公开(公告)号：US5216082A

公开(公告)日：1993-06-01

申请号：US815594

申请日：1991-12-27

申请人： Ernst Heil ,  Uwe Numrich ,  Walter Schellhaas ,  Barbara Geppart ,  Thomas Rhein

发明人： Ernst Heil ,  Uwe Numrich ,  Walter Schellhaas ,  Barbara Geppart ,  Thomas Rhein

IPC分类号： C08F265/06

CPC分类号： C08F265/06

摘要： A clear impact resistant molding compound which does not become cloudy under either the influence of heat or moisture or on weathering and is composed according to the invention of:A) 10 to 90 percent by weight of a continuous rigid phase, essentially of methyl methacrylate, having a glass transition temperature greater than 70.degree. C. andB) 90 to 10 percent by weight of an elastomeric phase, distributed in the rigid phase and partly bound thereto, having a glass transition temperature below -10.degree. C., an average particle size of the elastomeric phase below 130 nm, and an inhomogeneity, U, of the elastomeric phase particle size of less than 0.5, comprising at least 50 percent by weight of B) of a lower alkyl acrylate and 0.5-5 percent by weight of a graft cross linking agent or an at least trifunctional cross linking agent,C) not more than 0.05 percent by weight of water soluble components,where U=D.sub.w.sup.3 /D.sub.n.sup.3- 1 D.sub.w and D.sub.n are, respectively the weight average- and number average-values of the particle size,films prepared from such a molding compound;multilayer shaped bodies wherein at least one layer is of such a molding compound;methods for making such molding compounds, films, and shaped bodies.

摘要翻译： 一种在热或湿气或风化影响下不变浑浊的透明抗冲击成型化合物，并且根据本发明组成：A）10至90重量％的连续刚性相，基本上为甲基丙烯酸甲酯， 具有大于70℃的玻璃化转变温度和B）90至10重量％的弹性体相分布在刚性相中且部分结合到其上，玻璃化转变温度低于-10℃，平均颗粒 弹性体相的尺寸低于130nm，弹性体相粒度的不均匀性U小于0.5，包含至少50重量％的B）丙烯酸低级烷基酯和0.5-5重量％的 接枝交联剂或至少三官能交联剂，C）不超过0.05重量％的水溶性组分，其中U = Dw3 / Dn3-1 Dw和Dn分别为重均分子量和数均分子量 o f粒径，由这种模塑料制备的薄膜; 多层成形体，其中至少一层是这种模塑料; 制造这种模塑料，薄膜和成形体的方法。

公开(公告)号：US4543383A

公开(公告)日：1985-09-24

申请号：US684179

申请日：1984-12-21

申请人： Ernst Heil ,  Franz Wenzel ,  Peter J. Arndt ,  Walter Schellhaas

发明人： Ernst Heil ,  Franz Wenzel ,  Peter J. Arndt ,  Walter Schellhaas

IPC分类号： C08F2/00 ,  C08F2/22 ,  C08F265/06 ,  C08F285/00 ,  C08F291/00 ,  C08F291/02

CPC分类号： C08F265/06 ,  C08F285/00 ,  Y10S525/902

摘要： What are disclosed are a continuous emulsion polymerization method for making an aqueous dispersion of an impact resistant resin, adaptable to use as a component of impact resistant polymethacrylate forming masses, by first emulsion polymerizing a first monomer component onto core particles of a seed latex until a degree of polymerization of said monomers from 80 to 95 percent is attained, whereby an intermediate product comprising said core particles covered with a rubbery polymer phase is obtained, and then emulsion polymerizing a second monomer component onto the particles of said intermediate product to form a shell of harder polymer on the particles of said intermediate product, and impact resistant resin products made by this method.

摘要翻译： 所公开的是通过首先将第一单体组分聚合到种子胶乳的核心颗粒上，制备适用于作为抗冲击聚甲基丙烯酸甲酯形成团块的组分的耐冲击树脂的水性分散体的连续乳液聚合方法，直至 得到所述单体的聚合度为80-95％，由此获得包含用橡胶状聚合物相覆盖的核心颗粒的中间产物，然后将第二单体组分乳液聚合到所述中间产物的颗粒上以形成壳 所述中间产物的颗粒上的较硬聚合物，以及通过该方法制备的耐冲击树脂产品。