烯的聚合反应。 基于钛（III）的化合物由下式1表示：其中X是C 1 -C 12烷氧基或胺基或卤素原子; R是C 1 -C 12烷基，芳基或烷基硅烷基。 优选地，X是N（SiMe 3）2 - 或OMe-，R是苯基，甲基或叔丁基。 基于钛（III）的化合物通过使三氯化钛与二酮和四氢呋喃反应形成中间产物，然后使中间产物Ti（AcAc）Cl 2（THF）2与氨基硅烷或醇反应来制备。
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2.发明授权Catalyst composition for preparing high syndiotacticity polystyrene from styrene of other arylethylene monomers and processes using the same 失效用于由其它芳基乙烯单体的苯乙烯制备高间同立构聚苯乙烯的催化剂组合物和使用其的方法
公开(公告)号：US5644009A
公开(公告)日：1997-07-01
申请号：US563272
申请日：1995-11-27
申请人： Jing-Cherng Tsai , Shian-Jy Wang , Shu-Ling Peng , Mickey Sue
发明人： Jing-Cherng Tsai , Shian-Jy Wang , Shu-Ling Peng , Mickey Sue
CPC分类号： C08F10/00 , C08F12/04 , C08F4/65904 , C08F4/65908 , C08F4/65912
摘要： An catalyst composition for preparing high-syndiotacticity polystyrene polymers which comprises: (a) a titanium complex represented by the following formula of TiR'.sub.1 R'.sub.2 R'.sub.3 R'.sub.4 or TiR'.sub.1 R'.sub.2 R'.sub.3, wherein R'.sub.1, R'.sub.2, R'.sub.3, and R'.sub.4 are, independently, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an amino group, a hydrogen atom, or a halogen atom; (b) a cyclopentadienyl complex of silicon (Si), germanium (Ge), or tin (Sn) represented by the following formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are, independently, an alkyl group, an aryl group, a silyl group, a germanyl group, a stannyl group, or a halogen atom; R is an alkyl group, aryl group, a hydrogen atom, or a halogen element; and X can be one of the Group IVA elements of silicon (Si), germanium (Ge), or tin (Sn); and (c) an activated transitional metal co-catalyst, which can be methyl aluminoxane, or a mixture containing a non-coordinated Lewis add (a Lewis acid is an electron-pair donor) and a trialkyl aluminum, such as triethyl aluminum or tetraisobutyl aluminum.
摘要翻译： 一种用于制备高间同立构聚苯乙烯聚合物的催化剂组合物，其包含：（a）由下式TiR'1R'2R'3R'4或TiR'1R'2R'3表示的钛络合物，其中R'1，R' 2，R'3和R '4独立地是烷基，芳基，烷氧基，芳氧基，氨基，氢原子或卤素原子; （b）由下式表示的硅（Si），锗（Ge）或锡（Sn）的环戊二烯基络合物：其中R 1，R 2，R 3和R 4独立地为烷基，芳基 基团，甲硅烷基，锗烷基，甲锡烷基或卤素原子; R是烷基，芳基，氢原子或卤素元素; X可以是硅（Si），锗（Ge）或锡（Sn）的IVA族元素之一; 和（c）活化的过渡金属助催化剂，其可以是甲基铝氧烷，或含有不协调的路易斯添加剂（路易斯酸是电子对供体）和三烷基铝的混合物，例如三乙基铝或四异丁基 铝。
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3.发明授权Catalyst composition for preparing high-syndiotactivity polystyrene from styrene or other aryl ethylene monomers and processes using the same 失效用于由苯乙烯或其它芳基乙烯单体制备高间同立构聚苯乙烯的催化剂组合物及使用其的方法
公开(公告)号：US5914375A
公开(公告)日：1999-06-22
申请号：US905620
申请日：1997-08-04
CPC分类号： C08F12/04
摘要： An catalyst composition for preparing high-syndiotacticity polystyrene polymers which comprises: (a) a titanium complex represented by the following formula of TiR'.sub.1 R'.sub.2 R'.sub.3 R'.sub.4 or TiR'.sub.1 R'.sub.2 R'.sub.3, wherein R'.sub.1, R'.sub.2, R'.sub.3, and R'.sub.4 are, independently, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an amino group, a hydrogen atom, or a halogen atom; (b) a cyclopentadienyl complex of silicon (Si), germanium (Ge), or tin (Sn) represented by the following formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 can be, independently, alkyl group, aryl group, silyl group, germanyl group, stannyl group, hydrogen atom, or halogen atom; R is an alkyl group, aryl group, hydrogen atom, or halogen atom; and X can be one of the Group IVA elements of silicon (Si), germanium (Ge), or tin (Sn); and (c) an activated transitional metal co-catalyst, which can be methyl aluminoxane, or a mixture containing a non-coordinated Lewis acid (a Lewis acid is an electron-pair donor) and a trialkyl aluminum, such as triethyl aluminum or tetraisobutyl aluminum. R.sub.1 and R.sub.2 and R.sub.3 and R.sub.4, respectively, can also be part of a benzene ring.
摘要翻译： 一种用于制备高间同立构聚苯乙烯聚合物的催化剂组合物，其包含：（a）由下式TiR'1R'2R'3R'4或TiR'1R'2R'3表示的钛络合物，其中R'1，R' 2，R'3和R '4独立地是烷基，芳基，烷氧基，芳氧基，氨基，氢原子或卤素原子; （b）由下式表示的硅（Si），锗（Ge）或锡（Sn）的环戊二烯基络合物：其中R1，R2，R3，R4和R5可以独立地为烷基，芳基，甲硅烷基 基团，锗烷基，甲锡烷基，氢原子或卤素原子; R是烷基，芳基，氢原子或卤素原子; X可以是硅（Si），锗（Ge）或锡（Sn）的IVA族元素之一; 和（c）活化的过渡金属助催化剂，其可以是甲基铝氧烷，或含有非配位路易斯酸（路易斯酸是电子对供体）和三烷基铝的混合物，例如三乙基铝或四异丁基 铝。 R1和R2以及R3和R4分别也可以是苯环的一部分。
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