公开(公告)号：US07407717B2

公开(公告)日：2008-08-05

申请号：US10545886

申请日：2004-01-13

申请人： Frank Tietz ,  Mohsine Zahid ,  Willem J. Quadakkers ,  Vladimir Shemet

发明人： Frank Tietz ,  Mohsine Zahid ,  Willem J. Quadakkers ,  Vladimir Shemet

IPC分类号： H01M2/00

CPC分类号： C23C8/02 ,  C23C10/18 ,  C23C10/30 ,  C23C26/00 ,  H01M8/0208 ,  H01M8/0217 ,  H01M8/0219 ,  H01M8/0228 ,  H01M2008/1293 ,  Y02P70/56 ,  Y10T428/12611 ,  Y10T428/12618 ,  Y10T428/12667

摘要： A method is disclosed for producing a protective coating on a chromium oxide-forming substrate, which comprises the steps of: (a) applying on the chromium-oxide-forming substrate having at least one alloying addition selected from the group consisting of manganese, magnesium, and vanadium, a coating consisting essentially of at least one spinel-forming element selected from the group consisting of cobalt, nickel, copper and vanadium, (b) forming a chromium oxide layer at the substrate/applied coating interface, and (c) at a temperature of 500° C. to 1000° C. causing the diffusion of the at least one alloying addition through the chromium oxide layer and forming a compound thereof with the at least one spinel-forming element diffusing from the applied coating and forming between the chromium oxide layer on the substrate and the applied coating, a uniform, compact, adherent chromium-free gas-tight spinel layer.

摘要翻译： 公开了一种在氧化铬形成基材上制备保护涂层的方法，其包括以下步骤：（a）在具有至少一种选自锰，镁的合金添加剂的氧化铬形成基材上施用 和钒，基本上由至少一种选自钴，镍，铜和钒的尖晶石形成元素组成的涂层，（b）在衬底/涂覆的界面处形成氧化铬层，以及（c） 在500℃至1000℃的温度下，引起至少一种合金添加物通过氧化铬层的扩散，并形成其与至少一种尖晶石形成元件的化合物，从施加的涂层扩散并形成在 基底上的氧化铬层和涂覆的涂层，均匀，致密，粘附的无铬密封尖晶石层。

公开(公告)号：US06723176B2

公开(公告)日：2004-04-20

申请号：US10122772

申请日：2002-04-12

申请人： Willem Quadakkers ,  Vladimir Shemet ,  Lorenz Singheiser

发明人： Willem Quadakkers ,  Vladimir Shemet ,  Lorenz Singheiser

IPC分类号： C23C1400

CPC分类号： C23C30/00 ,  C23C4/11 ,  C23C24/08 ,  C23C26/00 ,  Y02T50/67

摘要： In a method of producing on the surface of a component which consists of a titanium alloy or an intermetallic phase on the basis of titanium, a protective layer (according to the formula Ti5,0−xAgx+yAl3,0−yO2), a mixture of Ti powder and TiO2 powder, which has been sintered, is applied to the surfaces of the component or, if the titanium alloy includes 40-60 at % Al, a coating of silver is applied to the component and the component is then heat treated at 500 to 900° C. to form the protective layer on its surfaces.

摘要翻译： 在由钛合金或金属间相组成的部件的表面上制造保护层（根据式Ti5,0-xAgx + yAl3,0-yO2）的方法中，混合物 已经烧结的Ti粉末和TiO 2粉末被施加到部件的表面上，或者如果钛合金包括40-60at％的Al，则将银涂层施加到部件上，然后将该部件进行热处理 在500〜900℃下，在其表面形成保护层。

公开(公告)号：US20060099442A1

公开(公告)日：2006-05-11

申请号：US10545886

申请日：2004-01-13

申请人： Frank Tietz ,  Mohsine Zahid ,  Vladimir Shemet

发明人： Frank Tietz ,  Mohsine Zahid ,  Vladimir Shemet

IPC分类号： C03C27/04 ,  B32B15/00

CPC分类号： C23C8/02 ,  C23C10/18 ,  C23C10/30 ,  C23C26/00 ,  H01M8/0208 ,  H01M8/0217 ,  H01M8/0219 ,  H01M8/0228 ,  H01M2008/1293 ,  Y02P70/56 ,  Y10T428/12611 ,  Y10T428/12618 ,  Y10T428/12667

摘要： As a rule, chromium-oxide forming materials for high temperatures, in particular chromium-based alloys or chromium-rich alloys based on iron (ferritic steel), are used as interconnector materials that are subjected to high temperatures. At SOFC operating temperatures, said material group forms a chromium-based oxidic top coating, which has the advantage of preventing rapid oxidation damage, but also the disadvantage of continuing to react, forming Cr(VI) compounds. Said volatile compounds react regularly with the cathode material, producing the negative effect of impairing the oxygen reduction. The invention relates to a gas-tight protective coating, devoid of chromium, for chromium-oxide forming substrates, such as for example typical interconnector materials, said coating regularly preventing the evaporation of chromium VI compounds during SOFC operating conditions. The invention also relates to a simple method for producing said gas-tight protective coating that is devoid of chromium.

摘要翻译： 通常，用于高温的形成氧化铬的材料，特别是基于铁（铁素体钢）的铬基合金或富铬合金，用作经受高温的互连材料。 在SOFC操作温度下，所述材料组形成铬基氧化顶涂层，其具有防止快速氧化损伤的优点，而且还具有继续反应形成Cr（VI）化合物的缺点。 所述挥发性化合物与阴极材料定期反应，产生损害氧还原的负面影响。 本发明涉及一种不含铬的气态保护涂层，用于形成铬氧化物的基底，例如典型的互连器材料，所述涂层在SOFC操作条件期间有规律地阻止铬VI化合物的蒸发。 本发明还涉及一种用于生产不含铬的气密保护涂层的简单方法。

公开(公告)号：US06936217B2

公开(公告)日：2005-08-30

申请号：US10298293

申请日：2002-11-18

申请人： Willem Joseph Quadadakkers ,  Vladimir Shemet ,  Lorenz Singheiser

发明人： Willem Joseph Quadadakkers ,  Vladimir Shemet ,  Lorenz Singheiser

IPC分类号： C22C38/00 ,  C22C38/18 ,  C22C38/52 ,  H01M8/021 ,  H01M8/0217 ,  H01M2/00 ,  H01M4/02 ,  H01M4/86

CPC分类号： H01M8/0217 ,  C22C38/18 ,  H01M4/905 ,  H01M8/021

摘要： A high temperature material which consists of a chromium oxide forming iron alloy including: a) 12 to 28 wt % chromium, b) 0.01 to 0.4 wt % La, c) 0.2 to 1.0 wt % Mn, d) 0.05 to 0.4 wt % Ti, e) less than 0.2 wt % Si, f) less than 0.2 wt % Al, wherein, at temperatures of 700° C. to 950° C., the high temperature material is capable of forming a Mn Cr2O4 spinel phase. At a temperature of 700° C. to 950° on Mn, Cr2O4 the spinel phase formed protects a body, such as spark plug electrodes and other electrodes.

摘要翻译： 一种由形成氧化铬的铁合金组成的高温材料，包括：a）12至28重量％的铬，b）0.01至0.4重量％的La，c）0.2至1.0重量％的Mn，d）0.05至0.4重量％的Ti ，e）小于0.2重量％的Si，f）小于0.2重量％的Al，其中在700℃至950℃的温度下，高温材料能够形成Mn Cr 2， 尖晶石相。 在Mn上的700℃至950℃的温度下，形成的尖晶石相保护体，例如火花塞电极和其它电极。