公开(公告)号：US20060057054A1

公开(公告)日：2006-03-16

申请号：US10537151

申请日：2003-11-21

申请人： Yuichi Fujioka ,  Akinori Yasutake ,  Toshihiko Setoguchi ,  Isao Mochida

发明人： Yuichi Fujioka ,  Akinori Yasutake ,  Toshihiko Setoguchi ,  Isao Mochida

IPC分类号： D01F9/12 ,  B01J8/08 ,  B01J8/04

CPC分类号： B82Y40/00 ,  B82Y30/00 ,  C01B32/05 ,  C01B32/162 ,  C01B32/18 ,  D01F9/127 ,  D01F9/1273 ,  D01F9/133

摘要： A carbon nano-fibrous rod 12 is constituted of a hexagonal carbon layer 11 having a central axis extending in one direction, and the carbon nano-fibrous rods 12 are three-dimensionally gathered to form fibrous nanocarbon.

摘要翻译： 碳纳米纤维杆12由具有沿一个方向延伸的中心轴的六方碳层11构成，碳纳米纤维杆12三维聚集形成纤维状纳米碳。

公开(公告)号：US07700065B2

公开(公告)日：2010-04-20

申请号：US10537151

申请日：2003-11-21

申请人： Yuichi Fujioka ,  Akinori Yasutake ,  Toshihiko Setoguchi ,  Isao Mochida ,  Seong-Ho Yoon

发明人： Yuichi Fujioka ,  Akinori Yasutake ,  Toshihiko Setoguchi ,  Isao Mochida ,  Seong-Ho Yoon

IPC分类号： D01F9/12 ,  D01C5/00

CPC分类号： B82Y40/00 ,  B82Y30/00 ,  C01B32/05 ,  C01B32/162 ,  C01B32/18 ,  D01F9/127 ,  D01F9/1273 ,  D01F9/133

摘要： A carbon nano-fibrous rod including a predetermined number of hexagonal carbon layers extending in one direction, and a fibrous nanoncarbon which includes a plurality of the carbon nano-fibrous rods three-dimensionally gathered are disclosed.

摘要翻译： 公开了一种包括在一个方向上延伸的预定数量的六方碳层的碳纳米纤维棒和包括多个碳纳米纤维棒三维聚集的纤维状纳米碳。

公开(公告)号：US06631612B1

公开(公告)日：2003-10-14

申请号：US09736255

申请日：2000-12-15

申请人： Toshihiko Setoguchi ,  Yuichi Fujioka ,  Yoshihiko Tsuchiyama ,  Toshiaki Ohkubo ,  Akinori Yasutake ,  Norihisa Kobayashi ,  Akira Hattori

发明人： Toshihiko Setoguchi ,  Yuichi Fujioka ,  Yoshihiko Tsuchiyama ,  Toshiaki Ohkubo ,  Akinori Yasutake ,  Norihisa Kobayashi ,  Akira Hattori

IPC分类号： F01N300

CPC分类号： F01N3/0215 ,  B01D53/8631 ,  B01D53/864 ,  B01D53/885 ,  B01D53/9431 ,  B01D53/944 ,  F01N3/023 ,  F01N3/035 ,  F01N3/08 ,  F01N2250/02 ,  F01N2290/02 ,  F23J15/025 ,  F23J2219/20

摘要： A device to eliminate particulates contained in exhaust gas ejected from motors, such as diesel engines for ships, surface transportation vehicles and overland fixed diesel engines, and a process to eliminate particulates contained in the exhaust gas are provided. The device of the present invention is a device for eliminating particulates contained in exhaust gas 10 ejected from diesel engines constituted by a discoid-shaped filter 11 used as a capturing means to capture the particulates and sprayers 13 having a plurality of nozzles 13a, such as spray type and shower type, used as a catalyst attaching means to attach an alkaline metal catalyst solution 12 onto the surface of the captured particulates in the discoid-shaped filter 11, and the device attaches the catalyst onto the surface of the captured particulates, and then burns and decomposes the unburned particulates portion in the exhaust gas.

摘要翻译： 提供了一种消除从电动机排出的废气中所含的微粒的装置，例如用于船舶，地面运输车辆和陆上固定式柴油机的柴油发动机，以及消除废气中所含的微粒的方法。 本发明是一种用于消除由盘状过滤器（HIL＆amp; PDAT）11构成的柴油发动机排出的废气 10 中所含的微粒的装置。 PDAT>用作捕获具有多个喷嘴的颗粒和喷雾器 13 的捕获装置 a 用作催化剂附着装置的喷雾型和淋浴型的 将碱性金属催化剂溶液 附着在捕获的颗粒表面上 在盘状过滤器 11 中，并且该装置将催化剂附着到所捕获的颗粒的表面上，a 然后燃烧和分解废气中未燃烧的颗粒部分。

公开(公告)号：US06905544B2

公开(公告)日：2005-06-14

申请号：US10369749

申请日：2003-02-21

申请人： Toshihiko Setoguchi ,  Yuichi Fujioka ,  Yoshihiko Tsuchiyama ,  Akinori Yasutake ,  Matsuhei Noda ,  Norihisa Kobayashi ,  Ryoichi Nishida ,  Hitoshi Nishino ,  Katsuhide Okimi ,  Akihiro Hachiya

发明人： Toshihiko Setoguchi ,  Yuichi Fujioka ,  Yoshihiko Tsuchiyama ,  Akinori Yasutake ,  Matsuhei Noda ,  Norihisa Kobayashi ,  Ryoichi Nishida ,  Hitoshi Nishino ,  Katsuhide Okimi ,  Akihiro Hachiya

IPC分类号： B82B3/00 ,  B01J8/18 ,  C01B31/02 ,  D01F9/127 ,  C30B25/04 ,  C30B25/12 ,  C30B25/14

CPC分类号： B82Y30/00 ,  B01J8/18 ,  B01J2208/00407 ,  B01J2208/00415 ,  B01J2219/00268 ,  B82Y40/00 ,  C01B32/162 ,  C01B2202/36 ,  D01F9/127 ,  Y10S977/842

摘要： The invention has as an object proving a carbon nanomaterial fabrication method that can continuously mass-produce a high purity carbon a nanomaterial. The tube-shaped or fiber-shaped carbon nanomaterial having carbon as the main constituent is fabricated with a compound that includes carbon (raw material) and an additive that includes a metal by using a fluidized bed reactor.

摘要翻译： 本发明的目的是提供能够连续大规模生产高纯度碳纳米材料的碳纳米材料制造方法。 以碳为主要成分的管状或纤维状碳纳米材料通过使用流化床反应器的方式制造，所述化合物包括碳（原料）和包含金属的添加剂。

公开(公告)号：US20060104887A1

公开(公告)日：2006-05-18

申请号：US10540974

申请日：2003-11-27

申请人： Yuichi Fujioka ,  Toshihiko Setoguchi ,  Kazuya Suenaga ,  Susumu Miki

发明人： Yuichi Fujioka ,  Toshihiko Setoguchi ,  Kazuya Suenaga ,  Susumu Miki

IPC分类号： D01F9/12

CPC分类号： B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  D01F9/127 ,  D01F9/133

摘要： The present invention is provided with a reaction apparatus (12) that supplies carbon raw material (11) and fine particles (50) to cause carbon nanofibers to grow on surfaces of the fine particles (50), a heating apparatus (20) that heats the reaction apparatus 12, a recovery line (23) that recovers fine particles on which the carbon nanofibers have grown from the reaction apparatus, and a carbon nanofiber separating apparatus (24) that separates carbon nanofibers (52) from the recovered fine particles on which carbon nanofibers have been grown.

摘要翻译： 本发明提供一种提供碳原料（11）和微粒（50）以使碳纳米纤维在细颗粒（50）的表面上生长的反应装置（12），加热装置（20） 反应装置12，从反应装置回收碳纳米纤维生长的细小颗粒的回收管线（23）和碳纳米纤维分离装置（24），其将碳纳米纤维（52）与回收的微粒分离， 已经生长了碳纳米纤维。

公开(公告)号：US08318124B2

公开(公告)日：2012-11-27

申请号：US10540974

申请日：2003-11-27

申请人： Yuichi Fujioka ,  Toshihiko Setoguchi ,  Kazuya Suenaga ,  Susumu Miki

发明人： Yuichi Fujioka ,  Toshihiko Setoguchi ,  Kazuya Suenaga ,  Susumu Miki

IPC分类号： D01F9/127 ,  D01F9/12 ,  D01F9/133

CPC分类号： B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  D01F9/127 ,  D01F9/133

摘要： The present invention is provided with a reaction apparatus (12) that supplies carbon raw material (11) and fine particles (50) to cause carbon nanofibers to grow on surfaces of the fine particles (50), a heating apparatus (20) that heats the reaction apparatus 12, a recovery line (23) that recovers fine particles on which the carbon nanofibers have grown from the reaction apparatus, and a carbon nanofiber separating apparatus (24) that separates carbon nanofibers (52) from the recovered fine particles on which carbon nanofibers have been grown.

摘要翻译： 本发明提供一种提供碳原料（11）和微粒（50）以使碳纳米纤维在细颗粒（50）的表面上生长的反应装置（12），加热装置（20） 反应装置12，从反应装置回收碳纳米纤维生长的细小颗粒的回收管线（23）和碳纳米纤维分离装置（24），其将碳纳米纤维（52）与回收的微粒分离， 已经生长了碳纳米纤维。

公开(公告)号：US06228336B1

公开(公告)日：2001-05-08

申请号：US09373579

申请日：1999-08-13

申请人： Yasuo Katsuki ,  Takashi Ohnishi ,  Shozo Kaneko ,  Akira Hashimoto ,  Yuichi Fujioka ,  Kikuo Tokunaga ,  Toshihiko Setoguchi

发明人： Yasuo Katsuki ,  Takashi Ohnishi ,  Shozo Kaneko ,  Akira Hashimoto ,  Yuichi Fujioka ,  Kikuo Tokunaga ,  Toshihiko Setoguchi

IPC分类号： B01J800

CPC分类号： B01D50/002 ,  B01D53/508

摘要： A dust collecting apparatus and method for dedusting a Ca-containing gas using a ceramics filter is provided, in which a filter differential pressure elevation rate is suppressed. A desulferizing agent 103 and a mineral 106 containing MgO are supplied via a hopper 13, 15 a valve 14 and a feeder 16 into a pressurized fluidized-bed combustion furnace 1 together with coal 101 and air 102. A combustion gas 201 is dedusted by a cyclone 2 to become a combustion gas 301, the combustion gas 301 enters a filter container 3a, 3b having a ceramics filter 31a, 31b and is further dedusted. A combustion gas 401 which is dedusted is supplied into a gas turbine 4 to generate power, and combustion gas 501 heats a waste heat recovery boiler 5 which in turn drives a steam turbine 7. The mineral 106 containing MgO is added in the combustion gas 301 which flows in the ceramics filter 31a, 31b. Thereby MgO is added to the combustion gas so that the filter differential pressure elevation rate can be suppressed. The more MgO that is supplied, the greater the effect becomes, and an operation stop due to the differential pressure elevation is eliminated.

摘要翻译： 提供一种使用陶瓷过滤器除尘含Ca气体的集尘装置和方法，其中抑制了过滤器差压升高速率。 脱硫剂103和含有MgO的矿物106通过料斗13,15，阀14和进料器16与煤101和空气102一起供应到加压流化床燃烧炉1中。燃烧气体201通过 旋风分离器2成为燃烧气体301，燃烧气体301进入具有陶瓷过滤器31a，31b的过滤容器3a，3b，并进一步除尘。 将除尘的燃烧气体401供给燃气轮机4发电，燃烧气体501加热余热回收锅炉5，废热回收锅炉5又驱动蒸汽轮机7.含有MgO的矿物106加入燃烧气体301 其在陶瓷过滤器31a，31b中流动。 由此，将MgO添加到燃烧气体中，从而可以抑制过滤器差压提升率。 供给的MgO越多，效果越大，并且消除由于差压升高引起的操作停止。

公开(公告)号：US06475445B1

公开(公告)日：2002-11-05

申请号：US09394678

申请日：1999-09-13

申请人： Yoshihiko Tsuchiyama ,  Yuichi Fujioka ,  Toshihiko Setoguchi ,  Katsuhiko Shinoda ,  Kenji Tagashira ,  Shigeyasu Ishigami ,  Yoshinori Kobayashi

发明人： Yoshihiko Tsuchiyama ,  Yuichi Fujioka ,  Toshihiko Setoguchi ,  Katsuhiko Shinoda ,  Kenji Tagashira ,  Shigeyasu Ishigami ,  Yoshinori Kobayashi

IPC分类号： B01J818

CPC分类号： B01J8/1809 ,  B01D53/73 ,  B01J8/1836 ,  B01J8/34 ,  B01J8/386 ,  B01J2208/00008 ,  B01J2208/0084 ,  C01F11/46 ,  Y10S423/16

摘要： CaS oxidation has CaS particles oxidized into CaSO4 completely as far as to the interior of the particle. The interior of an oxidation apparatus 1 is partially partitioned by a partition 22 to thereby form a first fluidized bed 20 on the inner side, a second fluidized bed 21 on the outer side and a space portion 23 thereabove. A heat exchanger 27 having a baffle plate is disposed on the inner side of the partition 22 and an in-bed heat exchanger 33 is disposed on the outer side of same. A desulfurizing product-containing fine powder 204 and coarse powder 205 and a mixture gas 206 of nitrogen, oxygen and steam are supplied into the second fluidized bed 21. Also, coal 200 and coal char 201 are supplied into the first fluidized bed 20 from below. Of the particles 304 oxidized in the second fluidized bed 21 and supplied into the first fluidized bed 20 from below with the flow of a mixture gas 208, the fine powder entrains into the space portion 23 as entrained particles 300 and a major part thereof falls down into the second fluidized bed 21 as particles 207. The completely oxidized particles are discharged as discharged ash 303 and entrained ash 302.

摘要翻译： CaS氧化将CaS颗粒完全氧化成CaSO 4直至颗粒内部。 氧化装置1的内部被隔板22部分地隔开，从而在内侧形成第一流化床20，在外侧形成第二流化床21，在其上形成空间部23。 具有挡板的热交换器27设置在隔板22的内侧，并且在其外侧设置有床内热交换器33。 将含脱硫产物的细粉末204和粗粉末205以及氮气，氧气和蒸汽的混合气体206供给到第二流化床21中。另外，将煤200和煤炭201从下方供给到第一流化床20 。 在第二流化床21中被氧化并从下方供入混合气体208的第一流化床20的颗粒304中，细粉末作为夹带颗粒300进入空间部分23，并且其主要部分下降 作为颗粒207进入第二流化床21.完全氧化的颗粒作为排出的灰分303和夹带的灰分302排出。

公开(公告)号：US06245314B1

公开(公告)日：2001-06-12

申请号：US09140657

申请日：1998-08-26

申请人： Yoshihiko Tsuchiyama ,  Yuichi Fujioka ,  Toshihiko Setoguchi ,  Katsuhiko Shinoda ,  Kenji Tagashira ,  Shigeyasu Ishigami ,  Yoshinori Kobayashi

发明人： Yoshihiko Tsuchiyama ,  Yuichi Fujioka ,  Toshihiko Setoguchi ,  Katsuhiko Shinoda ,  Kenji Tagashira ,  Shigeyasu Ishigami ,  Yoshinori Kobayashi

IPC分类号： C01F1146

CPC分类号： B01J8/1809 ,  B01D53/73 ,  B01J8/1836 ,  B01J8/34 ,  B01J8/386 ,  B01J2208/00008 ,  B01J2208/0084 ,  C01F11/46 ,  Y10S423/16

摘要： CaS oxidation has CaS particles oxidized into CaSO4 completely as far as to the interior of the particle. The interior of an oxidation apparatus 1 is partially partitioned by a partition 22 to thereby form a first fluidized bed 20 on the inner side, a second fluidized bed 21 on the outer side and a space portion 23 thereabove. A heat exchanger 27 having a baffle plate is disposed on the inner side of the partition 22 and an in-bed heat exchanger 33 is disposed on the outer side of same. A desulfurizing product-containing fine powder 204 and coarse powder 205 and a mixture gas 206 of nitrogen, oxygen and steam are supplied into the second fluidized bed 21. Also, coal 200 and coal char 201 are supplied into the first fluidized bed 20 from below. Of the particles 304 oxidized in the second fluidized bed 21 and supplied into the first fluidized bed 20 from below with the flow of a mixture gas 208, the fine powder entrains into the space portion 23 as entrained particles 300 and a major part thereof falls down into the second fluidized bed 21 as particles 207. The completely oxidized particles are discharged as discharged ash 303 and entrained ash 302.

摘要翻译： CaS氧化将CaS颗粒完全氧化成CaSO 4直至颗粒内部。 氧化装置1的内部被隔板22部分地隔开，从而在内侧形成第一流化床20，在外侧形成第二流化床21，在其上形成空间部23。 具有挡板的热交换器27设置在隔板22的内侧，并且在其外侧设置有床内热交换器33。 将含脱硫产物的细粉末204和粗粉末205以及氮气，氧气和蒸汽的混合气体206供给到第二流化床21中。另外，将煤200和煤炭201从下方供给到第一流化床20 。 在第二流化床21中被氧化并从下方供入混合气体208的第一流化床20的颗粒304中，细粉末作为夹带颗粒300进入空间部分23，并且其主要部分下降 作为颗粒207进入第二流化床21.完全氧化的颗粒作为排出的灰分303和夹带的灰分302排出。

公开(公告)号：US5765365A

公开(公告)日：1998-06-16

申请号：US594407

申请日：1996-01-31

申请人： Yuichi Fujioka ,  Kimishiro Tokuda ,  Toshimitsu Ichinose ,  Yoshihiko Tsuchiyama ,  Fumiya Nakashima ,  Shigeyasu Ishigami ,  Satoshi Uchida

发明人： Yuichi Fujioka ,  Kimishiro Tokuda ,  Toshimitsu Ichinose ,  Yoshihiko Tsuchiyama ,  Fumiya Nakashima ,  Shigeyasu Ishigami ,  Satoshi Uchida

IPC分类号： F01K23/06 ,  F02C3/28

CPC分类号： F01K23/067 ,  F01K23/068 ,  Y02E20/18 ,  Y02E20/344

摘要： In a coal gasification power generator, coal gas 500 obtained by gasifying a coal 100 by a gasifying furnace is introduced into a desulfurization furnace in which the coal gas 500 is desulfurized by limestone 400. A coal gas 501 after desulfurization is burned by a combuster 5 after it has passed through a dust removing unit 3 so that high temperature combustion gas 800 is supplied to a gas turbine. The gas turbine 7 drives a power generating unit. Exhaust gas 801 from the gas turbine is supplied to an exhaust gas boiler 8. Char 60a produced in the gasifying furnace and limestone 60b containing CaS emitted from the desulfurization furnace are burned in an oxidation furnace, and by using the resultant combustion gas, water vapor introduced from the exhaust gas boiler 8 is heated by a heat exchanger, and thereafter it is supplied to the gasifying furnace as a gas. With the above construction, chemical energy possessed by the coal is effectively converted into electric energy, and also the rate of desulfurization of coal gasifying gas is improved thereby reducing emitted sulfur oxide.

摘要翻译： 在煤气化发电机中，将通过气化炉气化煤100获得的煤气500引入到通过石灰石400将煤气500脱硫的脱硫炉中。通过燃烧器5将脱硫后的煤气501燃烧 在通过除尘单元3之后，将高温燃烧气体800供给到燃气轮机。 燃气轮机7驱动发电单元。 来自燃气轮机的废气801被供给到废气锅炉8.在气化炉中生成的Char 60a和从脱硫炉排出的含有CaS的石灰石60b在氧化炉中燃烧，通过使用所得到的燃烧气体， 从废气锅炉8引入的热交换器被加热，之后作为气体供给到气化炉。 通过上述建设，煤炭所具有的化学能有效转化为电能，提高了煤气化气的脱硫率，减少了排放的硫氧化物。