公开(公告)号：US08865931B2

公开(公告)日：2014-10-21

申请号：US13704057

申请日：2011-06-10

申请人： Thomas Peter Anne Goossens ,  Freek Annie Camiel Vrielynck ,  Noel Gabriel Cornelius Hosten ,  Koen Jeanne Alfons Van Aken

发明人： Thomas Peter Anne Goossens ,  Freek Annie Camiel Vrielynck ,  Noel Gabriel Cornelius Hosten ,  Koen Jeanne Alfons Van Aken

IPC分类号： C07C67/02 ,  B01J31/26 ,  C07C68/06 ,  C07C67/03 ,  B01J31/22

CPC分类号： C07C67/03 ,  B01J31/2234 ,  B01J31/26 ,  B01J2231/49 ,  B01J2531/26 ,  B01J2531/842 ,  C07C67/28 ,  C07C68/06 ,  C07C69/157 ,  C07C69/54 ,  C07C69/78 ,  C07C69/82 ,  C07C69/24 ,  C07C69/16 ,  C07C69/68 ,  C07C69/96

摘要： This invention is directed to a process for the production of a variety of esters, particularly acrylate and methacrylate-based esters, by a transesterification reaction. This objective is achieved by reaction of an ester of a carboxylic or a carbonic acid, in particular of a saturated or unsaturated, typically, a 3 to 4 carbon atom carboxylic acid; with an alcohol in the presence of a catalyst comprising the combination of a metal 1,3-dicarbonyl complex (pref. Zn or Fe acetylacetonate) and a salt, in particular an inorganic salt, pref. ZnCl2, LiCI, NaCI, NH4CI or Lil. These catalysts are prepared from readily available starting materials within the reaction medium without the need for isolation (in-situ preparation).

摘要翻译： 本发明涉及通过酯交换反应生产各种酯，特别是丙烯酸酯和甲基丙烯酸酯的酯的方法。 该目的通过羧酸或碳酸的酯，特别是饱和或不饱和的，通常为3至4个碳原子的羧酸的反应来实现; 在含有金属1,3-二羰基络合物（优选Zn或Fe乙酰丙酮化物））和盐（特别是无机盐）的组合的催化剂存在下进行。 ZnCl 2，LiCl，NaCl，NH 4 Cl或Lil。 这些催化剂由反应介质中容易获得的原料制备而不需要分离（原位制备）。

公开(公告)号：US20130090492A1

公开(公告)日：2013-04-11

申请号：US13704057

申请日：2011-06-10

申请人： Thomas Peter Anne Goossens ,  Freek Annie Camiel Vrielynck ,  Noel Gabriel Cornelius Hosten ,  Koen Jeanne Alfons Van Aken

发明人： Thomas Peter Anne Goossens ,  Freek Annie Camiel Vrielynck ,  Noel Gabriel Cornelius Hosten ,  Koen Jeanne Alfons Van Aken

IPC分类号： C07C67/03 ,  B01J31/26 ,  B01J31/22 ,  C07C67/28 ,  C07C68/06

CPC分类号： C07C67/03 ,  B01J31/2234 ,  B01J31/26 ,  B01J2231/49 ,  B01J2531/26 ,  B01J2531/842 ,  C07C67/28 ,  C07C68/06 ,  C07C69/157 ,  C07C69/54 ,  C07C69/78 ,  C07C69/82 ,  C07C69/24 ,  C07C69/16 ,  C07C69/68 ,  C07C69/96

摘要： This invention is directed to a general catalyst of high activity and selectivity for the production of a variety of esters, particularly acrylate and methacrylate-based esters, by a transesterification reaction. This objective is achieved by reaction of an ester of a carboxylic or a carbonic acid, in particular of a saturated or unsaturated, typically, a 3 to 4 carbon atom carboxylic acid; with an alcohol in the presence of a catalyst comprising the combination of a metal 1,3-dicarbonyl complex (pref. Zn or Fe acetylacetonate) and a salt, in particular an inorganic salt, pref. ZnCl2, LiCI, NaCI, NH4CI or Lil. These catalysts are prepared from readily available starting materials within the reaction medium without the need for isolation (in-situ preparation).

摘要翻译： 本发明涉及通过酯交换反应生产各种酯，特别是丙烯酸酯和甲基丙烯酸酯的酯的高活性和选择性的一般催化剂。 该目的通过羧酸或碳酸的酯，特别是饱和或不饱和的，通常为3至4个碳原子的羧酸的反应来实现; 在含有金属1,3-二羰基络合物（优选Zn或Fe乙酰丙酮化物））和盐（特别是无机盐）的组合的催化剂存在下进行。 ZnCl 2，LiCl，NaCl，NH 4 Cl或Lil。 这些催化剂由反应介质中容易获得的原料制备而不需要分离（原位制备）。