Cationic dyes
    1.
    发明授权
    Cationic dyes 有权
    阳离子染料

    公开(公告)号:US07931696B2

    公开(公告)日:2011-04-26

    申请号:US12520887

    申请日:2008-01-22

    IPC分类号: A61Q5/10 C07D333/00

    摘要: Disclosed are dyes of formula wherein D is the radical of anthraquinone, acridine, azo, azomethine, hydrazomethine, benzodifuranone, coumarine, diketopyrrolopyrrol, dioxaxine, diphenylmethane, formazane, indigoid, indophenol, naphtalimide, naphthaquinone, nitroaryl, merocyanine, methine, oxazine, perinone, perylene, pyrenequinone, phtalocyanine, phenazine, quinoneimine, quinacridone, quinophtalone, stilbene, styryl, triphenylmethane, xanthene, thiazine dye and thioxanthene dye; and Q is defined herein.

    摘要翻译: 公开了下式的染料,其中D是蒽醌,吖啶,偶氮,偶氮甲碱,肼甲基,苯并二呋喃酮,香豆素,二酮吡咯并吡咯,二氧杂环己烷,二苯基甲烷,甲ane烷,靛类,靛酚,萘二甲酰亚胺,萘醌,硝基芳基,部花青,次甲基,恶嗪, ,苝,芘醌,酞菁,吩嗪,醌亚胺,喹吖啶酮,喹诺酮,芪,苯乙烯基,三苯甲烷,呫吨,噻嗪染料和噻吨染料; 并且Q在本文中定义。

    Tricationic dyes
    2.
    发明申请
    Tricationic dyes 有权
    化学染料

    公开(公告)号:US20100011518A1

    公开(公告)日:2010-01-21

    申请号:US12308042

    申请日:2007-06-04

    摘要: Disclosed are compounds of formula D is an aromatic or a cationic heteroaromatic group, which is optionally substituted by C1-C14alkyl, C1-C14alkoxy, hydroxy-C1-C14alkyl, C3-C8cycloalkyl, —CN, NO2, —NR3R4, halogen, C6-C10aryl, which is optionally substituted or C1-C14alkyl, or by one or more groups Z; E1 and E2 independently from each other are ═CH; or ═N—; K is an aromatic or heteroaromatic group which is optionally substituted by C1-C14alkyl, C1-C14alkoxy, C3-C8cycloalkyl, C6-C10aryl, halogen, hydroxy, NO2, —NR3R4, —N(R3)(CO)R4, —SO2NR1R2, —SONR1R2 or by one or more Z; or a radical of formula —NR1R2; R1 and R2 independently from each other are hydrogen; C1-C14alkyl; cyclo-C1-C14alkyl; C6-C10aryl; an aromatic or heteroaromatic group which is optionally substituted by C1-C14alkyl, C1-C14alkoxy, C3-C8cycloalkyl, C6-C10aryl, halogen, hydroxy, —NR5R6, —N(R5)—(CO)R5 or by Z; Z is a group of the formula (1a) *—X1—Y1—W1, wherein X1 is the direct bond; —NR7—; —O—; —NR7(C═O)—; —(CO)NR7—; —O(C═O)—; —(CO)O—; or —(C═O)—; Y1 is the direct bond; C1-C12alkylene, which is optionally interrupted by —O—, —NR8, —S—, —(C═O)—, —O(C═O)—, (C═O)O—, —NR7(C═O)—, —(C═O)NR7—, and which may substituted by C1-C14alkyl, hydroxy-C1-C14alkyl, hydroxy, —NR9R10 or halogen; or C6-C10arylene, which may substituted by C1-C14alkyl, hydroxy-C1-C14alkyl, hydroxy, amino or halogen; W1 is a cationic group; and R3, R4, R5, R6, R7, R8, R9 and R10 independently from each other are hydrogen; C1-C14alkyl; or Z; and An1−, An2− and An3− independently from each other are an anion. The compounds are useful for dyeing of organic materials, such as keratin-containing fibers, wool, leather, silk, cellulose or polyamides, especially keratin-containing fibers, cotton or nylon, more preferably human hair.

    摘要翻译: 公开了式D的化合物是芳族或阳离子杂芳基,其任选被C 1 -C 14烷基,C 1 -C 14烷氧基,羟基-C 1 -C 14烷基,C 3 -C 8环烷基,-CN,NO 2,-NR 3 R 4,卤素, C10芳基,其为任选取代的或C 1 -C 14烷基,或一个或多个基团Z; E1和E2彼此独立地是-CH; 或-N-; K是任选被C 1 -C 14烷基,C 1 -C 14烷氧基,C 3 -C 8环烷基,C 6 -C 10芳基,卤素,羟基,NO 2,-NR 3 R 4,-N(R 3)(CO)R 4,-SO 2 NR 1 R 2, -SONR1R2或一个或多个Z; 或式-NR1R2的基团; R1和R2彼此独立地是氢; C 1 -C 14烷基; 环C 1 -C 14烷基; C6-C10芳基; 任选被C 1 -C 14烷基,C 1 -C 14烷氧基,C 3 -C 8环烷基,C 6 -C 10芳基,卤素,羟基,-NR 5 R 6,-N(R 5) - (CO)R 5或Z取代的芳族或杂芳族基团; Z是式(1a)* -X1-Y1-W1的基团,其中X1是直接键; -NR7-; -O-; -NR7(C-O) - ; - (CO)NR7-; -O(C-O) - ; - (CO)O-; 或 - (C-O) - ; Y1是直接键; (CO) - , - (CO) - ,(CO)O - , - NR7(CO) - , - (CO) NR7-,其可以被C 1 -C 14烷基,羟基-C 1 -C 14烷基,羟基,-NR 9 R 10或卤素取代; 或可被C 1 -C 14烷基取代的C 6 -C 10亚芳基,羟基-C 1 -C 14烷基,羟基,氨基或卤素; W1是阳离子基团; 且R 3,R 4,R 5,R 6,R 7,R 8,R 9和R 10彼此独立地为氢; C 1 -C 14烷基; 或Z; 而An1-,An2-和An3-彼此独立地是阴离子。 这些化合物可用于染色有机材料,例如含角蛋白的纤维,羊毛,皮革,丝绸,纤维素或聚酰胺,特别是含角蛋白的纤维,棉或尼龙,更优选人发。

    THIOL DYES
    3.
    发明申请

    公开(公告)号:US20090113639A1

    公开(公告)日:2009-05-07

    申请号:US11992926

    申请日:2006-09-27

    摘要: Disclosed are thiol dyes of formula (1), wherein R1 is hydrogen; C1-C12alkyl; or phenyl-C1-C4alkyl; X is C1-C12alkylene; C2-C12alkenylene; C5-C10cycloalkylene; C5-C10arylene; or C5-C10arylene-C1-C10alkylene; Y is the residue of an organic dye which corresponds to the formula (1a), wherein R2 is hydrogen; or C1-C5alkyl; R3 is a radical of formula (1a1): (1a2); or (1a3); or R2 and R3 together with the linking carbon atom 1C form a 6 to 10 membered carbocyclic ring which may optionally be a condensated aromatic system and may contain one or more than one hetero atom; and R4, R5 and R6 independently form each other are hydrogen, or C1-C5alkyl; Z is H; or a thio ester group of formula (1b), wherein A is O; S; or N—R9; B is —OR7; —NR7R8, or —SR7; and A is O; S; or N—R9; B is —OR7; —NR7R8, or —SR7; and R7, R8 and R9, independently from each other are hydrogen; C1-C12alkyl C6-C12aryl; or C6-C12aryl-C1-C12alkyl. The compounds are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.

    摘要翻译: 公开了式(1)的硫醇染料,其中R 1是氢; C 1 -C 12烷基; 或苯基-C 1 -C 4烷基; X是C 1 -C 12亚烷基; C 2 -C 12亚烯基; C5-C10环亚烷基; C5-C10亚芳基 或C 5 -C 10亚芳基-C 1 -C 10亚烷基; Y是对应于式(1a)的有机染料的残基,其中R 2是氢; 或C 1 -C 5烷基; R3是式(1a1)的基团:(1a2); 或(1a3); 或R2和R3与连接碳原子1C一起形成6至10元碳环,其可以任选地是缩合的芳族体系,并且可以含有一个或多于一个的杂原子; 和R 4,R 5和R 6彼此独立地形成氢或C 1 -C 5烷基; Z是H; 或式(1b)的硫酯基,其中A为O; S; 或N-R9; B为-OR7; -NR7R8或-SR7; A是O; S 或N-R9; B为-OR7; -NR7R8或-SR7; 和R 7,R 8和R 9彼此独立地是氢; C 1 -C 12烷基C 6 -C 12芳基; 或C 6 -C 12芳基-C 1 -C 12烷基。 该化合物可用于染色有机材料,例如角蛋白纤维,优选人发。

    Disulfide dyes, composition comprising them and method of dyeing hair
    4.
    发明授权
    Disulfide dyes, composition comprising them and method of dyeing hair 有权
    二硫化染料,包含它们的组合物和染发方法

    公开(公告)号:US07476260B2

    公开(公告)日:2009-01-13

    申请号:US11547571

    申请日:2005-03-29

    IPC分类号: A61Q5/10 C09B31/02

    摘要: Formula (I) wherein R1 and R2 each independently from each other are a residue of an organic dye: Y1 and Y2 each independently from each other are unsubstituted or substituted, straightchain or branched, interrupted or uninterrupted —C1-C10alkylene-; —C5-C10cycloalkylene-; C5-C10arylene; or —C5-C10arylene-(C1-C10alkylene)-; Z1 and Z2 independently from each other are Formula (II) are each independently from each other hydrogen; or unsubstituted or substituted, straight-chain or branched, mono-cyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); r, q and n independently from each other are 0 or 1, if n is 0, Z3 is hydrogen; and if n is 1, Z3 is —S—: with the proviso that the method does not comprise treating the fiber with an enzyme of the type of a protein disulfidisomerase (EC 5.3.4.1). Further, the present invention relates to novel disulfid compounds, compositions thereof, especially comprising other dyes, and to processes for their preparation.

    摘要翻译: 式(I)其中R 1和R 2各自独立地是有机染料的残基:Y 1和Y 2各自独立地是未取代或取代的,直链或支链的,间断的或不间断的-C 1 -C 10亚烷基 - ; -C 5 -C 10环亚烷基 - C5-C10亚芳基 或-C 5 -C 10亚芳基 - (C 1 -C 10亚烷基) - ; Z 1和Z 2彼此独立地是式(II)各自独立地为氢; 或未取代或取代的直链或支链的单环或多环,间断或不间断的C 1 -C 14烷基; C2-C14烯基; C6-C10芳基; C 6 -C 10芳基-C 1 -C 10烷基; 或C 5 -C 10烷基(C 5 -C 10芳基); r,q和n彼此独立地为0或1,如果n为0,则Z 3为氢; 并且如果n为1,则Z 3为-S-,条件是该方法不包括用蛋白质二硫代异构酶类型的EC处理纤维(EC 5.3.4.1)。 此外,本发明涉及新的二硫化物,其组合物,特别是其它染料,以及其制备方法。

    Disulfide Dyes, Composition Comprising them and Method of Dyeing Hair
    5.
    发明申请
    Disulfide Dyes, Composition Comprising them and Method of Dyeing Hair 有权
    二硫化物染料,包含它们的组合物和染发剂的方法

    公开(公告)号:US20080295260A1

    公开(公告)日:2008-12-04

    申请号:US11547571

    申请日:2005-03-29

    摘要: Formula (I) wherein R1 and R2 each independently from each other are a residue of an organic dye: Y1 and Y2 each independently from each other are unsubstituted or substituted, straightchain or branched, interrupted or uninterrupted —C1-C10alkylene-; —C5-C10cycloalkylene-; C5-C10arylene; or —C5-C10arylene-(C1C10alkylene)-; Z1 and Z2 independently from each other are Formula (II) are each independently from each other hydrogen; or unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); r, q and n independently from each other are 0 or 1, if n is 0, Z3 is hydrogen; and if n is 1, Z3 is —S—; with the proviso that the method does not comprise treating the fiber with an enzyme of the type of a protein disulfidisomerase (EC 5.3.4.1). Further, the present invention relates to novel disulfide compounds, compositions thereof, especially comprising other dyes, and to processes for their preparation.

    摘要翻译: 式(I)其中R 1和R 2各自独立地是有机染料的残基:Y 1和Y 2各自独立地是未取代或取代的,直链或支链的,间断的或不间断的-C 1 -C 10亚烷基 - ; -C 5 -C 10环亚烷基 - C5-C10亚芳基 或-C 5 -C 10亚芳基 - (C 1 -C 10亚烷基) - ; Z 1和Z 2彼此独立地是式(II)各自独立地为氢; 或未取代或取代的直链或支链的单环或多环,间断或不间断的C 1 -C 14烷基; C2-C14烯基; C6-C10芳基; C 6 -C 10芳基-C 1 -C 10烷基; 或C 5 -C 10烷基(C 5 -C 10芳基); r,q和n彼此独立地为0或1,如果n为0,则Z 3为氢; 如果n为1,则Z 3为-S-; 条件是该方法不包括用蛋白质二硫代异构酶类型的EC(EC 5.3.4.1)处理纤维。 此外,本发明涉及新的二硫化物化合物,其组合物,特别是其它染料,以及其制备方法。

    Cationic direct dyes
    6.
    发明授权
    Cationic direct dyes 有权
    阳离子直接染料

    公开(公告)号:US07307155B2

    公开(公告)日:2007-12-11

    申请号:US10565137

    申请日:2004-07-14

    IPC分类号: C09B44/16 A61Q5/10

    CPC分类号: C09B44/16

    摘要: The present invention relates to novel the cationic dyes of formula (1) wherein R1 is an unsubstituted or substituted C1-C14 alkyl or an aryl radical; X− is an anion; R3 is an unsubstituted or substituted C1-C14 alkyl, aryl radical, C1-C6 alkoxy, cyanid, nitro or halide; n is 1 or 2; and if n is 1, then R2 is hydrogen, unsubstituted or substituted C1-C14 alkyl; or if n is 2, then R2 is an unsubstituted or substituted C1-C14 alkylen. Further, the present invention relates to compositions thereof, especially comprising other dyes, to processes for the preparation thereof and to the use thereof in the dyeing of organic material, such as keratin, wool, leather, silk, paper, cellulose or polyamides, and preferably human hair

    摘要翻译: 本发明涉及新型式(1)的阳离子染料,其中R 1是未取代或取代的C 1 -C 14烷基或 芳基; X 是阴离子; R 3是未取代或取代的C 1 -C 14烷基,芳基,C 1 -C 6烷基, 氰基,硝基或卤素; n为1或2; 并且如果n为1,则R 2为氢,未取代或取代的C 1 -C 14烷基; 或者如果n为2,则R 2为未取代或取代的C 1 -C 14亚烷基。 此外,本发明涉及其组合物,特别是其它染料,其制备方法及其在染色有机材料如角蛋白,羊毛,皮革,丝,纸,纤维素或聚酰胺中的用途,以及 优选人发

    Pyrido thiazinium dyes
    7.
    发明授权
    Pyrido thiazinium dyes 有权
    吡啶并噻嗪染料

    公开(公告)号:US07785375B2

    公开(公告)日:2010-08-31

    申请号:US11922660

    申请日:2006-06-21

    IPC分类号: A61Q5/10 C07D279/00

    摘要: Disclosed is a method of dyeing keratin-containing fibers comprising treating the fiber with at least one compound of formula (1), wherein R1, R2, R3, R4 independently from each other are hydrogen; hydroxy; —S—H; —S—C1-C12alkyl; halogen; C1-C12alkyl or C1-C12alkoxy, which may be substituted by one or more C1-C5alkyl, C1-C5-alkoxy, hydroxy, —(CO)—H or —(CO)—C1-C5alkyl; —NR5R6; —NO2; —(CO)H or (CO)—C1-C5alkyl; C6-C12aryl, C6-C12aryl-C1-C4alkyl or C6-C12aryl-C1-C4alkoxy, wherein the aryl moiety may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, —(CO)—H or —(CO)—C1-C5alkyl; R5 and R6 independently from each other are hydrogen; hydroxy; C1-C12alkyl; hydroxy-C1-C12alkyl; —(CO)—H; —(CO)—C1-C5alkyl; phenyl or phenyl-C1-C5alkyl, wherein the phenyl moiety may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, halogen, —NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, —NO2, carboxy or hydroxy; and An is an anion. Furthermore, the present invention relates to novel heterocyclic compounds, compositions thereof, especially comprising other dyes, and to processes for their preparation and application to hair dying.

    摘要翻译: 公开了一种染色含角蛋白纤维的方法,包括用至少一种式(1)化合物处理纤维,其中R 1,R 2,R 3,R 4彼此独立地为氢; 羟基; -S-H; -S-C 1 -C 12烷基; 卤素; C 1 -C 12烷基或C 1 -C 12烷氧基,其可以被一个或多个C 1 -C 5烷基,C 1 -C 5 - 烷氧基,羟基, - (CO)-H或 - (CO)-C 1 -C 5烷基取代; -NR5R6; -NO2; - (CO)H或(CO)-C 1 -C 5烷基; C 1 -C 12芳基,C 6 -C 12芳基-C 1 -C 4烷基或C 6 -C 12芳基-C 1 -C 4烷氧基,其中芳基部分可被一个或多个C 1 -C 5烷基,C 1 -C 5烷氧基, - (CO)-H或 - (CO) -C 1 -C 5烷基; R5和R6彼此独立地是氢; 羟基; C 1 -C 12烷基; 羟基-C 1 -C 12烷基; - (CO)-H; - (CO)-C 1 -C 5烷基; 苯基或苯基-C 1 -C 5烷基,其中苯基部分可被一个或多个C 1 -C 5烷基,C 1 -C 5烷氧基,卤素,-NH 2,单C 1 -C 5烷基氨基,二-C 1 -C 5烷基氨基,-NO 2,羧基或羟基 ; 而An是阴离子。 此外,本发明涉及新颖的杂环化合物,其组合物,特别是其它染料,以及其制备和应用于染发的方法。

    THIOL DERIVATIVE DYES
    8.
    发明申请
    THIOL DERIVATIVE DYES 有权
    THIOL衍生染发剂

    公开(公告)号:US20100000029A1

    公开(公告)日:2010-01-07

    申请号:US12310118

    申请日:2007-08-08

    IPC分类号: A61K8/49 C09B29/036

    摘要: Disclosed are thiol dyes of formula (1) wherein L1 is hydrogen; C1-C12alkyl; or phenyl-C1-C4alkyl; X is C1-C12alkylene, C2-C12alkenylene, C5-C10cycloalkylene, C5-C10arylene, or C5-C10arylene-C1-C10alkylene, which may by interrupted by —O—, —NH—, —S—, —CO—, o-SO2—; Y is the residue of an organic dye Z is a group of formula (1b) or —C≡N; wherein A is O; S; or N-L2; B is L3; —OL3; —NL3L4; or —SL3; and L2, L3 and L4, independently from other are hydrogen; C1-C12alkyl; C5-C12aryl-C1-C12alkyl. The compounds are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.

    摘要翻译: 公开了式(1)的硫醇染料,其中L 1是氢; C 1 -C 12烷基; 或苯基-C 1 -C 4烷基; X是C 1 -C 12亚烷基,C 2 -C 12亚烯基,C 5 -C 10亚环烷基,C 5 -C 10亚芳基或C 5 -C 10亚芳基-C 1 -C 10亚烷基,其可以被-O - , - NH - , - S-, -​​ CO- SO2-; Y是有机染料的残基Z是式(1b)或-C≡N的基团; 其中A为O; S; 或N-L2; B是L3; -OL3; -NL3L4; 或-SL3; 和L2,L3和L4独立地是氢; C 1 -C 12烷基; C5-C12芳基-C1-C12烷基。 该化合物可用于染色有机材料,例如角蛋白纤维,优选人发。

    Styryl sulfide dyes
    9.
    发明申请

    公开(公告)号:US20100000028A1

    公开(公告)日:2010-01-07

    申请号:US11922069

    申请日:2006-06-07

    IPC分类号: A61K8/49 C07D401/12 A61Q5/10

    摘要: Disclosed are styryl sulfide dyes of formula (1), wherein R1, R′1, R2, R′2, R3 and R′3, independently from each other are hydrogen; C1-C20alkyl or C1-C20alkoxy, which may be substituted by one or more C1-C5alkoxy, halogen, —NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, —NO2 or hydroxy; C3-C6cycloalkyl; —C(O)H; —C(O)—C1-C5alkyl; halogen; NO2; OH; phenyl, which may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, halogen, —NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, —NO2 or hydroxy; or a radical of formula —NR4R5, wherein R4 and R5 independently from each other are hydrogen; C1-C12alkyl, which may be substituted by one or more C1-C5alkyl, C1-C5-alkoxy, hydroxy or —(CO)—H; —(CO)—C1-C5alkyl; phenyl or phenyl-C1-C4alkyl, wherein the phenyl moiety may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, halogen, —N2, mono-C1-C5alkylamino, di-C1-C5alkylamino, —NO2, carboxy or hydroxy; W1, W′1, W2, W′2, W3, W′3, W4 or W′4, independently from each other are —CH— or —N+—; wherein only one of W1/W′1, W2/W′2, W3/W′3, W4/W4′ is —N+; and the bivalent radical -Q-Z-Y—S—S—Y′-Z′-Q′- is bonded to W1 or W2 and W′1 or W′2 respectively; Y1 and Y2 independently from each other are C1-C10alkylene; C5-C10cycloalkylene; C5-C12arylene; or C5-C12arylene-(C1-C10alkylene); Q and Q′ independently from each other are the direct bond; or —C(O)—; —C(O)O—; —OCO—; —N(R6)—; formula (AA); —C(O)N(R6)—; —(R6)NC(O)—; —O—; —S—; —S(O)—; or —S(O)2—; and R6 and R7 independently from each other are hydrogen; C1-C14alkyl; C2-C14alkenyl; C6-C12aryl; C6-C12aryl-C1-C10alkyl; or C1-C10alkyl(C5-C12aryl). Further, the present invention relates to novel styryl sulfide compounds, compositions thereof, especially comprising other dyes, and to processes for their preparation.