公开(公告)号：US08796406B2

公开(公告)日：2014-08-05

申请号：US13208864

申请日：2011-08-12

Applicant: Neeraj Gupta ,  Anantharaman Dhanabalan ,  Nagendiran Shanmugam ,  Vivek Khare

Inventor： Neeraj Gupta ,  Anantharaman Dhanabalan ,  Nagendiran Shanmugam ,  Vivek Khare

IPC: C08F130/08

CPC classification number: C08F230/08 ,  C08F220/18 ,  C08F290/148 ,  C08G77/20 ,  C08G77/46 ,  H01M8/1037 ,  H01M10/0565 ,  C08F220/20

Abstract: A copolymer suitable for use in forming a solid polymer electrolyte film comprising a first monomer represented by Formula (1): wherein n is 2 to 1,000; m is 2 to 1,000; x and y are individually 1 to 100; p is 0 to 10; and q is 1 to 10, R1 is an alkyl group having 1 to 10 carbon atoms, and A is an alkyl acryloyl group an acryloyl group, alkyl acryloyl group, methacryloyl group, alkyl methacryloyl group, a vinyl group, an allyl group, a styryl group, or a combination of two or more thereof; and a second monomer chosen from a hydroxyl-substituted alkyl acrylate, a hydroxyl-substituted alkyl methacrylate, or a combination of two or more thereof. The copolymer may be used to form a solid polymer electrolyte composition comprising (i) the copolymer, (ii) a plasticizer, and (iii) a salt. The solid polymer electrolyte may be used to form a solid polymer electrolyte film, which may be suitable for use in electrochemical devices.

Abstract translation: 一种适合用于形成固体聚合物电解质膜的共聚物，其包含由式（1）表示的第一单体：其中n为2至1,000; m为2〜1,000; x和y分别为1〜100; p为0〜10; q为1〜10，R1为碳原子数1〜10的烷基，A为烷基丙烯酰基，丙烯酰基，烷基丙烯酰基，甲基丙烯酰基，烷基甲基丙烯酰基，乙烯基，烯丙基， 苯乙烯基或其两种或更多种的组合; 和选自羟基取代的丙烯酸烷基酯，羟基取代的甲基丙烯酸烷基酯或其两种或更多种的组合的第二单体。 共聚物可用于形成固体聚合物电解质组合物，其包含（i）共聚物，（ii）增塑剂和（iii）盐。 固体聚合物电解质可用于形成固体聚合物电解质膜，其可适用于电化学装置。

公开(公告)号：US20130040207A1

公开(公告)日：2013-02-14

申请号：US13208864

申请日：2011-08-12

Applicant: Neeraj Gupta ,  Anantharaman Dhanabalan ,  Nagendiran Shanmugam ,  Vivek Khare

Inventor： Neeraj Gupta ,  Anantharaman Dhanabalan ,  Nagendiran Shanmugam ,  Vivek Khare

IPC: H01M10/056 ,  C08F230/08

CPC classification number: C08F230/08 ,  C08F220/18 ,  C08F290/148 ,  C08G77/20 ,  C08G77/46 ,  H01M8/1037 ,  H01M10/0565 ,  C08F220/20

Abstract: A copolymer suitable for use in forming a solid polymer electrolyte film comprising a first monomer represented by Formula (1): wherein n is 2 to 1,000; m is 2 to 1,000; x and y are individually 1 to 100; p is 0 to 10; and q is 1 to 10, R1 is an alkyl group having 1 to 10 carbon atoms, and A is an alkyl acryloyl group an acryloyl group, alkyl acryloyl group, methacryloyl group, alkyl methacryloyl group, a vinyl group, an allyl group, a styryl group, or a combination of two or more thereof; and a second monomer chosen from a hydroxyl-substituted alkyl acrylate, a hydroxyl-substituted alkyl methacrylate, or a combination of two or more thereof. The copolymer may be used to form a solid polymer electrolyte composition comprising (i) the copolymer, (ii) a plasticizer, and (iii) a salt. The solid polymer electrolyte may be used to form a solid polymer electrolyte film, which may be suitable for use in electrochemical devices.

Abstract translation: 一种适合用于形成固体聚合物电解质膜的共聚物，其包含由式（1）表示的第一单体：其中n为2至1,000; m为2〜1,000; x和y分别为1〜100; p为0〜10; q为1〜10，R1为碳原子数1〜10的烷基，A为烷基丙烯酰基，丙烯酰基，烷基丙烯酰基，甲基丙烯酰基，烷基甲基丙烯酰基，乙烯基，烯丙基， 苯乙烯基或其两种或更多种的组合; 和选自羟基取代的丙烯酸烷基酯，羟基取代的甲基丙烯酸烷基酯或其两种或更多种的组合的第二单体。 共聚物可用于形成固体聚合物电解质组合物，其包含（i）共聚物，（ii）增塑剂和（iii）盐。 固体聚合物电解质可用于形成固体聚合物电解质膜，其可适用于电化学装置。

公开(公告)号：US08829257B2

公开(公告)日：2014-09-09

申请号：US13547703

申请日：2012-07-12

Applicant: Richard W. Cruse ,  Vivek Khare ,  Jozef Kowalski ,  Wlodzimierz Stanczyk

Inventor： Richard W. Cruse ,  Vivek Khare ,  Jozef Kowalski ,  Wlodzimierz Stanczyk

IPC: C07C5/29 ,  C07C13/19 ,  C07C5/22

CPC classification number: C07C5/22 ,  C07B2200/07 ,  C07C5/29 ,  C07C2601/14 ,  C07C13/19

Abstract: Disclosed herein is a process for making 1,2,4-trivinylcyclohexane that is enriched in a particular geometric isomer. The process involves the thermal isomerization of 1,5,9-cyclododecatriene at temperature between 400° C. and 600° C. followed by an equilibration of the resultant intermediate in either the gas phase or liquid phase at temperature between 180° C. and 375° C. and at pressures ranging from 0.101 kPa to 1,013 kPa. Also disclosed are 1,2,4-trivinylcyclohexane compositions that are enriched in a particular geometric isomer.

Abstract translation: 本文公开了一种制备富含特定几何异构体的1,2,4-三乙烯基环己烷的方法。 该方法涉及在400℃和600℃之间的温度下1,5,9-环十二碳三烯的热异构化，然后在180℃和180℃之间的温度下在气相或液相中平衡所得中间体 375℃，压力范围为0.101kPa至1,013kPa。 还公开了富含特定几何异构体的1,2,4-三乙烯基环己烷组合物。

公开(公告)号：US20130018212A1

公开(公告)日：2013-01-17

申请号：US13547703

申请日：2012-07-12

Applicant: Richard W. Cruse ,  Vivek Khare ,  Jozef Kowalski ,  Wlodzimierz Stanczyk

Inventor： Richard W. Cruse ,  Vivek Khare ,  Jozef Kowalski ,  Wlodzimierz Stanczyk

IPC: C07C5/29 ,  C07C13/19

CPC classification number: C07C5/22 ,  C07B2200/07 ,  C07C5/29 ,  C07C2601/14 ,  C07C13/19

Abstract: Disclosed herein is a process for making 1,2,4-trivinylcyclohexane that is enriched in a particular geometric isomer. The process involves the thermal isomerization of 1,5,9-cyclododecatriene at temperature between 400° C. and 600° C. followed by an equilibration of the resultant intermediate in either the gas phase or liquid phase at temperature between 180° C. and 375° C. and at pressures ranging from 0.101 kPa to 1.013 kPa. Also disclosed are 1,2,4-trivinylcyclohexane compositions that are enriched in a particular geometric isomer.

Abstract translation: 本文公开了一种制备富含特定几何异构体的1,2,4-三乙烯基环己烷的方法。 该方法涉及在400℃和600℃之间的温度下1,5,9-环十二碳三烯的热异构化，然后在180℃和180℃之间的温度下在气相或液相中平衡所得中间体 375℃，压力范围为0.101kPa至1.013kPa。 还公开了富含特定几何异构体的1,2,4-三乙烯基环己烷组合物。