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公开(公告)号：US08661993B2
公开(公告)日：2014-03-04
申请号：US12809347
申请日：2009-02-09
Applicant: Naoyuki Kamiyama , Tomoo Akiyama , Toshihiko Setoguchi , Koutaro Fujimura , Yoshihisa Yamamoto , Koichi Tagami , Yasutoshi Ueda
Inventor： Naoyuki Kamiyama , Tomoo Akiyama , Toshihiko Setoguchi , Koutaro Fujimura , Yoshihisa Yamamoto , Koichi Tagami , Yasutoshi Ueda
IPC: F23J3/00
CPC classification number: F23J15/003 , F23J15/02 , F23J15/06 , F23J2215/101 , F23J2215/20 , F23J2217/102 , Y02E20/363
Abstract: In an exhaust gas treatment system including a denitration device that removes nitrogen oxide in exhaust gas from a heavy fuel-fired boiler, an air preheater that recovers heat in the gas after the nitrogen oxide is removed, an electric precipitator that removes dust while adding ammonia into the gas after heat recovery, a desulfurization device that removes sulfur oxide in the gas after dust removal, and a stack that exhausts the gas after desulfurization to the outside, an ash-shear-force measuring instrument is provided to measure an ash shear force, which is ash flowability, on the downstream side of the electric precipitator, so that a feed rate of an air supply unit that supplies air to the boiler is reduced according to ash shear-force information.
Abstract translation: 在包含从重燃燃烧锅炉排出的废气中的氮氧化物的脱硝装置的废气处理系统中，除去氮氧化物后，在气体中回收热量的空气预热器，除去灰尘的电除尘器， 进入热回收后的气体中，除尘后除去气体中的硫氧化物的脱硫装置，以及将脱硫后的气体排出到外部的叠层，设置灰剪切力测定装置，测定灰分剪切力 ，其是灰尘流动性，在电除尘器的下游侧，使得根据灰分剪切力信息减少向锅炉供应空气的供气单元的进料速率。
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公开(公告)号：US20110060162A1
公开(公告)日：2011-03-10
申请号：US12991197
申请日：2009-05-28
Applicant: Kiyoshi Tatsuhara , Tomoaki Sugiyama , Atsushi Tanaka , Toshihiko Setoguchi
Inventor： Kiyoshi Tatsuhara , Tomoaki Sugiyama , Atsushi Tanaka , Toshihiko Setoguchi
CPC classification number: B82Y40/00 , B01J8/005 , B01J8/1836 , B01J2208/00592 , B01J2208/00681 , B01J2219/00006 , B82Y30/00 , C01B32/162
Abstract: Included are a nano-carbon material production unit for producing a nano-carbon material using a fluidized catalyst formed by granulating a carrier supporting an active component, an acid treatment unit for dissolving and separating a catalyst by an acid solution by feeding a catalyst-containing nano-carbon material into the acid solution, and a pH adjustment unit, which is an anti-agglomeration treatment unit, provided on a downstream side of the acid treatment unit, for performing an anti-agglomeration treatment to prevent agglomeration among nano-carbons due to repulsion caused by dissociation among oxygen-containing functional groups added to the nano-carbon material.
Abstract translation: 包括使用流化催化剂制造纳米碳材料的纳米碳材料生产单元，所述流化催化剂通过使支撑活性组分的载体成粒而形成，酸处理单元，用于通过酸溶液溶解和分离催化剂， 将酸性溶液中的纳米碳材料和作为抗附聚处理单元的pH调节单元设置在酸处理单元的下游侧，进行抗附聚处理以防止纳米碳之间的附聚 由添加到纳米碳材料中的含氧官能团之间的离解引起的排斥。
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3.发明授权Heat-treated active carbons for use in denitration, processes for producing same, denitration method using same, and denitration system using same 失效用于脱硝的热处理活性炭，其制造方法，使用其的脱硝方法和使用其的脱硝系统公开(公告)号：US07655204B2
公开(公告)日：2010-02-02
申请号：US12292273
申请日：2008-11-14
Applicant: Isao Mochida , Akinori Yasutake , Toshihiko Setoguchi , Norihisa Kobayashi , Takahiro Kasuh , Masaaki Yoshikawa
Inventor： Isao Mochida , Akinori Yasutake , Toshihiko Setoguchi , Norihisa Kobayashi , Takahiro Kasuh , Masaaki Yoshikawa
IPC: B01D53/56
CPC classification number: B01J21/18 , B01D53/8628 , B01D2255/702
Abstract: This invention relates to a technique for removing nitrogen oxides (NOx) present in exhaust gases discharged from boilers and the like. When the temperature of the exhaust gas is 100° C. or below, a heat-treated active carbon produced by heat-treating a raw active carbon at 600 to 1,200° C. in a non-oxidizing atmosphere so as to remove oxygen-containing functional groups present at the surfaces thereof and thereby reduce the atomic surface oxygen/surface carbon ratio to 0.05 or less is preferably used. When the temperature of the exhaust gas exceeds 100° C., a heat-treated active carbon produced by heat-treating a raw active carbon at 600 to 1,200° C. in a non-oxidizing atmosphere and activating the surfaces thereof with sulfuric acid or nitric acid to impart oxidizing oxygen-containing functional groups thereto is preferably used.
Abstract translation: 本发明涉及一种除去从锅炉等排出的废气中存在的氮氧化物（NOx）的技术。 当废气的温度为100℃以下时，通过在非氧化性气氛中将600〜1200℃的原料活性炭进行热处理而除去含氧的热处理活性炭 优选使用其表面存在的官能团，从而将原子表面氧/表面碳比降低至0.05以下。 当废气温度超过100℃时，通过在非氧化性气氛中将原料活性炭在600〜1200℃下热处理而生成的热处理活性炭，并用硫酸或 优选使用硝酸赋予其氧化性含氧官能团。
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4.发明申请Heat-treated active carbons for use in denitration, processes for producing same, denitration method using same, and denitration system using same 失效用于脱硝的热处理活性炭，其制造方法，使用其的脱硝方法和使用其的脱硝系统公开(公告)号：US20090081097A1
公开(公告)日：2009-03-26
申请号：US12292273
申请日：2008-11-14
Applicant: Isao Mochida , Akinori Yasutake , Toshihiko Setoguchi , Norihisa Kobayashi , Takahiro Kasuh , Masaaki Yoshikawa
Inventor： Isao Mochida , Akinori Yasutake , Toshihiko Setoguchi , Norihisa Kobayashi , Takahiro Kasuh , Masaaki Yoshikawa
IPC: B01D53/56
CPC classification number: B01J21/18 , B01D53/8628 , B01D2255/702
Abstract: This invention relates to a technique for removing nitrogen oxides (NOx) present in exhaust gases discharged from boilers and the like. When the temperature of the exhaust gas is 100° C. or below, a heat-treated active carbon produced by heat-treating a raw active carbon at 600 to 1,200° C. in a non-oxidizing atmosphere so as to remove oxygen-containing functional groups present at the surfaces thereof and thereby reduce the atomic surface oxygen/surface carbon ratio to 0.05 or less is preferably used. When the temperature of the exhaust gas exceeds 100° C., a heat-treated active carbon produced by heat-treating a raw active carbon at 600 to 1,200° C. in a non-oxidizing atmosphere and activating the surfaces thereof with sulfuric acid or nitric acid to impart oxidizing oxygen-containing functional groups thereto is preferably used.
Abstract translation: 本发明涉及一种除去从锅炉等排出的废气中存在的氮氧化物（NOx）的技术。 当废气的温度为100℃以下时，通过在非氧化性气氛中将600〜1200℃的原料活性炭进行热处理而除去含氧的热处理活性炭 优选使用其表面存在的官能团，从而将原子表面氧/表面碳比降低至0.05以下。 当废气温度超过100℃时，通过在非氧化性气氛中将原料活性炭在600〜1200℃下热处理而生成的热处理活性炭，并用硫酸或 优选使用硝酸赋予其氧化性含氧官能团。
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5.发明申请Carbon nano-fibrous rod, fibrous nano carbon, and method and apparatus for preparing fibrous nano carbon 有权碳纳米纤维棒，纤维状纳米碳，以及制备纤维状纳米碳的方法和装置公开(公告)号：US20060057054A1
公开(公告)日：2006-03-16
申请号：US10537151
申请日：2003-11-21
Applicant: Yuichi Fujioka , Akinori Yasutake , Toshihiko Setoguchi , Isao Mochida
Inventor： Yuichi Fujioka , Akinori Yasutake , Toshihiko Setoguchi , Isao Mochida
CPC classification number: B82Y40/00 , B82Y30/00 , C01B32/05 , C01B32/162 , C01B32/18 , D01F9/127 , D01F9/1273 , D01F9/133
Abstract: A carbon nano-fibrous rod 12 is constituted of a hexagonal carbon layer 11 having a central axis extending in one direction, and the carbon nano-fibrous rods 12 are three-dimensionally gathered to form fibrous nanocarbon.
Abstract translation: 碳纳米纤维杆12由具有沿一个方向延伸的中心轴的六方碳层11构成，碳纳米纤维杆12三维聚集形成纤维状纳米碳。
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Patent Agency Ranking6.发明授权Heat-treated active carbons for use in denitration, processes for producing same denitration method using same, and denitration systems using same 失效用于脱硝的热处理活性炭，使用相同脱硝方法的方法以及使用其的脱硝系统
公开(公告)号：US6127312A
公开(公告)日：2000-10-03
申请号：US817659
申请日：1997-04-22
Applicant: Isao Mochida , Akinori Yasutake , Toshihiko Setoguchi , Norihisa Kobayashi , Takahiro Kasuh , Masaaki Yoshikawa
Inventor： Isao Mochida , Akinori Yasutake , Toshihiko Setoguchi , Norihisa Kobayashi , Takahiro Kasuh , Masaaki Yoshikawa
CPC classification number: B01J21/18 , B01D53/8628 , B01D2255/702
Abstract: This invention relates to a technique for removing nitrogen oxides (NO.sub.x) present in exhaust gases discharged from boilers and the like. When the temperature of the exhaust gas is 100.degree. C. or below, a heat-treated active carbon produced by heat-treating a raw active carbon at 600 to 1,200.degree. C. in a non-oxidizing atmosphere so as to remove oxygen-containing functional groups present at the surfaces thereof and thereby reduce the atomic surface oxygen/surface carbon ratio to 0.05 or less is preferably used. When the temperature of the exhaust gas exceeds 100.degree. C., a heat-treated active carbon produced by heat-treating a raw active carbon at 600 to 1,200.degree. C. in a non-oxidizing atmosphere and activating the surfaces thereof with sulfuric acid or nitric acid to impart oxidizing oxygen-containing functional groups thereto is preferably used.
Abstract translation: PCT No.PCT / JP96 / 02737第 371日期1997年04月22日 102（e）1997年4月22日PCT PCT 1996年9月24日PCT公布。 公开号WO97 / 12671 日期1997年04月10日本发明涉及一种除去从锅炉等排出的排气中存在的氮氧化物（NOx）的技术。 当废气的温度为100℃以下时，通过在非氧化性气氛中在600〜1200℃下热处理原料活性炭而生成的热处理活性炭，以除去含氧的 优选使用其表面存在的官能团，从而将原子表面氧/表面碳比降低至0.05以下。 当废气的温度超过100℃时，将热处理的活性炭在600-2200℃下在非氧化性气氛中热处理，并将其表面用硫酸或 优选使用硝酸赋予其氧化性含氧官能团。
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公开(公告)号：US08318124B2
公开(公告)日：2012-11-27
申请号：US10540974
申请日：2003-11-27
Applicant: Yuichi Fujioka , Toshihiko Setoguchi , Kazuya Suenaga , Susumu Miki
Inventor： Yuichi Fujioka , Toshihiko Setoguchi , Kazuya Suenaga , Susumu Miki
CPC classification number: B82Y30/00 , B82Y40/00 , C01B32/162 , D01F9/127 , D01F9/133
Abstract: The present invention is provided with a reaction apparatus (12) that supplies carbon raw material (11) and fine particles (50) to cause carbon nanofibers to grow on surfaces of the fine particles (50), a heating apparatus (20) that heats the reaction apparatus 12, a recovery line (23) that recovers fine particles on which the carbon nanofibers have grown from the reaction apparatus, and a carbon nanofiber separating apparatus (24) that separates carbon nanofibers (52) from the recovered fine particles on which carbon nanofibers have been grown.
Abstract translation: 本发明提供一种提供碳原料（11）和微粒（50）以使碳纳米纤维在细颗粒（50）的表面上生长的反应装置（12），加热装置（20） 反应装置12，从反应装置回收碳纳米纤维生长的细小颗粒的回收管线（23）和碳纳米纤维分离装置（24），其将碳纳米纤维（52）与回收的微粒分离， 已经生长了碳纳米纤维。
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8.发明授权Carbon nano-fibrous rod, fibrous nanocarbon, and method and apparatus for producing fibrous nanocarbon 有权碳纳米纤维棒，纤维状纳米碳纤维，以及纤维状纳米碳纤维的制造方法和装置公开(公告)号：US07700065B2
公开(公告)日：2010-04-20
申请号：US10537151
申请日：2003-11-21
Applicant: Yuichi Fujioka , Akinori Yasutake , Toshihiko Setoguchi , Isao Mochida , Seong-Ho Yoon
Inventor： Yuichi Fujioka , Akinori Yasutake , Toshihiko Setoguchi , Isao Mochida , Seong-Ho Yoon
CPC classification number: B82Y40/00 , B82Y30/00 , C01B32/05 , C01B32/162 , C01B32/18 , D01F9/127 , D01F9/1273 , D01F9/133
Abstract: A carbon nano-fibrous rod including a predetermined number of hexagonal carbon layers extending in one direction, and a fibrous nanoncarbon which includes a plurality of the carbon nano-fibrous rods three-dimensionally gathered are disclosed.
Abstract translation: 公开了一种包括在一个方向上延伸的预定数量的六方碳层的碳纳米纤维棒和包括多个碳纳米纤维棒三维聚集的纤维状纳米碳。
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公开(公告)号：US06228336B1
公开(公告)日：2001-05-08
申请号：US09373579
申请日：1999-08-13
Applicant: Yasuo Katsuki , Takashi Ohnishi , Shozo Kaneko , Akira Hashimoto , Yuichi Fujioka , Kikuo Tokunaga , Toshihiko Setoguchi
Inventor： Yasuo Katsuki , Takashi Ohnishi , Shozo Kaneko , Akira Hashimoto , Yuichi Fujioka , Kikuo Tokunaga , Toshihiko Setoguchi
IPC: B01J800
CPC classification number: B01D50/002 , B01D53/508
Abstract: A dust collecting apparatus and method for dedusting a Ca-containing gas using a ceramics filter is provided, in which a filter differential pressure elevation rate is suppressed. A desulferizing agent 103 and a mineral 106 containing MgO are supplied via a hopper 13, 15 a valve 14 and a feeder 16 into a pressurized fluidized-bed combustion furnace 1 together with coal 101 and air 102. A combustion gas 201 is dedusted by a cyclone 2 to become a combustion gas 301, the combustion gas 301 enters a filter container 3a, 3b having a ceramics filter 31a, 31b and is further dedusted. A combustion gas 401 which is dedusted is supplied into a gas turbine 4 to generate power, and combustion gas 501 heats a waste heat recovery boiler 5 which in turn drives a steam turbine 7. The mineral 106 containing MgO is added in the combustion gas 301 which flows in the ceramics filter 31a, 31b. Thereby MgO is added to the combustion gas so that the filter differential pressure elevation rate can be suppressed. The more MgO that is supplied, the greater the effect becomes, and an operation stop due to the differential pressure elevation is eliminated.
Abstract translation: 提供一种使用陶瓷过滤器除尘含Ca气体的集尘装置和方法，其中抑制了过滤器差压升高速率。 脱硫剂103和含有MgO的矿物106通过料斗13,15，阀14和进料器16与煤101和空气102一起供应到加压流化床燃烧炉1中。燃烧气体201通过 旋风分离器2成为燃烧气体301，燃烧气体301进入具有陶瓷过滤器31a，31b的过滤容器3a，3b，并进一步除尘。 将除尘的燃烧气体401供给燃气轮机4发电，燃烧气体501加热余热回收锅炉5，废热回收锅炉5又驱动蒸汽轮机7.含有MgO的矿物106加入燃烧气体301 其在陶瓷过滤器31a，31b中流动。 由此，将MgO添加到燃烧气体中，从而可以抑制过滤器差压提升率。 供给的MgO越多，效果越大，并且消除由于差压升高引起的操作停止。
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公开(公告)号：US20060104887A1
公开(公告)日：2006-05-18
申请号：US10540974
申请日：2003-11-27
Applicant: Yuichi Fujioka , Toshihiko Setoguchi , Kazuya Suenaga , Susumu Miki
Inventor： Yuichi Fujioka , Toshihiko Setoguchi , Kazuya Suenaga , Susumu Miki
IPC: D01F9/12
CPC classification number: B82Y30/00 , B82Y40/00 , C01B32/162 , D01F9/127 , D01F9/133
Abstract: The present invention is provided with a reaction apparatus (12) that supplies carbon raw material (11) and fine particles (50) to cause carbon nanofibers to grow on surfaces of the fine particles (50), a heating apparatus (20) that heats the reaction apparatus 12, a recovery line (23) that recovers fine particles on which the carbon nanofibers have grown from the reaction apparatus, and a carbon nanofiber separating apparatus (24) that separates carbon nanofibers (52) from the recovered fine particles on which carbon nanofibers have been grown.
Abstract translation: 本发明提供一种提供碳原料（11）和微粒（50）以使碳纳米纤维在细颗粒（50）的表面上生长的反应装置（12），加热装置（20） 反应装置12，从反应装置回收碳纳米纤维生长的细小颗粒的回收管线（23）和碳纳米纤维分离装置（24），其将碳纳米纤维（52）与回收的微粒分离， 已经生长了碳纳米纤维。
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