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公开(公告)号:US20060117648A1
公开(公告)日:2006-06-08
申请号:US11235075
申请日:2005-09-27
Applicant: Yuen Choo , Sit Cheng , Ah Ma , Yusof Basiron
Inventor: Yuen Choo , Sit Cheng , Ah Ma , Yusof Basiron
IPC: C10L1/18
Abstract: A lubricity additive for fuels with sulphur content of not more than 0.05 wt % is described herein. The lubricity additive comprises a polyol ester or a mixture of polyol esters derived from C8-C18 saturated and/or unsaturated fatty acids. The polyol esters is produced by: i) esterification of a C8-C18 saturated or unsaturated fatty acids, or a mixture thereof, with a polyhydric alcohol; ii) transesterification of an oil or a mixture of oils, with fatty acid composition comprising C8-C18 saturated and/or unsaturated fatty acids, with a polyhydric alcohol. The preferred fatty acids are unsaturated C18 fatty acids, more particularly, oleic acid whereas the preferred polyhydric alcohol is neopolyol, more particularly, trimethylol propane and its isomers. A fuel composition comprising a major amount of fuel with sulphur content of not more than 0.05 wt % and a minor amount of the lubricity additive is also described herein. The amount of the lubricity additive is not more than 0.1 wt %.
Abstract translation: 本文描述了硫含量不超过0.05重量%的燃料的润滑添加剂。 润滑添加剂包括多元醇酯或衍生自C 8 -C 18饱和和/或不饱和脂肪酸的多元醇酯的混合物。 多元醇酯通过以下方法制备:i)饱和或不饱和脂肪酸或其混合物与多元醇的酯化反应; ii)油或油的混合物与包含C 8 -C 18 - 饱和和/或不饱和脂肪酸的脂肪酸组合物与多元醇的酯交换反应。 优选的脂肪酸是不饱和C 18脂肪酸,更特别是油酸,而优选的多元醇是neolyol,更特别的是三羟甲基丙烷及其异构体。 本文还描述了包含硫含量不超过0.05重量%的主要量的燃料和少量润滑性添加剂的燃料组合物。 润滑添加剂的量不超过0.1重量%。
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公开(公告)号:US20060128979A1
公开(公告)日:2006-06-15
申请号:US11232461
申请日:2005-09-21
Applicant: Yuen Choo , Sit Cheng , Ah Ma , Yusof Basiron
Inventor: Yuen Choo , Sit Cheng , Ah Ma , Yusof Basiron
IPC: C07C51/43
Abstract: The present invention relates to a process for producing high purity monoglycerides from edible oils/fats and fatty acids through glycerolysis, in particular but not exclusively to the production of monoglycerides from palm oil and palm oil products. This is achieved by providing a process for the production of monoglycerides of fatty acids or fats and oils, comprising the steps of reacting fatty acids or fats and oils with excess glycerol in the presence of an acidic or alkaline catalyst; substantially separating the crude reaction product from the other reaction components; removing unwanted reaction components from the crude reaction product by washing; drying the reaction product.
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公开(公告)号:US20050119137A1
公开(公告)日:2005-06-02
申请号:US10979782
申请日:2004-11-01
Applicant: Yuen Choo , Sit Cheng , Ah Ma , Basiron Yusof
Inventor: Yuen Choo , Sit Cheng , Ah Ma , Basiron Yusof
IPC: C07C67/08 , C07C69/22 , C10M105/34 , C10M105/38 , C10M177/00 , C10M15/34
CPC classification number: C10M177/00 , C07C67/08 , C10M105/34 , C10M105/38 , C10M2207/2815 , C10M2207/2835 , C10N2220/10 , C10N2220/14 , C10N2230/02 , C10N2230/04 , C10N2230/64 , C07C69/24 , C07C69/52 , C07C69/28 , C07C69/30 , C07C69/33
Abstract: A cost effective and less energy demanding method of producing ester oils or lubricant base oils, particularly fatty monoesters and fatty polyol esters, by esterifying palm fatty acid, which is abundant from the fat splitting process, with a monohydric alcohol or polyhydric alcohol in the presence of an acid catalyst at elevated temperature wherein an azeotroping agent, particularly toluene, is used to facilitate continuous removal by distillation, of water formed as a by-product during the esterification reaction. The esterification reaction is completed within 5 hours and palm fatty esters as produced with the current method exhibit comparable lubricity and biodegradability.
Abstract translation: 在脂肪分解过程中将棕榈脂肪酸与一元醇或多元醇酯化在一起存在下,通过酯化棕榈脂肪酸来生产酯油或润滑油基础油,特别是脂肪单酯和脂肪多元醇酯的成本有效且能耗低的方法 的酸催化剂,其中使用共沸剂,特别是甲苯来促进通过蒸馏连续除去在酯化反应期间作为副产物形成的水。 酯化反应在5小时内完成,用本方法生产的棕榈脂肪酯显示出相当的润滑性和生物降解性。
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