公开(公告)号：US4330573A

公开(公告)日：1982-05-18

申请号：US207618

申请日：1980-11-17

申请人： Leonid A. Kostandov ,  Nikolai S. Enikolopov ,  Fridrikh S. Dyachkovsky ,  Ljudmila A. Novokshonova ,  Jury A. Gavrilov ,  Olga I. Kudinova ,  Tatyana A. Maklakova ,  Leonid A. Akopian ,  Otar P. Mchedlov-Petrosian ,  Mikhail I. Boilko ,  Alexandr A. Staroselsky ,  Vladimir P. Tkachenko

发明人： Leonid A. Kostandov ,  Nikolai S. Enikolopov ,  Fridrikh S. Dyachkovsky ,  Ljudmila A. Novokshonova ,  Jury A. Gavrilov ,  Olga I. Kudinova ,  Tatyana A. Maklakova ,  Leonid A. Akopian ,  Otar P. Mchedlov-Petrosian ,  Mikhail I. Boilko ,  Alexandr A. Staroselsky ,  Vladimir P. Tkachenko

IPC分类号： C04B20/10 ,  C04B41/48 ,  B05D7/24

CPC分类号： C04B20/1033 ,  C04B41/4861

摘要： The composite material, which is a solid porous carrier, whose pores are filled with a polymer, a polyolefin having the molecular weight not less than 300,000, the degree of pore filling with said polymer being at least 4 percent of the total volume of the pores, in which the ratio of the carrier mass to the mass of the polymer is 50-99.5:50-0.5. The method of producing said composite material consists in precipitation, from the gas phase, of a complex organometallic catalyst consisting of a compound of a transition metal and of an organic compound of a metal in the 2nd or 3rd group of the Periodic Table, inside the pores of a solid porous carrier, and in polymerization of olefins from the gas phase on said catalyst, precipitated in the pores of the solid porous carrier, at a temperature of 50.degree.-165.degree. C. and a pressure of 1-60 atm. The composite material is characterized by high mechanical strength (compression strength reaching 100-200 kg/sq.cm) high frost resistance, and hydrophobic properties. The proposed method effectively controls the degree of filling the carrier pores with the polymer (from at least 4 percent of the total volume of the pores), and can be used to manufacture composite materials possessing a predetermined set of properties.

摘要翻译： 作为固体多孔载体的复合材料，其孔被聚合物填充，分子量不小于30万的聚烯烃，所述聚合物的孔填充度为孔的总体积的至少4％ ，其中载体质量与聚合物的质量比为50-99.5:50-0.5。 制备所述复合材料的方法是在气相中沉淀由元素周期表第二或第三组中的过渡金属和金属有机化合物组成的复合有机金属催化剂， 固体多孔载体的孔，以及在所述催化剂上的气相中的烯烃聚合，在固体多孔载体的孔中沉淀，温度为-50°-165℃，压力为1-60大气压。 复合材料的特点是机械强度高（抗压强度达到100-200 kg / sq.cm），抗冻性高，疏水性能好。 所提出的方法有效地控制用聚合物填充载体孔隙的程度（从孔的总体积的至少4％），并且可以用于制造具有预定特性的复合材料。

公开(公告)号：US4234659A

公开(公告)日：1980-11-18

申请号：US943188

申请日：1978-09-18

申请人： Leonid A. Kostandov ,  Nikolai S. Enikolopov ,  Fridrikh S. Dyachkovsky ,  Ljudmila A. Novokshonova ,  Jury A. Gavrilov ,  Olga I. Kudinova ,  Tatyana A. Maklakova ,  Leonid A. Akopian ,  Otar P. Mchedlov-Petrosian ,  Mikhail I. Boiko ,  Alexandr A. Staroselsky ,  Vladimir P. Tkachenko

发明人： Leonid A. Kostandov ,  Nikolai S. Enikolopov ,  Fridrikh S. Dyachkovsky ,  Ljudmila A. Novokshonova ,  Jury A. Gavrilov ,  Olga I. Kudinova ,  Tatyana A. Maklakova ,  Leonid A. Akopian ,  Otar P. Mchedlov-Petrosian ,  Mikhail I. Boiko ,  Alexandr A. Staroselsky ,  Vladimir P. Tkachenko

IPC分类号： C04B20/10 ,  C04B41/48 ,  B32B5/16 ,  B32B9/00

CPC分类号： C04B20/1033 ,  C04B41/4861 ,  C04B2111/76 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/2998

摘要： The composite material, which is a solid porous carrier, whose pores are filled with a polymer, a polyolefin having the molecular weight not less than 300,000, the degree of pore filling with said polymer being at least 4 percent of the total volume of the pores, in which the ratio of the carrier mass to the mass of the polymer is 50-99.5:50-0.5. The method of producing said composite material consists in precipitation, from the gas phase, of a complex organometallic catalyst consisting of a compound of a transition metal and of an organic compound of a metal in the 2nd or 3rd group of the Periodic Table, inside the pores of a solid porous carrier, and in polymerization of olefins from the gas phase on said catalyst, precipitated in the pores of the solid porous carrier, at a temperature of 50.degree.-165.degree. C. and a pressure of 1-60 atm. The composite material is characterized by high mechanical strength (compression strength reaching 100-200 kg/sq. cm) high frost resistance, and hydrophobic properties. The proposed method effectively controls the degree of filling the carrier pores with the polymer (from at least 4 percent of the total volume of the pores), and can be used to manufacture composite materials possessing a predetermined set of properties.

摘要翻译： 作为固体多孔载体的复合材料，其孔被聚合物填充，分子量不小于30万的聚烯烃，所述聚合物的孔填充度为孔的总体积的至少4％ ，其中载体质量与聚合物的质量比为50-99.5:50-0.5。 生产所述复合材料的方法是在气相中沉淀由元素周期表第二或第三组中的过渡金属和金属有机化合物组成的复合有机金属催化剂， 固体多孔载体的孔，以及在所述催化剂上的气相中的烯烃聚合，在固体多孔载体的孔中沉淀，温度为-50°-165℃，压力为1-60大气压。 复合材料的特点是机械强度高（抗压强度达到100-200 kg / sq。cm），抗冻性高，疏水性好。 所提出的方法有效地控制用聚合物填充载体孔隙的程度（从孔的总体积的至少4％），并且可以用于制造具有预定特性的复合材料。